Biological and granulometric controls on sedimentary organic matter of an intertidal mudflat

A variety of measures of organic matter concentration and quality were made on samples collected from the top few mm of intertidal mudflat sediment over the course of a year, in order to assess the relative importance of biological and sedimentological influences on sedimentary organic matter. Winter and summer were times of relatively fine-grained sediment accumulation, caused by biological deposition or stabilization processes and resulting in higher organic matter concentrations. Stable carbon isotope and Br:C ratios indicated a planktonic source of bulk organic matter. Ratios of organic carbon to specific surface area of the sediments were consistent with an organic monolayer coverage of sediment grains. Correction for changing grain size during the year showed no change in the organic concentration per unit surface area, in spite of organic matter inputs by in situ primary production, buildup of heterotroph biomass and mucus coatings, and biodeposition of organic-rich seston. There were also no indications of changes in bulk organic quality, measured as hydrolyzable carbohydrates and amino acids, in response to these biological processes. It is concluded that biological processes on a seasonal time scale affect the bulk organic matter of these sediments via a modulation of grain size rather than creation or decay of organic matter.     

Postglacial vegetation and climate dynamics in the Seymour‐Belize Inlet Complex,central coastal British Columbia,Canada: palynological evidence from Tiny Lake

A pollen‐based study from Tiny Lake in the Seymour‐Belize Inlet Complex of central coastal British Columbia, Canada, permits an evaluation of the dynamic response of coastal temperate rainforests to postglacial climate change. Open Pinus parklands grew at the site during the early Lateglacial when the climate was cool and dry, but more humid conditions in the later phases of the Lateglacial permitted mesophytic conifers to colonise the region. Early Holocene conditions were warmer than present and a successional mosaic of Tsuga heterophylla and Alnus occurred at Tiny Lake. Climate cooling and moistening at 8740 ± 70 ¹⁴C a BP initiated the development of closed, late successional T. heterophylla–Cupressaceae forests, which achieved modern character after 6860 ± 50 ¹⁴C a BP, when a temperate and very wet climate became established. The onset of early Holocene climate cooling and moistening at Tiny Lake may have preceded change at more southern locations, including within the Seymour‐Belize Inlet Complex, on a meso‐ to synoptic scale. This would suggest that an early Holocene intensification of the Aleutian Low pressure system was an important influence on forest dynamics in the Seymour‐Belize Inlet Complex and that the study region was located near the southern extent of immediate influence of this semi‐permanent air mass. Copyright © 2008 John Wiley & Sons, Ltd.     

Potential of the VLTI for linking stellar frames to ICRF

The question of positioning the optical counterparts of the ICRF quasars is outlined in the perspective of future space astrometry missions, which ultimately will bring a new realization of the ICRS in the optical range. Ground-based interferometry with a dual-field observing mode (PRIMA/VLTI),together with the missions DIVA and FAME, will have a key role in building an extragalactic reference frame in the optical/near-IR range with about the same accuracy as that of the present (VLBI) primary frame. This revised version was published online in July 2006 with corrections to the Cover Date.     

Transforming observational data and theoretical isochrones into the ACS/WFC Vega-mag system

We propose a zero-point photometric calibration of the data from the Advanced Camera for Surveys (ACS) Wide Field Channel (WFC) on board the Hubble Space Telescope , based on a spectrum of Vega and the most up-to-date in-flight transmission curves of the camera. This calibration is accurate at the level of a few hundredths of a magnitude. The main purpose of this effort is to transform the entire set of evolutionary models into a simple observational photometric system for ACS/WFC data, and to make them available to the astronomical community. We provide the zero-points for the most used ACS/WFC bands, and give basic recipes for calibrating both the observed data and the models. We also present the colour–magnitude diagram from ACS data of five Galactic globular clusters, spanning the metallicity range  −2.2 <[Fe/H] < −0.04  , and we provide fiducial points representing their sequences from several magnitudes below the turn-off to the red giant branch tip. The observed sequences are compared with the models in the newly defined photometric system.     

Interpretation of transient electromagnetic soundings over three-dimensional structures for the central-loop configuration

Summary. An assessment is made of the bias of fitting constrained layered-earth models to transient electromagnetic data obtained over 3-D structures. In this assessment we use the central-loop configuration and show that accurate estimates of the depth of burial of 3-D structures can be obtained with layered-earth model fitting. However, layered-earth interpretations are not reliable for estimating depth extents and resistivities of 3-D structures. When layered earths are used for interpretation, it is advantageous in some cases to use data based on the magnetic field instead of the voltage. A magnetic-field definition of apparent resistivity, in contrast to a definition based on the voltage, eliminates apparent-resistivity overshoots and undershoots in the data. A resistivity undershoot in the data can produce an extraneous and misleading layer in an interpretation of a 3-D resistive structure. Due to 3-D effects, apparent-resistivity soundings (magnetic field and voltage) may rise so steeply at late times that it may not be possible to fit a sounding to a reasonable layered-earth model. Truncating such a sounding, over a buried conductor, allows for a reasonable layered-earth fit and an accurate estimate of the depth to the conductor. However, the resistivity of the conductor is overestimated.
Measurements of the horizontal field in the central-loop configuration can map 3-D structures, provided the sensor is located accurately at the centre of the transmitting loop. Horizontal-field calculations show that the transients peak on the flanks of a 3-D structure, but are depressed over the structure's centre. Weak transient responses flanked by two large transient responses, which are opposite in sign, locate the structure. The sign reversal is caused by a corresponding reversal in the currents that are channelled through or deflected away from conductive or resistive structures, respectively.     

The Mordor Alkaline Igneous Complex,Central Australia: PGE-enriched disseminated sulfide layers in cumulates from a lamprophyric magma

The Mordor Alkaline Igneous Complex (MAIC) is a composite intrusion comprising a body of syenite and a funnel-shaped layered mafic–ultramafic intrusion of lamprophyric parentage, the Mordor Mafic–Ultramafic Intrusion or MMUI. The MMUI is highly unusual among intrusions of lamprophyric or potassic parentage in containing primary magmatic platinum-group element (PGE)-enriched sulfides. The MMUI sequence consists largely of phlogopite-rich pyroxenitic cumulates, with an inward dipping conformable layer of olivine-bearing cumulates divisible into a number of cyclic units. Stratiform-disseminated sulfide accumulations are of two types: disseminated layers at the base of cyclic units, with relatively high PGE tenors; and patchy PGE-poor disseminations within magnetite-bearing upper parts of cyclic units. Sulfide-enriched layers at cycle bases contain anomalous platinum group element contents with grades up to 1.5 g/t Pt+Pd+Au over 1-m intervals, returning to background values of low parts per billion (ppb) on a meter scale. They correspond to reversals in normal fractionation trends and are interpreted as the result of new magma influxes into a continuously replenished magma chamber. Basal layers have decoupled Cu and PGE peaks reflecting increasing PGE tenors up-section, due to increasing R factors during the replenishment episode, or progressive mixing of between resident PGE-poor magma and more PGE-enriched replenishing magma. The presence of PGE enriched sulfides in cumulates from a lamprophyric magma implies that low-degree partial melts do not necessarily leave sulfides and PGEs in the mantle restite during partial melting. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Development of the mixed conifer forest in northern New Mexico and its relationship to Holocene environmental change

Chihuahueños Bog (2925 m) in the Jemez Mountains of northern New Mexico contains one of the few records of late-glacial and postglacial development of the mixed conifer forest in southwestern North America. The Chihuahueños Bog record extends to over 15,000 cal yr BP. An Artemisia steppe, then an open Picea woodland grew around a small pond until ca. 11,700 cal yr BP when Pinus ponderosa became established. C/N ratios, δ¹³C and δ¹⁵N values indicate both terrestrial and aquatic organic matter was incorporated into the sediment. Higher percentages of aquatic algae and elevated C/N ratios indicate higher lake levels at the opening of the Holocene, but a wetland developed subsequently as climate warmed. From ca. 8500 to 6400 cal yr BP the pond desiccated in what must have been the driest period of the Holocene there. C/N ratios declined to their lowest Holocene levels, indicating intense decomposition in the sediment. Wetter conditions returned after 6400 cal yr BP, with conversion of the site to a sedge bog as groundwater levels rose. Higher charcoal influx rates after 6400 cal yr BP probably result from greater biomass production rates. Only minor shifts in the overstory species occurred during the Holocene, suggesting that mixed conifer forest dominated throughout the record.     

An Atomic Force Microscopy study of the growth of calcite in the presence of sodium sulfate

In situ atomic force microscopy (AFM) has been used to compare the growth of pure calcite and the growth of calcite in the presence of sulfate ions from aqueous solutions at a constant value of supersaturation (S.I. = 0.89) with respect to calcite. The effect of sulfate ions on calcite growth rates is determined and a potential incorporation of sulfate ions is identified in the calcite during growth. Solutions supersaturated with respect to calcite with solution concentration ratio of one and a constant pH of 10.2, were prepared and sulfate was added as Na₂SO₄ aqueous solution. The solution composition was readjusted in order to keep the supersaturation and pH constant. PHREEQC was used to determine relevant solution concentrations. In situ AFM experiments of calcite growth were performed using a fluid cell and flowing solutions passed over a freshly cleaved calcite surface. Growth rates were determined from the closure of the rhombohedral etch pits induced by initial dissolution with pure water. The spreading rate of 2-dimensional nuclei was also measured. At low concentrations of sulfate (≤ 0.5 mM), no effect on the growth rate of the calcite was observed. At higher concentrations (2 to 3 mM) of sulfate, the growth rate increased, possibly because a higher concentration of calcium and carbonate was necessary to maintain the supersaturation constant. At much higher concentrations of additional sulfate (up to 60 mM) the growth rate of the calcite was substantially decreased, despite the fact that a further increase of calcium and carbonate was required. The morphology of 2-dimensional growth nuclei became increasingly elongated with increasing sulfate content. Measurements of step height showed that newly grown steps were approximately 1 Å higher when grown in high sulfate concentrations, compared to steps grown in sulfate-free solutions. At sulfate concentrations above 5 mM the growth mechanism changes from layer growth to surface roughening. These observations suggest that the new growth has incorporated sulfate into the calcite surface.