Recognizable primary volcanic and sedimentary features in a low-strain domain of the highly deformed, oldest known (≈ 3.7–3.8 Gyr) Greenstone Belt, Isua, West Greenland

A low-strain domain has been identified in the metamorphosed, mostly highly deformed volcanic and sedimentary rocks of the early Archaean Isua supracrustal belt. This domain contains well-preserved volcanic and sedimentary features, including basaltic pillow lavas, pillow breccia, heterogeneous volcanic breccia, amygdules in metabasalt, and polymict conglomerate dominated by recrystallized chert and volcanic clasts. The low-strain domain is bounded by highly deformed rocks mostly derived from basalt, chert, and banded iron formation. These discoveries demonstrate that some primary features have escaped the pervasive metasomatism dominant in other parts of the belt and, furthermore, strengthen the characterization of the Isua supracrustals as a typical greenstone belt.     

Provenance ages and alteration histories of shales from the Middle Archean Buhwa greenstone belt, Zimbabwe: Nd and Pb isotopic evidence

Shales of the ca. 3.0 Ga Buhwa Greenstone Belt, Zimbabwe, were derived from a compositionally diverse provenance whose ages, determined by ion probe analyses of detrital zircons in interbedded sandstones, range from 3.8 to 3.1 Ga. Geochemical data for the shales were previously interpreted to indicate that sediments had been derived from an intensely weathered source. REE concentrations in the shales were interpreted to suggest that the provenance was compositionally mixed, with components of felsic (tonalite and alkalic granitoid) and mafic rocks. Sm/Nd and Nd isotopic compositions of these rocks can be used to model initial Nd isotopic ratios at the time of sedimentation (ε_Ndsed), as well as model crustal formation ages (T_DM). The former, at the age of sedimentation, range from +0.6 to −10.8, consistent with a range of provenance ages. The latter range from 4.46 Ga to 2.99 Ga. The oldest crustal formation ages, up to 0.7 Ga older than known detrital components, are interpreted here to indicate that the Sm-Nd system of the sediments experienced open system behavior. The implied alteration would have included an increase in Sm/Nd by about 20-25 percent, probably in the form of preferential loss of Nd with respect to Sm. The Pb isotopic compositions of whole rock samples are quite radiogenic, with a range of ²⁰⁶Pb/²⁰⁴Pb from 25.5 to 154. An array of ten samples lies scattered about a line with a ²⁰⁷Pb/²⁰⁴Pb -²⁰⁶Pb/²⁰⁴Pb slope age of about 2.73 Ga. Five individual samples were sequentially leached to further test the timing and characteristics of this U-Th-Pb alteration event. These arrays of a whole rock, three leach steps, and a residue also form linear Pb-Pb arrays (one is more scattered) with ages ranging from 2260 ± 360 Ma to 2824 ± 170 Ma, suggesting that all samples experienced a latest Archean to earliest Proterozoic enrichment in U/Pb. This age range also may be the approximate age of Sm/Nd enrichment for the shales. All samples, both whole rocks and leached samples, lie grouped on a ²⁰⁸Pb/²⁰⁴Pb - ²⁰⁶Pb/²⁰⁴Pb diagram around a line with ²³²Th/²³⁸U = 3.5 (2.9 to 3.9). Because of the lack of large differences in the Th/U of the samples through large ranges of U/Pb, we interpret this consistency in Th/U to mean that the shales of the Buhwa belt experienced Pb loss, rather than U and Th gain. Circumstances that may be responsible for Pb loss in a sedimentary basin include loss of saline fluids during basin dewatering. Such an event would likely have been related to folding associated with the thrusting and magmatic intrusion of the adjacent Limpopo Belt, suggesting that uplift, dewatering, and geochemical and isotopic alteration can be genetically related.     

Characterisation of early Archaean chemical sediments by trace element signatures

Rare earth element (REE) plus yttrium (Y) patterns of modern seawater have characteristic features that can be used as chemical fingerprints. Reliable proxies for marine REE+Y chemistry have been demonstrated from a large geological time span, including Archaean banded iron formation (BIF), stromatolitic limestone, Phanerozoic reef carbonate and Holocene microbialite.Here we present new REE+Y data for two distinct suites of early Archaean (ca. 3.7-3.8 Ga) metamorphosed rocks from southern West Greenland, whose interrelationships, if any, have been much debated in recent literature. The first suite comprises magnetite-quartz BIF, magnetite-carbonate BIF and banded magnetite-rich quartz rock, mostly from the Isua Greenstone Belt (IGB). The REE+Y patterns, particularly diagnostic anomalies (Ce/Ce*, Pr/Pr*), are closely related to those of published seawater proxies. The second suite includes banded quartz-pyroxene-amphibole±garnet rocks with minor magnetite from the so-called Akilia Association enclaves (in early Archaean granitoid gneisses) of the coastal region, some 150 km southwest of the IGB. Rocks of this type from one much publicised and highly debated locality (the island of Akilia) have been identified by some workers [Nature 384 (1996) 55; Geochim. Cosmochim. Acta 61 (1997) 2475] as BIF-facies, and their ¹³C-depleted signature in trace graphite interpreted as a proxy for earliest life on Earth. However, REE+Y patterns of the Akilia Association suite (except for one probably genuine magnetite-rich BIF from Ugpik) are inconsistent with a seawater origin. We agree with published geological and geochemical (including REE) work [Science 296 (2002) 1448] that most of the analysed Akilia rocks are not chemical sediments, and that C-isotopes in such rocks therefore cannot be used as biological proxies.Application of the REE+Y discriminant for the above two rock suites has been facilitated in this study by the use of MC-ICP technique which yields a more complete and precise REE+Y spectrum than was available in many previous studies.     

Micro‐scale silicon isotope heterogeneity observed in hydrothermal quartz precipitates from the >3.7 Ga Isua Greenstone Belt,SW Greenland

Pillow basalt and chert form integral lithologies comprising many Archean greenstone belt packages. To investigate details of these lithologies in the >3.7 Ga Isua Greenstone Belt, SW Greenland, we measured silicon isotope compositions of quartz crystals, by secondary ion mass spectrometry, from a quartz‐cemented, quartz‐amygdaloidal basaltic pillow breccia, recrystallized chert and chert clasts thought to represent silica precipitation under hydrothermal conditions. The recrystallized chert, chert clasts and quartz cement have overlapping δ³⁰Si values, while the δ³⁰Si values of the quartz amygdules span nearly the entire range of previously published values for quartz precipitates of any age, despite amphibolite facies metamorphism. We suggest that the heterogeneity is derived from kinetic isotope fractionation during quartz precipitation under disequilibrium conditions in a hydrothermal setting, consistent with the pillow breccia origin. On the basis of the present data, we conclude that the geological context of each sample must be carefully evaluated when interpreting δ³⁰Si values of quartz.     

Architecture of a distal pre-vegetation braidplain: Cambrian middle member of the Wood Canyon Formation,southern Marble Mountains,California, USA

Architectural element analysis and detailed mapping of a 300 m along-strike exposure of the middle member Wood Canyon Formation, southern Marble Mountains, California, USA, provides new evidence for extensive braided–fluvial channel-belt deposits with adjacent overbank environments. Three-dimensional models constructed using ‘Structure from Motion’ techniques, combined with field-based observations, allowed interpretation of outcrop-scale trends, barforms, channel fills and fine-scale features. The ca 80 m thick member is divisible into five distinct units, including units M1 to M3 that form the bulk of the stratigraphy. Units are defined by stacking patterns of three facies associations (Facies Association 1 to Facies Association 3), each representing the product of a subenvironment within the fluvial system. In Facies Association 1, stacked cosets, interpreted as low-relief fluvial bars and channel fills, preserve vertical-accretion and downstream-accretion elements under unimodal north-north-west palaeoflow, with minor lateral accretion near bar edges. Deposits of Facies Association 2 to Facies Association 3, linked to overbank environments, are found only in unit M2, in the middle 27 m of the middle member. Floodplains, represented by Facies Association 2, include crumbly red-orange intervals of fine to medium-grained sandstone and thinner sets of cross-bedding than Facies Association 1, interbedded with thicker cross-stratification indicative of overbank splay or overland flow aggradation from adjacent channel belts during flood stage. Possible aeolian beds of Facies Association 3 preserve broad festooned trough cross-strata that average 23 cm in thickness; their small size, medium-grained sandstone and iron oxide cement suggest a high water table. The diverse assemblage of interpreted subenvironments, paired with bedform and facies patterns, implies a perennial fluvial system that gradually built large sand bars as the channel belt migrated and avulsed across an unconfined braided–fluvial reach, leaving the overbank area on its flanks subject to weathering and aeolian transport. Despite the occurrence of strata deposited in low-energy and ponded settings, and a marine influence proposed for nearby sections of middle member, no ichnofossils were encountered.