Variation of infiltration rate through karstic surfaces due to land use changes: A case study in Murgia (SE-Italy)

Groundwaters of the Murgia carbonate aquifer represent the main groundwater resource of the Apulia region (SE Italy). In the highlands (Alta Murgia) karst crops out in different forms and textures which have been preserved up to the 1970s: little evolved agriculture and sheep rearing produced only a marginal modification of the epikarst while a high degree of division into parcels by drystone walls helped in preserving soils from erosion. In the last years the original scenery of the Alta Murgia changed due to widespread transformations of surface karstic textures for agricultural purposes, with undeniable negative consequences on the hydrogeological balance, concerning both the infiltration and the runoff terms. Stone shattering led to flattening and deep alteration of a large part of the original karstic landscape and to demolition of drystone walls.In a study area of about 139 km² located in the Alta Murgia, the comparison of aerial photos related to the period 1950–2001 indicated that stone shattering had occurred for about 42% of the area.The hydrological behaviour of the first soil layer of experimental parcels representing both shattered stone and natural karstic surface textures was analysed by using the numerical model Hydrus-2D with the aim of estimating the variation on infiltration rate due to stone shattering. Intensive field and laboratory measurements concerned soil texture, soil water content, pressure head, saturated hydraulic conductivity, pan evaporation and meteorological parameters.     

Evidence for fluid circulation, overpressure and tectonic style along the Southern Chilean margin

The southern Chilean convergent margin, between 50° and 57° S, is shaped by the interaction of the three main plates: Antarctic, South America and Scotia. North of 53° S, the convergence between Antarctic and South America plates is close to orthogonal to the continental margin strike. Here, the deformational style of the accretionary prism is mainly characterized by seaward-verging thrusts and locally by normal faults and fractures, a very limited lateral extension of prism, a very shallow dip ( 6°) décollement, and subduction of a thick and relatively undeformed trench sedimentary sequence. South of 53° S, convergence is oblique to the margin, locally, the trench sediments are proto-deformed by double vergence thrusting and the front of the prism grows through landward-verging thrusting. The décollement is sub-horizontal and deep, involving most of the sediment over the oceanic crust in the accretionary process, building a comparatively wide and thicker prism. A Bottom Simulating Reflector is present across the whole prism to the abyssal plan, suggesting the presence of gas in the sediments.The analysis of P- and S-wave velocity reflectivity sections, derived by amplitude versus offset technique (AVO), detailed velocity information and the velocity-derived sediment porosity have been integrated with the structural analysis of the accretionary prism of two selected pre-stack depth migrated seismic lines, aiming to explain the relation between fluid circulation and tectonics.Accretion along double vergence thrust faults may be associated with the presence of overpressured fluid, which decreases the effective shear stress coefficient along the main décollement and within the sediments, and modify the rheolgical properties of rocks. The presence of an adequate drainage network, represented by interconnected faults and fractures affecting the entire sedimentary sequence, can favour the escape of pore fluid toward the sea bottom, while, less permeable and not faulted sediments can favour fluid accumulations. Gravitational and tectonic dewatering, and stratigraphy could control the consolidation and the pore overpressure of sediments involved in subduction along the trench. The results of our analysis suggest the existence of a feedback between tectonic style and fluid circulation.     

Analyses of bottom simulating reflections offshore Arauco and Coyhaique (Chile)

Two seismic sections offshore Arauco and Coyhaique, Chile, have been analysed to better define the seismic character of hydrate-bearing sediments. The velocity analysis was used to estimate the gas-phase concentration, which can serve to correlate hydrate presence to the geological features. The velocity model allowed us to recognise the hydrate layer above the bottom simulating reflector (BSR), and the free gas layer below it. The velocity field is affected by strong lateral variation, showing maximum (above the BSR) and minimum (below the BSR) values in the southern sector. Here, highest gas hydrate and free gas concentrations were calculated (15% and 2.7% of total volume respectively). The estimated geothermal gradient ranges from 35 to 95°C/km. In the northern sector, the highest gas hydrate and free gas concentrations are 15% and 0.2% of total volume respectively, and the geothermal gradient is uniform and equal to about 30°C/km.     

An upwelling filament off southwest Iberia: Effect on the chlorophyll a and nutrient export

The present paper describes the chemical and biological characteristics of an upwelling filament off southern Iberia in October 2004, based on a total of 42 CTD casts, along with ADCP velocity measurements distributed by an almost regular grid of 15 km mean spacing. Stations were sampled from the surface to a maximum depth of 400 dbar, for nutrients (nitrate, phosphate and silicate) and chlorophyll a determination. The effect of cross-shelf exchange of nutrients and chlorophyll a between the coastal and oceanic waters was also investigated. Data revealed that, during the cruise conducted under relaxed winds, a relatively small filament was formed down to 75 m. However, an amount of 180 t of chlorophyll a was estimated there accompanied by low nutrient concentrations. The observed water properties reveal that SW Iberia is similar to NW Iberia, showing the continuity of the Canary Upwelling System along the Iberian Peninsula, one of poorest upwelling systems of the oceanic eastern boundaries. Nevertheless, the amounts of chlorophyll and nutrients transported through the filament are significant, revealing that those play a key role in the seaward export of matter with an important impact on the regional oceanography of this region. Considering the periods of strong upwelling events and the extent of their duration along the year, the amounts of exported matter must be hugely increased and responsible for the high productivity of these waters.     

Coastal and inland karst morphologies driven by sea level stands: a GIS based method for their evaluation

Sea level is the base level for groundwater circulation in coastal aquifers. The evolution of karst surface landforms and subsurface drainage systems in these aquifers has been conditioned in geological time by tectonics and glacio‐eustatic sea‐level changes. Present morpho‐structural settings and the type/distribution of karst surface and subsurface forms have developed in different carbonate formations according to differences in lithology, climate and exposure time, all driving the intensity of morphologic and karst processes. The repeated and significant changes of groundwater level linked to ‘sea‐level changes’ have had the most important role in driving the continuous evolution of karstic drainage systems, and has resulted in most cases in a multiphase karst. This study aims at defining a general method for identifying, in karst coastal settings, the elevations of flat or low topographic gradient surfaces (using morphometric analysis of Digital Elevation Models (DEMs) and geographical information systems (GISs), and their comparison with elevations of distinctive karstic levels (passages, lateral solution cavities) observed in vertical shafts and horizontal caves. Of the elevations of flat or low topographic gradient surfaces only those agreeing, within ±10 m or ±20 m, with elevation ranges marked by the high frequency of distinctive karst levels were considered as representative of the more probable past sea‐level stands. The method is applied to a regional coastal carbonate formation in southern Italy, by using a 10 m DEM and information on 140 complex caves and 85 shafts. Of the 15 elevations indicated by DEM analysis [620, 600, 470, 450, 425, 385, 355, 315, 270, 250, 205, 180, 150, 110, and 70 m above sea level (a.s.l.)], 13 match clearly those highlighted by significant frequencies of distinctive karstic levels. These elevations are validated by comparison to the elevation of terraces and karst plains indicated in the literature. Copyright © 2012 John Wiley & Sons, Ltd.     

Ultraviolet SN observations with Swift

Ultraviolet (UV) data are powerful tools to understand supernovae (SNe). Currently, the Swift satellite is the best suited telescope available for SN UV studies, due to its photometric and spectroscopic capabilities and its fast response. We present recent results obtained with the Swift SN program, demonstrating the importance of the UV emission, which provides fundamental information about SN explosion mechanism, its environment and progenitor structure.     

Organic pollutants (PAHs, PCBs) in sediments from the Mar Piccolo in Taranto (Ionian Sea, Southern Italy)

Polychlorinated biphenyls (PCBs) and 17 parent polycyclic aromatic hydrocarbons (PAHs) were determined in surface sediments from nine stations in the Mar Piccolo of Taranto (Ionian Sea, Southern Italy). Total PAH concentrations ranged from 380 to 12,750 microg/kg d.w., while total PCB levels ranged from 2 to 1684 microg/kg d.w.; this values were higher than those found in others marine coastal areas of the Mediterranean Sea. For PAHs, low molecular weight/high molecular weight, phenanthrene/anthracene and fluoranthene/pyrene ratio were used for discriminating between pyrolitic and petroleum origin. Results showed that PAHs were mainly of pyrolitic origin. PCB and PAH levels in sediments were compared with Sediments Quality Guidelines (ERM-ERL, TEL-PEL indexes) for evaluation probable toxic effects on marine organism. Finally, ERM and PEL quotients were used to evaluate the degree to which chemicals exceed guidelines. Results suggest an ecotoxicological risk for benthic organisms mainly in the first inlet, where high concentrations of PCBs were found in sediments influenced by harbour activities.