Solid bitumens: an assessment of their characteristics, genesis, and role in geological processes

Familiar since antiquity, and subject in contemporary times to various characterization schemes, the exact nature of solid bitumen is not yet fully known. Bitumens have ‘random polymer-like’ molecular structures, are mobile as highly viscous fluids or were once fluids but have since turned into solids. Solid bitumens consist mainly of large moieties, of polyclyclic aromatic hydrocarbons, occasionally with finely admixed, fine-grained cryptocrystalline graphite. Solid bitumens are distinguished from kerogen, which is the syngenetic and generally finely dispersed particulate organic matter in sedimentary rock that virtually does not migrate following its deposition. Occurrences of solid bitumens are relevant to petroleum exploration as well as the search for, and evaluation of, a variety of metallic mineral deposits. Genesis of bitumen is in many cases linked to the thermal and hydrothermal history of organic matter in sedimentary rock. Apparently bitumen, or more specifically organic acids generated along with bitumen during diagenesis, may alter porosity of reservoir rocks or otherwise prepare the ground for ore deposition. Bitumen is also relatively sensitive to alteration processes, some of which, such as oxidative weathering, water leaching, biodegradation (contact) metamorphism and ionizing radiation may likewise affect its nature. Elemental composition of bitumen commonly reflects the nature of mineral deposits. Is is possible that in petroleum exploration, trace metal abundances of bitumen may eventually allow prediction of crude oil types and volumes anticipated from a given source rock? Beside transition elements, notably Ni and V, highly anomalous concentrations of U, Pt and Au occur in some solid bitumens. During the generation of petroleum from kerogen, the trend in δ¹³C is toward lighter values. The opposite seems to occur when liquid petroleum is subjected to thermal cracking (and /or related processes) yielding solid bitumen enriched in ¹³C, and isotopically light methane. In fact, except for deasphalting and possibly some irradiation processes, the result of thermal cracking, oxidation, water leaching, inspissation (drying) and bacterial degradation of crude oil is that lower molecular weight hydrocarbons are removed leaving bitumen residues enriched in aromatic hydrocarbons, heteroatomic compounds (NSO) and ¹³C. Such phenomena are relevant to bitumen paragenesis in petroleum reservoir rocks, to certain Phanerozoic occurrences of multiple generations of bitumens, and to bitumens in mineral deposits.     

Core, Halo and Strahl Electrons in the Solar Wind

Electron velocity distribution functions (VDF) observed in the low speed solar wind flow are generally characterized by ‘core’ and ‘halo’ electrons. In the high speed solar wind, a third population of ‘strahl’ electrons is generally observed. New collisional models based on the solution of the Fokker-Planck equation can be used to determine the importance of the different electron populations as a function of the radial distance. Typical electron velocity distribution functions observed at 1 AU from the Sun are used as boundary conditions for the high speed solar wind and for the low speed solar wind. Taking into account the effects of external forces and Coulomb collisions with a background plasma, suprathermal tails are found to be present in the electron VDF at low altitudes in the corona when they exist at large radial distances. This revised version was published online in July 2006 with corrections to the Cover Date.     

The Yarkovsky effect as a heat engine

We show how the Yarkovsky effect can be understood as a heat engine. The output of the engine, manifested in the rate of change in semimajor axis of the body, has a maximum at an intermediate heat capacity, depending on the rotation rate of the body. This maximum arises because the work output depends on the product of the solar heat absorbed by the body and transported from its morning to evening side (this am-pm heat flux increases with heat capacity) and the Carnot efficiency (which declines with heat capacity).     

A stepwise method for determining the number of component distributions in a mixture

This paper considers the problem of estimatingm, the number of components in a finite mixture of distributions from a parametric family. A step-up procedure using the bootstrap method is proposed. Some properties of the procedure are illustrated with simulation studies. An example of the method, applied to orientation of beach clasts, is given.     

Photometry of rough planetary surfaces: The role of multiple scattering

Topographic features affect the scattering properties of planetary surfaces by casting shadows and altering the local incidence and emission angles. Measurements of this phenomenon were obtained on the Cornell goniometer for both high and low albedo surfaces. For the low albedo surface, the decrease in reflected radiation due to topography increases sharply with increasing phase angle, whereas for the high albedo sample the effects are approximately constant between phase angles of 30 and 70°. The observations are in good agreement with a theoretical model in the case of the dark surface. However, for the high albedo surface the model overestimates the effects by about a factor of 2, since it does not include the partial illumination of shadows by multiple scattering. For both high and low albedo surfaces, the effects of topography do not become significant until a phase angle of 30–40°.     

Resonant behaviour of MHD waves on magnetic flux tubes

Resonant absorption of MHD waves on a nonuniform flux tube is investigated as a driven problem for a 1D cylindrical equilibrium. The variation of the fractional absorption is studied as a function of the frequency and its relation to the eigenvalue problem of the MHD radiating eigenmodes of the nonuniform flux tube is established. The optimal frequencies producing maximal fractional absorption are determined and the condition for total absorption is obtained. This condition defines an impedance matching and is fulfilled for an equilibrium that is fine tuned with respect to the incoming wave. The variation of the spatial wave solutions with respect to the frequency is explained as due to the variation of the real and imaginary parts of the dispersion relation of the MHD radiating eigenmodes with respect to the real driving frequency.