Correlation between geochemical environments and controlling factors in the metallation of porphyrins

Experimental study on metallation of tetrapyrroles in biphasic systems showed that complexation with metal cations of the first transition series is a feasible under chemical environments similar to the naturally occurring ones. The metal transport from the aqueous media to the organic, which is a novel approach using naturally occurring fatty acids hydroxy aromatic compounds and thiols, is demonstrated. Selectivity between Ni²⁺ and VO²⁺ complexation is achieved under sulfurous rich conditions. The kinetic implications are discussed in view of their geoenvironmental applicability.     

Assessment of the coupled effects of vegetation leaf and root characteristics on soil suction: an integrated numerical modeling and probabilistic approach

Acta Geotechnica - Root depth and leaf area ratio are two important features of a plant and exhibit a coupled relation. Assessing their coupled effects on induced soil suction is essential for...     

Arsenic and mercury contamination in 31 cores taken in 1965, St. Anna Trough, Kara Sea, Arctic Ocean

 Several cores of 31 collected in 1965 in the St. Anna Trough, Kara Sea, have very high concentrations of Hg and As in surface/near-surface samples. Mercury contents range from 94 to 3915 ppb with a mean of 444 ppb and a baseline value of 314 ppb. Arsenic contents range from 5 to 710 ppm with a mean of 51 ppm and a baseline value of 23 ppm. The Hg and part of the As loading is likely anthropogenic from industrial activities in Siberia via atmospheric emission and deposition onto catchments. This is followed by mobilization into fluvial systems and is added to by industrial effluent discharge. Post-depositional diagenesis from depth in the cores contributes to high As values. A north-flowing bottom current transports Hg- and As-bearing suspended material from the Ob River sea discharge zone to depositional environments in the St. Anna Trough. Dumping of military materials and other wastes into the Kara Sea from the late 1940s to 1991 has likely added to Hg and As loading in the trough sediments. The bioavailability of mercury from suspended materials may be the reason why higher than normal levels of these potentially toxic elements are found in European Arctic seabirds, ringed seal and polar bear. Received: 12 December 1999 · Accepted: 23 May 2000     

Technical characteristics of a solar geoengineering deployment and implications for governance

ABSTRACT

Consideration of solar geoengineering as a potential response to climate change will demand complex decisions. These include not only the choice of whether to deploy solar engineering, but decisions regarding how to deploy, and ongoing decision-making throughout deployment. Research on the governance of solar geoengineering to date has primarily engaged only with the question of whether to deploy. We examine the science of solar geoengineering in order to clarify the technical dimensions of decisions about deployment – both strategic and operational – and how these might influence governance considerations, while consciously refraining from making specific recommendations. The focus here is on a hypothetical deployment rather than governance of the research itself. We first consider the complexity surrounding the design of a deployment scheme, in particular the complicated and difficult decision of what its objective(s) would be, given that different choices for how to deploy will lead to different climate outcomes. Next, we discuss the on-going decisions across multiple timescales, from the sub-annual to the multi-decadal. For example, feedback approaches might effectively manage some uncertainties, but would require frequent adjustments to the solar geoengineering deployment in response to observations. Other decisions would be tied to the inherently slow process of detection and attribution of climate effects in the presence of natural variability. Both of these present challenges to decision-making. These considerations point toward particular governance requirements, including an important role for technical experts – with all the challenges that entails.

Key policy insights

• Decisions about solar geoengineering deployment will be informed not only by political choices, but also by climate science and engineering.

• Design decisions will pertain to the spatial and temporal goals of a climate intervention and strategies for achieving those goals.

• Some uncertainty can be managed through feedback, but this would require frequent operational decisions.

• Some strategic decisions will depend on the detection and attribution of climatic effects from solar geoengineering, which may take decades.

• Governance for solar geoengineering deployment will likely need to incorporate technical expertise for making short-term adjustments to the deployment and conducting attribution analysis, while also slowing down decisions made in response to attribution analysis to avoid hasty choices.

     

Friction on a granite to granite interface

Summary Direct shear tests were conducted on a granite to granite interface for the purpose of tracing the evolution of frictional resistance as the initially smooth and polished surface wears during continuing shearing displacement. At the moment when sliding on the freshly manufactured interface starts (first slip), the friction angle is very low, between 15° and 20°, but then it increases with displacement rapidly without reaching a peak in the first test (maximum displacement less than 25 mm). Upon repeated shearing of the same surface (without re-finishing), this process of displacement-strengthening continues until a total accumulated displacement of about one half of one meter is reached. At this point, the angle of friction would typically be between 42° and 44°.Once the residual surface was established, the effect of time-related parameters, the duration of stationary contact under constant normal and shear load and variable displacement rate, were investigated. The frictional resistance is shown to increase with decreasing displacement rate and to increase with the duration of stationary contact.At a normal load greater than about one half of one MPa, shear displacement on a residual surface proceeds in an unstable, stick-slip manner. The change from stable to unstable sliding, that can be effected by either decreasing the sliding velocity or increasing the normal load, is not instantaneous, but occurs over a finite amount of displacement.     

Relationships Among Exceedences of Sediment Guidelines,the Results of Ambient Sediment Toxicity Tests,and Community Metrics in Estuarine Systems

To use bioassessments to help diagnose or identify the specific environmental stressors affecting estuaries, we need a better understanding of the relationships among sediment chemistry guidelines, ambient toxicity tests, and community metrics. However, this relationship is not simple because metrics generally assess the responses at the community level of biological organization whereas sediment guidelines and ambient toxicity tests generally assess or are based on the responses at the organism level. The relationship may be further complicated by the influence of other chemical and physical variables that affect the bioavailability and toxicity of chemical contaminants in the environment. Between 1990 and 1993, the U.S. Environmental Protection Agency (USEPA) conducted an Environmental Monitoring and Assessment Program (EMAP) survey of estuarine sites in the Virginian Province of the eastern United States. The surveys collected data on benthic assemblages, physical and chemical habitat characteristics, and sediment chemistry and toxicity. We characterized these estuarine sites as affected by sediment contamination based on the exceedence of sediment guidelines or on ambient sediment toxicity tests (i.e., 10-day Ampelisca abdita survival). Then, benthic invertebrate metrics were compared among affected and unaffected sites to identify metrics sensitive to the contamination. A number of benthic invertebrate metrics differed between groups of sites segregated using the organism-level measures whereas other metrics did not. The difference among metrics appears to depend on the sensitivity of the individual metrics to the stressor gradient represented by metals or persistent organic toxics in sediments because the insensitive metrics do not effectively quantify the changes in the benthic invertebrate assemblage associated with these stressors. The significant relationships suggest that a relationship exists between the organism-level effects assessed by chemistry or ambient toxicity tests and the community-level effects assessed by community metrics and that the organism-level effects are predictive, to some extent, of community-level effects.     

Assimilation of Indian radar data with ADAS and 3DVAR techniques for simulation of a small-scale tropical cyclone using ARPS model

The center for Analysis and Prediction of Storms (CAPS) has developed a radar data assimilation system. The system consists of several principal components: (1) a program that quality-controls and remaps (or super-ob) radar data to the analysis grid, (2) a Bratseth analysis method (ADAS), or a 3DVAR method for analyzing all the data except for clouds and precipitation, (3) a cloud and hydrometer analysis package that applies diabetic adjustments to the temperature field, and (4) a non-hydrostatic forecast model named ARPS. In this study, the system is applied to a small cyclone named OGNI, which formed over Bay of Bengal, India during the last week of October 2006. Three experiments are carried out to test the impact of the radar data from Chennai, India. These experiments include (1) using NCEP GFS data to initialize the ARPS model (2) using initial and boundary condition produced from the ADAS and the cloud analysis, (3) using initial and boundary condition produced from the 3DVAR and cloud analysis. The inter-comparison of results reveals that the experiment with the 3DVAR assimilation technique produces more realistic forecast to capture the genesis, structure, and northward movement of the cyclone in the short-range time scale.     

The Svalbard western coast: site of baseline geochemistry and incipient contamination

 Potentially toxic metals tracked by the Arctic Monitoring and Assessment Program were analysed in sediments from the Svalbard western coastal zone. These include As and Hg found as contaminants in other Arctic seas as well as other elements (e.g. Pb, V, Cu, Zn, Cr, Ni). Svalbard shelf sediments contain average values of 12 ppm As, 12 ppm Pb, 56 ppb Hg and 114 ppm V. These values increase in Isfjorden sediments to 15 ppm As, 28 ppm Pb, 99 ppb Hg and 210 ppm V. Cluster analysis yields a major cluster that is likely related to clay minerals (Al, K, Ti, Mg) and sorption onto them of transition (Cu, V, Cr, Sc) and other elements (Pb, Rb). A second significant cluster includes Ca, Sr and plagioclase. The Svalbard western shelf is a natural geochemical environment. The possible incipient contamination of fjord sediments by As, Pb, Hg and V should be evaluated for possible links to anthropogenic sources. If links are found, remediation must be used to stop the input and preserve a pristine Svalbard fjord environment. Received: 21 December 1998 · Accepted: 15 March 1999     

Dynamics of the coupled human–climate system resulting from closed-loop control of solar geoengineering

If solar radiation management (SRM) were ever implemented, feedback of the observed climate state might be used to adjust the radiative forcing of SRM in order to compensate for uncertainty in either the forcing or the climate response. Feedback might also compensate for unexpected changes in the system, e.g. a nonlinear change in climate sensitivity. However, in addition to the intended response to greenhouse-gas induced changes, the use of feedback would also result in a geoengineering response to natural climate variability. We use a box-diffusion dynamic model of the climate system to understand how changing the properties of the feedback control affect the emergent dynamics of this coupled human–climate system, and evaluate these predictions using the HadCM3L general circulation model. In particular, some amplification of natural variability is unavoidable; any time delay (e.g., to average out natural variability, or due to decision-making) exacerbates this amplification, with oscillatory behavior possible if there is a desire for rapid correction (high feedback gain). This is a challenge for policy as a delayed response is needed for decision making. Conversely, the need for feedback to compensate for uncertainty, combined with a desire to avoid excessive amplification of natural variability, results in a limit on how rapidly SRM could respond to changes in the observed state of the climate system.     

The possible source of the causal time arrow in geo-historical explanations

My argument in this article, will be that nature, in general, and human nature in particular, suggests that, in principle, it is possible to derive the causal time arrow from several physical time arrows existing in nature and appearing to be unidirectional and irreversible phenomena. A more concrete argument will be that the assumption of a causal time arrow to which geologists resort in all geo-historical explanations, apparently originates in geo-historical time arrows concealed in unidirectional and irreversible physical-geological processes. I will illustrate this claim with a few examples of geo-historical explanations in the theory of plate tectonics, most of which are based on irreversible geo-physical processes. My final argument is a broader, of an epistemological nature, according to which the causal time arrow assumption used in logical-causative explanations in everyday life and in science, apparently “derives” in a way from the geo-historical time arrow. I will base this argument on the causal relationship and mutual influence that occurs in nature between geo-historical and evolutionary processes in animals, including developmental processes of the human brain and mind. From this reductionist argument, nicely integrated in the framework of evolutionary epistemology (EEM), it is possible to derive a wider naturalistic argument according to which, on principle, the laws of geo-historical physics can be reduced to the laws of logic and causality.