Oil-weathering behavior in Arctic environments

Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup.     

The concentration and isotopic composition of carbon in basaltic glasses from the Juan de Fuca Ridge, Pacific Ocean

The abundance and 13C/12C ratios of carbon were analyzed in basaltic glass from twenty locations along the Juan de Fuca Ridge using a 3-step combustion/extraction technique. Carbon released during the first two combustion steps at 400-500 degrees C and 600-650 degrees C is interpreted to be secondary, and only the carbon recovered during a final combustion step at approximately 1200 degrees C is thought to be indigenous to the samples. For carbon released at approximately 1200 degrees C, glasses analyzed as 1-2 mm chips contained 23-146 ppm C with delta 13C values of -4.8 to -9.3%, whereas samples crushed to 38-63 microns or 63-90 microns yielded 56-103 ppm C with delta 13C values of -6.1 to -9.2%. The concentrations and isotopic compositions of the primary carbon dissolved in the glasses and present in the vesicles are similar to those previously reported for other ocean-ridge basalts. The Juan de Fuca basaltic magmas were not in equilibrium with respect to carbon when they erupted and quenched on the sea floor. Evidence of disequilibrium includes (1) a large range of carbon contents among glasses collected at similar depths, (2) a highly variable calculated carbon isotopic fractionation between melt and vapor determined by comparing crushed and uncrushed splits of the same sample, and (3) a lack of correlation between vesicle abundance, carbon concentration, and depth of eruption. Variations in carbon concentration and delta 13C ratios along the ridge do not correlate with major element chemistry. The observed relationship between carbon concentrations and delta 13C values may be explained by late-stage, variable degrees of open-system (Rayleigh-like) degassing.     

A search for ultra-high energy counterparts to gamma-ray bursts

A small air shower array operating over many years has been used to search for ultra-high energy (UHE) gamma radiation ( 50 TeV) associated with gamma-ray bursts (GRBs) detected by the BATSE instrument on the Compton Gamma-Ray Observatory (CGRO). Upper limits for a one minute interval after each burst are presented for seven GRBs located with zenith angles < 20°. A 4.3 excess over background was observed between 10 and 20 minutes following the onset of a GRB on 11 May 1991. The confidence level that this is due to a real effect and not a background fluctuation is 99.8%. If this effect is real then cosmological models are excluded for this burst because of absorption of UHE gamma rays by the intergalactic radiation fields.     

Experimental Melting of Cordierite Gneiss and the Petrogenesis of Syntranscurrent Peraluminous Granites in Southern Brazil

To understand the petrogenesis of peraluminous granites syntectonicto the Dorsal de Canguçu Transcurrent Shear Zone in theSul-rio-grandense Shield, Brazil, melting experiments were performedon one of the potential protoliths, a cordierite-bearing semi-peliticmetasedimentary gneiss (PE-1). Experiments were conducted atpressures of 5, 10 and 15 kbar, at temperatures of 700–900°C,and under fluid-absent and 5% H₂O-present conditions. The experimentsshow that fluid-absent melting begins at near-solidus conditions,around 700°C, promoted by participation of retrogressivephengitic muscovite in the reaction Mus + Kf ± Qz = melt± Fe–Ti oxide ± Als, producing a very smallamount of melt (<9%) with widely ranging composition. Allhypersolidus experiments (>800°C) produced S-type graniticmelts promoted by participation of biotite or cordierite inthe reactions Bio + Pl + Crd + Qz = Px + Fe–Ti oxide +melt at 5 kbar, and Bio + Pl + Crd ± Qz = Grt + Als ±Kf + melt at 10 and 15 kbar, both producing a high amount ofmelt (10–63% by volume). The melt compositions obtainedat 900°C and 15 kbar under fluid-absent conditions, promotedby biotite or cordierite breakdown, are similar to the syntectonicgranites. However, it is unlikely that the granites were formedat this pressure (corresponding to a depth of melting of     

The Space That Race Makes

This essay is a revision of a paper prepared for an NSF workshop on race and geography. Participants in the workshop were asked to offer their views on the topic and our suggestions for further research. This contribution explores some aspects of the relationship and relevance of geography to the question of race in North America. It touches on three “places” that constitute the discipline: the place of research, the place of teaching, and the workplace. With respect to research, it suggests some promising lines of inquiry. Among these are studies of the relationship of scale to the politics of identity and studies of “passing” in connection with studies of geographies of experience and geographies of power.     

HOLOCENE CARBONATE PRECIPITATES ON PRECAMBRIAN BEDROCK IN THE HIGH ARCTIC: AGE AND POTENTIAL FOR PALAEOCLIMATIC INFORMATION

ABSTRACT. Crusts of white carbonate precipitate occur commonly on the upper surfaces of glacially sculptured Precambrian granites and gneisses in east-central Ellesmere Island. Radiocarbon dating of 21 such carbonate precipitates, from elevations between 50 m and 1050 m a.s.l., has yielded only Holocene ages. Two samples from Ellesmere Island, plus one from Inglefield Land, Greenland, have calibrated ages over 5000 years, the rest are younger. The formation of these deposits, mainly calcite and characterized by unusually heavy δ¹³C ratios (+3.36 to +15.18‰), has apparently been aided in some cases by the presence of bacteria, and some crusts seem to have developed where Ca-bearing minerals are more prevalent. In the case of Bache Peninsula and Cape Herschel, where the carbonate crusts are particularly abundant, the presence of calcareous till may have played a role as well. The carbonate crusts may be related to the presence of small, thin carapace ice caps, when such features formed at lower elevations than those at which they exist today. The more extensive cover of ice and snow is postulated to have existed during the latter, cooler part of the Holocene, especially during the period from 2500 to 100 years ago, deduced as a period of low melt from ice core studies on the Agassiz Ice Cap, 200 km to the north. The existence of carapace ice caps at lower elevations also agrees with the radiocarbon evidence for outlet glacier advances during the last 2000 years on both east and west margins of the Prince of Wales Icefield. Alternatively, the white carbonate crusts may be, to a large degree, the result of weathering processes. In either case they provide minimum ages for the exposed, ice-sculptured rock surfaces on which they occur.     

Sublittoral seaweed communities on natural and artificial substrata in a high-latitude coral community in South Africa

Coral mortality may result in macroalgal proliferation or a phase shift into an alga-dominated state. Subtidal, high-latitude western Indian Ocean coral communities at Sodwana Bay on the KwaZulu-Natal coast, South Africa, have experienced some mortality because of warm-water anomalies, storms and other causes, but the response of the macroalgae is unknown. We investigated the abundance and diversity of benthic algae on different hard natural substrata (dead digitate, brain and plate corals and beach rock) on Two-Mile Reef, Sodwana Bay. We also compared algal communities colonising ceramic, marble and pretreated ceramic tiles placed on the reef for six months. We identified 95 algae (14 Chlorophyta, 11 Phaeophyceae, 69 Rhodophyta and one cyanobacterium). Assemblages on natural and artificial substrata were dominated by the brown alga Lobophora variegata (Lamouroux) Womersley ex Oliveira and non-geniculate corallines (Rhodophyta, Corallinaceae). Cluster and ordination analyses revealed that the algae showed no affinity for particular substrata, whether natural or artificial. Algal cover was occasionally higher on rougher tiles and crustose corallines were significantly more abundant on marble than ceramic tiles. Two-Mile Reef had 23.1% dead and 48.4% live scleractinian coral cover, where dead corals were colonised indiscriminately by many small algal species, but there was no evidence of algal proliferation. The results provide a baseline for monitoring this high-latitude reef system.     

Effects of winter atmospheric circulation on temporal and spatial variability in annual streamflow in the western United States

Abstract

Winter mean 700-hectoPascal (hPa) height anomalies, representing the average atmospheric circulation during the snow season, are compared with annual streamflow measured at 140 streamgauges in the western United States. Correlation and anomaly pattern analyses are used to identify relationships between winter mean atmospheric circulation and temporal and spatial variability in annual streamflow. Results indicate that variability in winter mean 700-Hpa height anomalies accounts for a statistically significant portion of the temporal variability in annual streamflow in the western United States. In general, above-average annual streamflow is associated with negative winter mean 700-Hpa height anomalies over the eastern North Pacific Ocean and/or the western United States. The anomalies produce an anomalous flow of moist air from the eastern North Pacific Ocean into the western United States that increases winter precipitation and snowpack accumulations, and subsequently streamflow. Winter mean 700-hPa height anomalies also account for statistically significant differences in spatial distributions of annual streamflow. As part of this study, winter mean atmospheric circulation patterns for the 40 years analysed were classified into five winter mean 700-hPa height anomaly patterns. These patterns are related to statistically significant and physically meaningful differences in spatial distributions of annual streamflow.     

Volume of magma accumulation or withdrawal estimated from surface uplift or subsidence,with application to the 1960 collapse of Kilauea volcano

An elastic point source model proposed by Mogi for magma chamber inflation and deflation has been applied to geodetic data collected at many volcanoes. The volume of ground surface uplift or subsidence estimated from this model is closely related to the volume of magma injection into or withdrawal from the reservoir below. The analytical expressions for these volumes are reviewed for a spherical chamber and it is shown that they differ by the factor 2(1-v), where v is Poisson's ratio of the host rock. For the common estimate v=0.25, as used by Mogi and subsequent workers, the uplift volume is 3/2 the injection volume. For highly fractured rocks, v can be even less and the uplift volume can approach twice the injection volume. Unfortunately, there is no single relation between the inflation of magma reservoirs and the dilation or contraction of host rocks. The inflation of sill-like bodies, for instance, generates no overall change in host rock volume. Inflation of dike-like bodies generates contraction such that, in contrast with Mogi's result, the uplift volume is generally less than the injection volume; for v=0.25, the former is only 3/4 of the latter. Estimates of volumes of magma injection or withdrawal are there-fore greatly dependent on the magma reservoir configuration. Ground surface tilt data collected during the 1960 collapse of Kilauea crater, one of the first events interpreted with Mogi's model and one of the largest collapses measured at Kilauea, is not favored by any one of a variety of deformation models. These models, however, predict substantially different volumes of both magma withdrawal and ground surface subsidence.     

Lake Hoare, Antarctica: sedimentation through a thick perennial ice cover

Lake Hoare in the Dry Valleys of Antarctica is covered with a perennial ice cover more than 3 m thick, yet there is a complex record of sedimentation and of growth of microbial mats on the lake bottom. Rough topography on the ice covering the lake surface traps sand that is transported by the wind. In late summer, vertical conduits form by melting and fracturing, making the ice permeable to both liquid water and gases. Cross-sections of the ice cover show that sand is able to penetrate into and apparently through it by descending through these conduits. This is the primary sedimentation mechanism in the lake. Sediment traps retrieved from the lake bottom indicate that rates of deposition can vary by large amounts over lateral scales as small as 1 m. This conclusion is supported by cores taken in a 3 × 3 grid with a spacing of 1.5 m. Despite the close spacing of the cores, the poor stratigraphic correlation that is observed indicates substantial lateral variability in sedimentation rate. Apparently, sand descends into the lake from discrete, highly localized sources in the ice that may in some cases deposit a large amount of sand into the lake in a very short time. In some locations on the lake bottom, distinctive sand mounds have been formed by this process. They are primary sedimentary structures and appear unique to the perennially ice-covered lacustrine environment. In some locations they are tens of centimetres high and gently rounded with stable slopes; in others they reach ～ 1 m in height and have a conical shape with slopes at angle of repose. A simple formation model suggests that these differences can be explained by local variations in water depth and sedimentation rate. Rapid colonization and stabilization of fresh sand surfaces by microbial mats composed of cyanobacteria, eukaryotic algae, and heterotrophic bacteria produces a complex intercalation of organic and sandy layers that are a distinctive form of modern stromatolites.