Water pollution in gold mining industry: a case study in Roşia Montană district, Romania

The preliminary study of streams and rivers from the Roşia Montană area revealed that the concntration of heavy metals— Cd, Mn, Cu, Pb, and Zn—are above accepted limits. The gold extraction method is based on flotation. The most important pollution sources are mine tailings. The determinations were performed for samples collected in: April 2004, July 2004, September 2004, November 2004, February 2005 and May 2005. The highest concentrations were found for cadmium in September 2004: 0.17 mg/L; for copper in September 2004: 1.38 mg/L; for manganese in July 2004: 239.4 mg/L; for lead in May 2005: 0.54 mg/L; and for zinc in September 2004: 35.37 mg/L;. This study involved three small rivers (streams) that flow into the Mureş River and finally into the Danube River, having a great impact on human health and environmental stability in the area. In May 2005, a sample of drinking water from the mining district was also collected.     

Stability and inter-conversion of synthetic dawsonites in aqueous media

Previous works have opened the debate on the importance of dawsonite in CO₂ sequestration by mineral trapping, although there is a lack of systematic studies assessing its long-term stability. With an open eye to this application, we have systematically investigated the stability of synthetic dawsonites (MAlCO₃(OH)₂, M = , Na⁺, and K⁺) in a variety of aqueous media (, Cl⁻, , , and OH⁻) at ambient pressure and 323 K. The three compositions dissolved under strong acid (pH 2) and basic (pH 14) conditions. In water (pH 7), dawsonites were not stable, evolving into boehmite (NH₄-form) and bayerite (Na and K-forms). The most interesting transformations occurred upon contacting the synthesized dawsonites with ammonium, potassium, and sodium carbonate solutions. NH₄-dawsonite was converted into Na-dawsonite and K-dawsonite in Na₂CO₃ and K₂CO₃ (pH 12), respectively. Na-dawsonite transformed into NH₄-dawsonite in (NH₄)₂CO₃ (pH 10). The NH₄-dawsonite and Na-dawsonite can be successively inter-converted in the appropriate carbonate solution. These transformations are thought to follow a dissolution-precipitation mechanism. In the pH range of 10-12, K-dawsonite was the most stable among the three synthesized samples. Besides structural changes, the treatment of dawsonites in carbonate solutions caused remarkable morphology and porosity alterations of the product samples. Our study provides an improved understanding of the chemistry of dawsonite-type compounds. In particular, the narrow pH range at which they are stable poses serious constraints in their potential use for geochemical fixation of CO₂.     

Linking Tarim Basin sea retreat (west China) and Asian aridification in the late Eocene

The Tarim Basin in western China formed the easternmost margin of a shallow epicontinental sea that extended across Eurasia and was well connected to the western Tethys during the Paleogene. Climate modelling studies suggest that the westward retreat of this sea from Central Asia may have been as important as the Tibetan Plateau uplift in forcing aridification and monsoon intensification in the Asian continental interior due to the redistribution of the land‐sea thermal contrast. However, testing of this hypothesis is hindered by poor constraints on the timing and precise palaeogeographic dynamics of the retreat. Here, we present an improved integrated bio‐ and magnetostratigraphic chronological framework of the previously studied marine to continental transition in the southwest Tarim Basin along the Pamir and West Kunlun Shan, allowing us to better constrain its timing, cause and palaeoenvironmental impact. The sea retreat is assigned a latest Lutetian–earliest Bartonian age (ca. 41 Ma; correlation of the last marine sediments to calcareous nannofossil Zone CP14 and correlation of the first continental red beds to the base of magnetochron C18r). Higher up in the continental deposits, a major hiatus includes the Eocene–Oligocene transition (ca. 34 Ma). This suggests the Tarim Basin was hydrologically connected to the Tethyan marine Realm until at least the earliest Oligocene and had not yet been closed by uplift of the Pamir–Kunlun orogenic system. The westward sea retreat at ca. 41 Ma and the disconformity at the Eocene–Oligocene transition are both time‐equivalent with reported Asian aridification steps, suggesting that, consistent with climate modelling results, the sea acted as an important moisture source for the Asian continental interior.     

Unique first-forbidden β-decay rates for neutron-rich nickel isotopes in stellar environment

In astrophysical environments, allowed Gamow-Teller (GT) transitions are important, particularly for β-decay rates in presupernova evolution of massive stars, since they contribute to the fine-tuning of the lepton-to-baryon content of the stellar matter prior to and during the collapse of a heavy star. In environments where GT transitions are unfavored, first-forbidden transitions become important especially in medium heavy and heavy nuclei. Particularly in case of neutron-rich nuclei, first-forbidden transitions are favored primarily due to the phase-space amplification for these transitions. In this work the total β-decay half-lives and the unique first-forbidden (U1F) β-decay rates for a number of neutron-rich nickel isotopes, ^72–78Ni, are calculated using the proton-neutron quasi-particle random phase approximation (pn-QRPA) theory in stellar environment for the first time. For the calculation of the β-decay half-lives both allowed and unique first-forbidden transitions were considered. Comparison of the total half-lives is made with measurements and other theoretical calculations where it was found that the pn-QRPA results are in better agreement with experiments and at the same time are suggestive of inclusion of rank 0 and rank 1 operators in first-forbidden rates for still better results.     

Isolation,biodegradation ability and molecular detection of hydrocarbon degrading bacteria in petroleum samples from a Brazilian offshore basin

The detection of microorganisms with potential for biodeterioration and biodegradation in petroleum fields is of great relevance, since these organisms may be related to a decrease in petroleum quality in the reservoirs or damage in the production facilities. In this sense, petroleum formation water and oil samples were collected from the Campos Basin, Brazil, with the aim of isolating microorganisms and evaluating their ability to degrade distinct classes of hydrocarbon biomarkers (9,10-dihydrophenanthrene, phytane, nonadecanoic acid and 5α-cholestane). Twenty eight bacterial isolates were recovered and identified by sequencing their 16S rRNA genes. Biodegradation assays revealed that bacterial metabolism of hydrocarbons occurred through reactions based on oxidation, carbon–carbon bond cleavage and generation of new bonds or by the physical incorporation of hydrocarbons into microbial cell walls. Based on the biodegradation results, selective PCR-based systems were developed for direct detection in petroleum samples of bacterial groups of interest, namely Bacillus spp., Micrococcus spp., Achromobacter xylosoxidans, Dietzia spp. and Bacillus pumilus. Primer sets targeting 16S rRNA genes were designed and their specificity was confirmed in silico (i.e. computational analysis) and in PCR reactions using DNA from reference strains as positive and negative controls. Total DNA from oil was purified and the amplification tests revealed the presence of the target bacteria in the samples, unraveling a significant potential for petroleum deterioration in the reservoirs sampled, once proper conditions are present for hydrocarbon degradation. The application of molecular methods for rapid detection of specific microorganisms in environmental samples would be valuable as a supporting tool for the evaluation of oil quality in production reservoirs.     

Paleogene evolution and demise of the proto‐Paratethys Sea in Central Asia (Tarim and Tajik basins): Role of intensified tectonic activity at ca. 41 Ma

The proto‐Paratethys Sea covered a vast area extending from the Mediterranean Tethys to the Tarim Basin in western China during Cretaceous and early Paleogene. Climate modelling and proxy studies suggest that Asian aridification has been governed by westerly moisture modulated by fluctuations of the proto‐Paratethys Sea. Transgressive and regressive episodes of the proto‐Paratethys Sea have been previously recognized but their timing, extent and depositional environments remain poorly constrained. This hampers understanding of their driving mechanisms (tectonic and/or eustatic) and their contribution to Asian aridification. Here, we present a new chronostratigraphic framework based on biostratigraphy and magnetostratigraphy as well as a detailed palaeoenvironmental analysis for the Paleogene proto‐Paratethys Sea incursions in the Tajik and Tarim basins. This enables us to identify the major drivers of marine fluctuations and their potential consequences on Asian aridification. A major regional restriction event, marked by the exceptionally thick (≤ 400 m) shelf evaporites is assigned a Danian‐Selandian age (ca. 63–59 Ma) in the Aertashi Formation. This is followed by the largest recorded proto‐Paratethys Sea incursion with a transgression estimated as early Thanetian (ca. 59–57 Ma) and a regression within the Ypresian (ca. 53–52 Ma), both within the Qimugen Formation. The transgression of the next incursion in the Kalatar and Wulagen formations is now constrained as early Lutetian (ca. 47–46 Ma), whereas its regression in the Bashibulake Formation is constrained as late Lutetian (ca. 41 Ma) and is associated with a drastic increase in both tectonic subsidence and basin infilling. The age of the final and least pronounced sea incursion restricted to the westernmost margin of the Tarim Basin is assigned as Bartonian–Priabonian (ca. 39.7–36.7 Ma). We interpret the long‐term westward retreat of the proto‐Paratethys Sea starting at ca. 41 Ma to be associated with far‐field tectonic effects of the Indo‐Asia collision and Pamir/Tibetan plateau uplift. Short‐term eustatic sea level transgressions are superimposed on this long‐term regression and seem coeval with the transgression events in the other northern Peri‐Tethyan sedimentary provinces for the 1st and 2nd sea incursions. However, the 3rd sea incursion is interpreted as related to tectonism. The transgressive and regressive intervals of the proto‐Paratethys Sea correlate well with the reported humid and arid phases, respectively in the Qaidam and Xining basins, thus demonstrating the role of the proto‐Paratethys Sea as an important moisture source for the Asian interior and its regression as a contributor to Asian aridification.     

The Tajik Basin: A composite record of sedimentary basin evolution in response to tectonics in the Pamir

Investigation of a >6-km-thick succession of Cretaceous to Cenozoic sedimentary rocks in the Tajik Basin reveals that this depocentre consists of three stacked basin systems that are interpreted to reflect different mechanisms of subsidence associated with tectonics in the Pamir Mountains: a Lower to mid-Cretaceous succession, an Upper Cretaceous–Lower Eocene succession and an Eocene–Neogene succession. The Lower to mid-Cretaceous succession consists of fluvial deposits that were primarily derived from the Triassic Karakul–Mazar subduction–accretion complex in the northern Pamir. This succession is characterized by a convex-up (accelerating) subsidence curve, thickens towards the Pamir and is interpreted as a retroarc foreland basin system associated with northward subduction of Tethyan oceanic lithosphere. The Upper Cretaceous to early Eocene succession consists of fine-grained, marginal marine and sabkha deposits. The succession is characterized by a concave-up subsidence curve. Regionally extensive limestone beds in the succession are consistent with late stage thermal relaxation and relative sea-level rise following lithospheric extension, potentially in response to Tethyan slab rollback/foundering. The Upper Cretaceous–early Eocene succession is capped by a middle Eocene to early Oligocene (ca. 50–30 Ma) disconformity, which is interpreted to record the passage of a flexural forebulge. The disconformity is represented by a depositional hiatus, which is 10–30 Myr younger than estimates for the initiation of India–Asia collision and overlaps in age with the start of prograde metamorphism recorded in the Pamir gneiss domes. Overlying the disconformity, a >4-km-thick upper Eocene–Neogene succession displays a classic, coarsening upward unroofing sequence characterized by accelerating subsidence, which is interpreted as a retro-foreland basin associated with crustal thickening of the Pamir during India–Asia collision. Thus, the Tajik Basin provides an example of a long-lived composite basin in a retrowedge position that displays a sensitivity to plate margin processes. Subsidence, sediment accumulation and basin-forming mechanisms are influenced by subduction dynamics, including periods of slab-shallowing and retreat.     

Petrology and provenance of a very‐low‐titanium picrite clast in lunar highland regolith breccia 15295

Clast 100 in regolith breccia 15295 could be a key to resolving the relationship(s) between mare basalts and lunar picritic glasses. The clast is basaltic, with texture, mineralogy, mineral compositions, and calculated bulk composition suggesting that it crystallized in a thick lava flow or shallow intrusive body from a very‐low‐titanium (VLT) basaltic magma. The estimated bulk composition of clast 15295,100 is primitive (i.e., magnesian) compared to those of known VLT basalts, and is very close to those of VLT picritic green glasses, especially the Apollo 14 A green glass. From these similarities, we infer that clast 15295,100 is a crystalline product of a picritic magma similar to the Apollo 14 A glass. Clementine and M³ remotely sensed data of the lunar surface were used to find areas that have chemical compositions consistent with those of clast 15295,100, not only near the Apollo 15 site, but in a broad region surrounding the site. Two regions are consistent with clast's 15295,100 compositional data. The larger region is in southern Mare Imbrium, and a smaller region is in the eastern half of Sinus Aestuum. These locations should be considered as candidates for future missions focusing on sample science.     

Late Miocene to Pliocene stratigraphy of the Kura Basin,a subbasin of the South Caspian Basin: implications for the diachroneity of stage boundaries

Relative ages of late Cenozoic stratigraphy throughout the Caspian region are referenced to regional stages that are defined by changes in microfauna and associated extreme (>1000 m) variations in Caspian base level. However, the absolute ages of these stage boundaries may be significantly diachronous because many are based on the first occurrence of either transgressive or regressive facies, the temporal occurrence of which should depend on position within a basin. Here, we estimate the degree of diachroneity along the Akchagyl regional stage boundary within the Caspian basin system by presenting two late Miocene‐Pliocene aged measured sections, Sarica and Vashlovani, separated by 50 km and exposed within the Kura fold‐thrust belt in the interior of the Kura Basin. The Kura Basin is a western subbasin of the South Caspian Basin and the sections presented here are located >250 km from the modern Caspian coast. New U‐Pb detrital zircon ages from the Sarica section constrain the maximum depositional age for Productive Series strata, a lithostratigraphic package considered correlative with the 2–3 Myr‐long regional Eoakchagylian or Kimmerian stage that corresponds to a period of extremely low (>500 m below the modern level) Caspian base level. This new maximum depositional age from the Productive Series at Sarica of 2.5 ± 0.2 Ma indicates that the regionally extensive Akchagyl transgression, which ended the deposition of the Productive Series near the Caspian coast at 3.2 Ma, may have appeared a minimum of 0.5 Myr later in the northern interior of the Kura Basin than at the modern Caspian Sea coast. The results of this work have important implications for the tectonic and stratigraphic history of the region, suggesting that the initiation of the Plio‐Pleistocene Kura fold‐thrust belt may have not been as diachronous along strike as previously hypothesized. More generally, these results also provide a measure of the magnitude of diachroneity possible along sequence boundaries, particularly in isolated basins. Comparison of accumulation rates between units in the interior of the Kura subbasin and the South Caspian main basin suggest that extremely large variations in these rates within low‐stand deposits may be important in identifying the presence of subbasins in older stratigraphic packages.