Salinity and redox alternations in the northwestern Baltic proper during the late Holocene

Selected geochemical parameters and siliceous microfossil assemblages in Baltic Sea sediments are presented which reflect past variations in redox conditions, salinity and primary production. The sediments were deposited during the freshwater Ancylus Lake (9500-8000 ¹⁴C BP) and brackish Litorina Sea (8000-3000 BP) stages of the Baltic. The diatom record shows that surface-water salinity increased further at c . 7000-6500 BP, although smaller amounts of brackish water entered the basin from c . 8000 BP onwards. Attempts to use exchangeable Mg as a palaeosalinity indictor were not applicable. Gross primary productivity increased along with salinity, which has been interpreted as an effect of nutrient enrichment in the photic zone. This led between c . 6500 and 4500 BP to a high accumulation of organic carbon, anoxic or nearly anoxic bottom conditions and formation of laminated deposits. Certain laminae consist of alternating layers of organic and minerogenic material and were probably formed annually, i.e. in the manner of varves. The laminated successions are distinguished by enrichments of V, Cu and especially Mo. The highest Mo content occurs in the core from the greatest water depth, an effect of anoxic conditions during deposition. The Fe/Mn ratio was shown to be ambiguous as an indicator of past redox conditions. Since biogenic silica shows large variablity in contemporaneously deposited sediments, this parameter cannot be used as a proxy for the past production of siliceous algae in the Baltic Sea.     

The Holocene history of the southwestern Baltic Sea as reflected in a sediment core from the Bornholm Basin

A study of changes in siliceous microfossil assemblages and chemical analyses in a well-dated offshore sediment core from the Bornholm Basin, southwestern Baltic Sea, is carried out with the objective of increasing knowledge of the Holocene history of the area. The core covers about 11 300 calendar years from the brackish phase of the Yoldia Sea stage to the present. The first weak marine influence in the Ancylus Lake stage is recorded about 10 100 cal. yr BP (c. 8900 ¹⁴C BP), indicating a complex transition to the Litorina Sea with different phases of brackish-water inflow. The lithology, organic carbon content and C/N and C/S ratios indicate no major changes in the sedimentary environment during the Litorina-Post-Litorina Sea stages. A high productivity event recorded in the Post-Litorina Sea stage around 950 cal. yr BP correlates with the Medieval warm event. A biostratigraphical change indicating a colder climate is recorded in the sediment at about 800 cal. yr BP, which might mark the beginning of the Little Ice Age.     

Simulated climate conditions in Europe during the Marine Isotope Stage 3 stadial

Kjellström, E., Brandefelt, J., Näslund, J.‐O., Smith, B., Strandberg, G., Voelker, A. H. L. & Wohlfarth, B. 2010: Simulated climate conditions in Europe during the Marine Isotope Stage 3 stadial. Boreas, 10.1111/j.1502‐3885.2010.00143.x. ISSN 0300‐9483. State‐of‐the‐art climate models were used to simulate climate conditions in Europe during Greenland Stadial (GS) 12 at 44 ka BP. The models employed for these simulations were: (i) a fully coupled atmosphere–ocean global climate model (AOGCM), and (ii) a regional atmospheric climate model (RCM) to dynamically downscale results from the global model for a more detailed investigation of European climate conditions. The vegetation was simulated off‐line by a dynamic vegetation model forced by the climate from the RCM. The resulting vegetation was then compared with the a priori vegetation used in the first simulation. In a subsequent step, the RCM was rerun to yield a new climate more consistent with the simulated vegetation. Forcing conditions included orbital forcing, land–sea distribution, ice‐sheet configuration, and atmospheric greenhouse gas concentrations representative for 44 ka BP. The results show a cold climate on the global scale, with global annual mean surface temperatures 5 °C colder than the modern climate. This is still significantly warmer than temperatures derived from the same model system for the Last Glacial Maximum (LGM). Regional, northern European climate is much colder than today, but still significantly warmer than during the LGM. Comparisons between the simulated climate and proxy‐based sea‐surface temperature reconstructions show that the results are in broad agreement, albeit with a possible cold bias in parts of the North Atlantic in summer. Given a prescribed restricted Marine Isotope Stage 3 ice‐sheet configuration, with large ice‐free regions in Sweden and Finland, the AOGCM and RCM model simulations produce a cold and dry climate in line with the restricted ice‐sheet configuration during GS 12. The simulated temperature climate, with prescribed ice‐free conditions in south‐central Fennoscandia, is favourable for the development of permafrost, but does not allow local ice‐sheet formation as all snow melts during summer.     

Mineral magnetic properties of Late Weichselian-Holocene sediments from the northwestern Baltic Proper

Mineral magnetic measurements were carried out on twelve sediment cores from the northwestern part of the Baltic Proper. The purpose was to use magnetic properties to correlate sediment sequences and to investigate changes in depositional conditions (e.g. rate of sedimentation and redox conditions). A general lithostratigraphy consisting of five units was established based mainly on mineral magnetic properties. Sediment has been deposited from the time of the Baltic Ice Lake (before 10 300 ¹⁴C years BP) to the present, i.e. since the Late Weichselian deglaciation. Five of the cores were also investigated by means of biostratigraphical methods and three by ¹⁴C dates. Based on the general stratigraphy and hiatuses, variations in sedimentation rate were identified. The occurrence of authigenically formed ferrimagnetic greigite (Fe₃S₄), mainly in sediments deposited during the brackish Yoldia Sea and Litorina Sea stages, is implied. These sequences are characterized by low S-ratios and high SIRM/z ratios. Glacial clay, deposited in freshwater during the Baltic Ice Lake stage and the early freshwater phase of the Yoldia Sea stage, seems to be unaffected by diagenetic processes. Gyttja clay, deposited in the Litorina Sea, has significantly lower susceptibility and SIRM than in the underlying clay. Dissolution of magnetic iron oxides (e.g. magnetite and hematite) in an anoxic environment was suggested as an explanation.