Restructuring of polygalacturonate on alumina upon hydration—Effect on phosphate sorption kinetics

Hydration of organic coatings in soils is expected to affect the sorption of oxyanions onto hydrous Fe and Al oxides. We hypothesized that the hydration of polygalacturonate (PGA) coatings on alumina (Al₂O₃) increases their permeability for phosphate. Pure and PGA-coated alumina were equilibrated in deionized water for 2 and 170 h at pH 5 and 20 °C before studying (i) their porosity with N₂ gas adsorption and ¹H NMR relaxometry, (ii) structural changes of PGA-coatings with differential scanning calorimetry (DSC), and (iii) the kinetics of phosphate sorption and PGA desorption in batch experiments. Scanning electron micrographs revealed that PGA molecules formed three-dimensional networks with pores ranging in size from <10 to several hundred nanometers. Our NMR results showed that the water content of intraparticle alumina pores decreased upon PGA sorption, indicating a displacement of pore water by PGA. The amount of water in interparticle alumina pores increased strongly after PGA addition, however, and was attributed to water in pores of PGA and/or in pores at the PGA-alumina interface. The flexibility of PGA molecules and the fraction of a PGA gel phase increased within one week of hydration, implying restructuring of PGA. Hydration of PGA coatings increased the amount of phosphate defined as instantaneously sorbed by 84%, showing that restructuring of PGA enhanced the accessibility of phosphate to external alumina surfaces. Despite the fact that the efficacy of phosphate to displace PGA was higher after 170 h than after 2 h, a higher phosphate surface loading was required after 170 h to set off PGA desorption. Our findings imply that the number of PGA chain segments directly attached to the alumina surface decreased with time. We conclude that hydration/dehydration of polymeric surface coatings affects the sorption kinetics of oxyanions, and may thus control the sorption and transport of solutes in soils.     

A 2,500-year record of environmental change in Highlands Hammock State Park (Central Florida, U.S.A.) inferred from siliceous microfossils

Analysis of siliceous microfossils of a 79 cm long peat sediment core from Highlands Hammock State Park, Florida, revealed distinct changes in the local hydrology during the past 2,500 years. The coring site is a seasonally inundated forest where water availability is directly influenced by precipitation. Diatoms, chrysophyte statospores, sponge remains and phytoliths were counted in 25 samples throughout the core. Based on the relative abundance of diatom species, the record was subdivided into four diatom assemblage zones, which mainly reflect the hydrological state of the study site. An age-depth relationship based on radiocarbon measurements of eight samples reveals a basal age of the core of approximately 2,500 cal. yrs. BP. Two significant changes of diatom assemblage composition were found that could be linked to both, natural and anthropogenic influences. At 700 cal. yrs. BP, the diatom record documents a shift from tychoplanktonic Aulacoseira species to epiphytic Eunotia species, indicating a shortening of the hydroperiod, i.e. the time period during which a wetland is covered by water. This transition was interpreted as being triggered by natural climate change. In the middle of the twentieth century a second major turnover took place, at that time however, as a result of human impact on the park hydrology through the construction of dams and canals close to the study site.     

Spring-season changes during the Late Pleniglacial and Bølling/Allerød interstadial

Earlier spring onset and the associated extension of the growing season in high latitudes belong to the most obvious consequences of global warming. The natural dynamics of growing-season properties during past climate shifts however, are extremely difficult to reconstruct since temperature reconstructions are hardly ever seasonally resolved and the applied proxies such as chirinomid or pollen analysis are mainly sensitive to summer temperatures. Here we apply a newly developed leaf cuticle-based proxy to reconstruct growing degree-days (GDD) in a quantitative way and to estimate changes in the timing of spring onset over the last deglaciation. Cuticle analyses of fossil birch leaves preserved in lake sediments from southern Germany reveal extremely low GDD values during the Late Pleniglacial, which are rapidly increasing at the onset of the Bølling/Allerød interstadial. While temperature and GDDs show a simultaneous warming during deglaciation, a GDD decline precedes lowering of summer temperatures during the Older Dryas cooling. Later bud-burst dates support the hypothesis of a shortening the growing season during this cool pulse.     

Quantification strategies for human-induced and natural hydrological changes in wetland vegetation, southern Florida, USA

An accurately dated peat profile from a mixed cypress swamp in the Fakahatchee Strand Preserve State Park (FSPSP, Florida, USA) has been examined for pollen and spores. The near-annual resolved pollen record shows a gradual shift from a wet to a relatively dry assemblage during the past 100 years. Timing of drainage activities in the region is accurately reflected by the onset and duration of vegetation change in the swamp. The reconstructed vegetation record has been statistically related to pollen assemblages from surface sediment samples. The response range of the FSPSP wetland to environmental perturbations could thus be determined and this allows better understanding of naturally occurring vegetation changes. In addition, the human impact on Florida wetlands becomes increasingly apparent. Superimposed high-frequency variation in the record suggests a positive correlation between winter-precipitation and pollen productivity of the dominant tree taxa. However, further high-resolution analysis is needed to confirm this relation. The response range of the FSPSP wetland to environmental perturbations on both annual- and decadal-scales documented in this study allows recognition and quantification of natural hydrological changes in older deposits from southwest Florida. The strong link between local hydrology and the El Niño Southern Oscillation makes the palynological record from FSPSP highly relevant for studying past El Niño—variability.     

Climate change during the past 1000 years: a high‐temporal‐resolution multiproxy record from a mire in northern Finland

We present a record of peatland development in relation to climate changes and human activities from the Palomaa mire, a remote site in northern Finland. We used fine‐resolution and continuous sampling to analyse several proxies including pollen (for vegetation on and around the mire), testate amoebae (TA; for mire‐wetness changes), oxygen and carbon isotopes from Sphagnum cellulose (δ¹⁸O and δ¹³C; for humidity and temperature changes), peat‐accumulation rates and peat‐colour changes. In spite of an excellent accumulation model (30 ¹⁴C dates and estimated standard deviation of sample ages <1 year in the most recent part), the potential to determine cause–effect (or lead–lag) relationships between environmental changes and biotic responses is limited by proxy‐specific incorporation processes below the actively growing Sphagnum surface. Nevertheless, what emerges is that mire development was closely related to water‐table changes rather than to summer temperature and that water‐table decreases were associated with increasing peat‐accumulation rates and more abundant mire vegetation. A rapid fen‐to‐bog transition occurred within a few years around AD 1960 when the water table decreased beyond the historical minimum, supporting the notion that mires can rapidly shift into bogs in response to allogenic factors. Copyright © 2012 John Wiley & Sons, Ltd.     

“You have to engage with life,or life will go away”: An intersectional life course analysis of older women’s social participation in a disadvantaged urban area

Social participation in later life has been studied as part of discourses around ‘active ageing’ but the promotion of participation in disadvantaged urban neighbourhoods meets with particular challenges. In this paper I argue that in order to effectively promote social participation in later life researchers and practitioners require an understanding of life-long relational practices which are embedded in social norms and places as they intersect with identities such as gender, class and age.The intersectional life course analysis traces complex relationalities between people and place across the life course of two women living in disadvantaged urban areas. It shows the effects of societal and structural changes on individuals’ opportunities for social participation as well as demonstrating how age-related relational practices may lead to spatial segregation of older people in society.     

The high-resolution Holocene sea-level curve for Northwest Germany: global signals, local effects or data-artefacts?

A few years ago, a new relative sea-level curve for northwest Germany was constructed for the entire German North Sea coast. It is characterised by several suspected sea-level fluctuations. To test this curve for local effects, it was broken down into five relative sea-level curves representative for five coastal sections. The relative sea-level curves were corrected for tidal effects and also, a rough first correction for compaction was applied. The five curves all differ from the original curve and from each other. Most of the suspected sea-level fluctuations in the original curve cannot be supported and are discussed as data-artefacts or local effects. Around AD 800–1000 all curves show stagnation or drop of sea-level. Thus, this signal is discussed as of over-regional stratigraphic meaning. This study is a first step (1) to show that several curves are needed to demonstrate the Holocene sea-level history of such a big area as the entire German North Sea coast and (2) to establish reliable relative sea-level curves for the German North Sea coast. Further research is necessary to apply detailed corrections especially with respect to compaction-prone data and to improve the individual curves.     

Integrated environmental assessment of fisheries management: Swedish Nephrops trawl fisheries evaluated using a life cycle approach

Fisheries management needs to broaden its perspective to achieve sustainable resource use. Life cycle assessment (LCA) is an ISO standardized method to evaluate the environmental impacts of products using a broad and systematic approach. In this study, the outcome of a management regime promoting species-selective trawling in Swedish Nephrops trawl fisheries was studied using LCA methodology by quantifying the impacts per kilogram of landing using two different fishing methods. Demersal trawling has previously been found to be both energy intensive and destructive in terms of seafloor impact and discards. It is demonstrated that species-selective trawling fulfils management objectives, although with tradeoffs in terms of fuel consumption and associated GHG emissions. To prioritize between impacts, one must be aware of and quantify these potential tradeoffs. LCA could be an important tool for defining sustainable seafood production as it can visualize a broad range of impacts and facilitate integrated, transparent decision making in the seafood industry. It is also concluded that, with current LCA methodology, use of total discarded mass could increasingly be distinguished from potential impact by applying two new concepts: primary production requirements and threatened species affected.