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A.J. Walsh F. Bertoldi M.G. Burton T. Nikola 《Monthly notices of the Royal Astronomical Society》2001,326(1):36-56
N -band (10.5 μm) and/or Q -band (20.0 μm) images taken with MANIAC on the ESO/MPI 2.2-m telescope are presented for 31 methanol maser sites and 19 ultracompact (UC) H ii regions. Most of the maser sites and UC H ii regions are coincident with mid-infrared (MIR) sources to within the positional uncertainties of ∼ 3 arcsec, consistent with the maser emission being powered by the MIR source. The IRAS source positions, however, do not always coincide with the MIR sources.
Based on an average infrared spectral energy distribution, we deduce that the MIR objects are luminous enough that they should also produce a strong ionizing radiation. Some sources are consistent with stars of later spectral type, but not all can be. A number of maser sites show no detectable radio continuum emission associated with MIR emission, despite a powering source luminous enough potentially to produce an UC H ii region. Since no signs of an UC H ii region are detected here, these maser sites might be produced during a very early stage of stellar evolution.
We present objects that show evidence of outflow activity stemming from a maser site, exhibiting CO and/or CS line profiles indicative of outflows coincident with the MIR source. These cases are promising examples of maser sites signposting the earliest stages of high-mass star formation. 相似文献
Based on an average infrared spectral energy distribution, we deduce that the MIR objects are luminous enough that they should also produce a strong ionizing radiation. Some sources are consistent with stars of later spectral type, but not all can be. A number of maser sites show no detectable radio continuum emission associated with MIR emission, despite a powering source luminous enough potentially to produce an UC H ii region. Since no signs of an UC H ii region are detected here, these maser sites might be produced during a very early stage of stellar evolution.
We present objects that show evidence of outflow activity stemming from a maser site, exhibiting CO and/or CS line profiles indicative of outflows coincident with the MIR source. These cases are promising examples of maser sites signposting the earliest stages of high-mass star formation. 相似文献
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Eloïse Gaillou Aurlien Delaunay Benjamin Rondeau Martine Bouhnik-le-Coz Emmanuel Fritsch Guy Cornen Christophe Monnier 《Ore Geology Reviews》2008,34(1-2):113
Seventy-seven gem opals from ten countries were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) through a dilution process, in order to establish the nature of the impurities. The results are correlated to the mode of formation and physical properties and are instrumental in establishing the geographical origin of a gem opal. The geochemistry of an opal is shown to be dependant mostly on the host rock, at least for examples from Mexico and Brazil, even if modified by weathering processes. In order of decreasing concentration, the main impurities present are Al, Ca, Fe, K, Na, and Mg (more than 500 ppm). Other noticeable elements in lesser amounts are Ba, followed by Zr, Sr, Rb, U, and Pb. For the first time, geochemistry helps to discriminate some varieties of opals. The Ba content, as well as the chondrite-normalized REE pattern, are the keys to separating sedimentary opals (Ba > 110 ppm, Eu and Ce anomalies) from volcanic opals (Ba < 110 ppm, no Eu or Ce anomaly). The Ca content, and to a lesser extent that of Mg, Al, K and Nb, helps to distinguish gem opals from different volcanic environments. The limited range of concentrations for all elements in precious (play-of-color) compared to common opals, indicates that this variety must have very specific, or more restricted, conditions of formation. We tentatively interpreted the presence of impurities in terms of crystallochemistry, even if opal is a poorly crystallized or amorphous material. The main replacement is the substitution of Si4+ by Al3+ and Fe3+. The induced charge imbalance is compensated chiefly by Ca2+, Mg2+, Mn2+, Ba2+, K+, and Na+. In terms of origin of color, greater concentrations of iron induce darker colors (from yellow to “chocolate brown”). This element inhibits luminescence for concentrations above 1000 ppm, whereas already a low content in U (≤ 1 ppm) induces a green luminescence. 相似文献
6.
Javiera Cervini-Silva Benjamin Gilbert Sirine Fakra Stephan Friedlich Jillian Banfield 《Geochimica et cosmochimica acta》2008,72(10):2454-2464
Highly insoluble Ce-bearing phosphate minerals form by weathering of apatite [Ca5(PO4)3.(OH,F,Cl)], and are important phosphorous repositories in soils. Although these phases can be dissolved via biologically-mediated pathways, the dissolution mechanisms are poorly understood. In this paper we report spectroscopic evidence to support coupling of redox transformations of organic carbon and cerium during the reaction of rhabdophane (CePO4·H2O) and catechol, a ubiquitous biogenic compound, at pH 5. Results show that the oxic–anoxic conditions influence the mineral dissolution behavior. Under anoxic conditions, the release of P and Ce occurs stoichiometrically. In contrast, under oxic conditions, the mineral dissolution behavior is incongruent, with dissolving Ce3+ ions oxidizing to CeO2. Reaction product analysis shows the formation of CO2, polymeric C, and oxalate and malate. The presence of more complex forms of organic carbon was also confirmed. Near edge X-ray absorption fine structure spectroscopy measurements at Ce-M4,5 and C-K absorption edges on reacted CePO4·H2O samples in the absence or presence of catechol and dissolved oxygen confirm that (1) the mineral surface converts to the oxide during this reaction, while full oxidation is limited to the near-surface region only; (2) the Ce valence remains unchanged when the reaction between CePO4·H2O and O2 but in the absence of catechol. Carbon K-edge spectra acquired from rhabdophane reacted with catechol under oxic conditions show spectral features before and after reaction that are considerably different from catechol, indicating the formation of more complex organic molecules. Decreases in intensity of characteristic catechol peaks are accompanied by the appearance of new π* resonances due to carbon in carboxyl (ca. 288.5 eV) and carbonyl (ca. 289.3 eV) groups, and the development of broad structure in the σ* region characteristic of aliphatic carbon. Evolution of the C K-edge spectra is consistent with aromatic-ring cleavage and polymerization. These results further substantiate that the presence of catechol, O2 (aq) causes both the oxidation of structural Ce3+ and the transformation of catechol to more complex organic molecules. Scanning Transmission X-Ray Microscopy measurements at the C K and Ce M4,5 edges indicate three dominant organic species, varying in complexity and association with the inorganic phase. Untransformed catechol is loosely associated with CeO2, whereas more complex organic molecules that exhibit lower aromaticity and stronger CO π* resonances of carboxyl-C and carbonyl-C groups are only found in association with the grains. These results further serve as basis to postulate that, in the presence of O2, CeO2 can mediate the oxidative polymerization of catechol to form higher molecular weight polymers. The present work provides evidence for a pathway of biologically-induced, non-enzymatic oxidation of cerium and formation of small CeO2 particles at room temperature. These findings may have implications for carbon cycling in natural and cerium-contaminated soils and aqueous environments. 相似文献
7.
Daniel A. Deeds Martin K. Vollmer Justin T. Kulongoski Benjamin R. Miller 《Geochimica et cosmochimica acta》2008,72(4):999-1013
Dissolved tetrafluoromethane (CF4) and sulfur hexafluoride (SF6) concentrations were measured in groundwater samples from the Eastern Morongo Basin (EMB) and Mojave River Basin (MRB) located in the southern Mojave Desert, California. Both CF4 and SF6 are supersaturated with respect to equilibrium with the preindustrial atmosphere at the recharge temperatures and elevations of the Mojave Desert. These observations provide the first in situ evidence for a flux of CF4 from the lithosphere. A gradual basin-wide enhancement in dissolved CF4 and SF6 concentrations with groundwater age is consistent with release of these gases during weathering of the surrounding granitic alluvium. Dissolved CF4 and SF6 concentrations in these groundwaters also contain a deeper crustal component associated with a lithospheric flux entering the EMB and MRB through the underlying basement. The crustal flux of CF4, but not of SF6, is enhanced in the vicinity of local active fault systems due to release of crustal fluids during episodic fracture events driven by local tectonic activity. When fluxes of CF4 and SF6 into Mojave Desert groundwaters are extrapolated to the global scale they are consistent, within large uncertainties, with the fluxes required to sustain the preindustrial atmospheric abundances of CF4 and SF6. 相似文献
8.
Edward F. Roseman Christine A. Tomichek Tracy Maynard Jennifer A. Burton 《Journal of Sea Research》2005,53(4):309-318
Grubby (Myoxocephalus aenaeus, Cottidae) is a common benthic fish of inshore waters and estuaries of eastern Long Island Sound; however, little information exists on their life history or population demographics. This study utilised a long-term data series (1976–2002) to assess grubby life history and population demographics and explores trends in the Niantic River and Niantic Bay populations. In addition, we examined the age, size, and fecundity of adult grubby in 2001–02 to determine the population characteristics in the region. Mean grubby catch per unit effort (CPUE) in Niantic Bay ranged from 0.4 per trawl in 1976 to 2.9 per trawl in 1984 while river CPUE ranged from 0.4 per trawl in 1977 to 7.6 per trawl in 1989. Catch of grubby in bottom trawls varied seasonally with highest CPUE occurring in winter. Highest entrainment of grubby larvae occurred in 2001 while the lowest entrainment observed was in 1991. Four age classes, 0+ through III+, were derived from otolith analysis (N = 51) although length frequency analysis suggested the possibility of older fish in the population. The total number of eggs in ovaries ranged from 286 to 16 451 for grubby (N = 64) between 52 mm and 155 mm TL. Results of this study indicated a decline in abundance of adult grubby over the 26-year period, possibly related to concurrent declines in eelgrass (Zostera marina) abundance and/or increased water temperature. 相似文献
9.
Brian J. Bett M. Gabriella Malzone Bhavani E. Narayanaswamy Benjamin D. Wigham 《Progress in Oceanography》2001,50(1-4)
We report a ten-year study of the abundance and activity of megabenthos on the Porcupine Abyssal Plain, northeast Atlantic, together with observations on the occurrence of phytodetritus at the deep-sea floor (4850 m). Using the Southampton Oceanography Centre time-lapse camera system, ‘Bathysnap’, we have recorded a radical change in the abundance and activity of megabenthos between the two periods of study (1991–1994 and 1997–2000). In 1991–1994, the larger megabenthos occurred at an abundance of c. 71.6/ha and were dominated by large holothurians. In addition, there were very substantial populations of smaller megabenthic ophiuroids (c. 4979/ha). Together, the total megabenthos are estimated to track over some 17 cm2/m2/d (exploiting 100% of the surface of the seabed in c. 2.5 years). In 1997–2000, the larger megabenthos increased to an abundance of c. 204/ha and were joined by exceptional numbers of a small holothurian species (Amperima rosea, 6457/ha) and ophiuroids (principally Ophiocten hastatum, 53,539/ha). The total megabenthos population was tracking at an estimnated rate of c. 247 cm2/m2/d (exploiting 100% of seabed in just 6 weeks). Coincident with these increases in the abundance and activity of the megabenthos, there were apparently no mass depositions of aggregated phytodetritus to the seabed in the summers of 1997–1999. Mass occurrences of phytodetritus had been noted during the summer months of the three years previously studied (1991, 1993 and 1994), with covering between 50 and 96% of the sediment surface. There is a statistically significant (p<0.02) negative correlation between maximum extent of this seabed cover of phytodetritus and seabed tracking by megabenthos. Additional studies [Lampitt et al., Progr. Ocean. 50 (2001)], indicate that there were no substantial changes in surface ocean primary productivity, in export flux, or in the composition of the flux that might otherwise account for the apparent absence of observable concentrations of phytodetritus during the summers of 1997–1999. We postulate that the marked increase in megabenthic tracking activity resulted in the removal (via consumption, disaggregation, burial etc.) of the bulk of the incoming phytodetrital flux during these years. A simple conceptual model, based on the apparent phytodetrital fluxes observed in 1991 and 1993, suggests that the megabenthos tracking rates estimated for 1997–1999 are sufficient to account for near-total removal of this flux. However, we are not able to estimate other processes removing phytodetritus (i.e. other elements of the benthos) that may also have increased between 1991–1994 and 1997–1999. Other independent studies [e.g. Ginger et al., Progr. Ocean. 50 (2001)] of flux constituents support the possibility that just a few species of megabenthos (e.g. A. rosea, and O. hastatum) could well have consumed a major proportion of the incoming flux and so substantially modified the composition of the organic matter available to other components of the benthos. 相似文献
10.
Personal thermal insulation by means of neoprene from wet suits provides adequate temporary control of body heat loss only at the shallow end of the air diving depth range, but it constitutes by far the most popular approach to diver thermal support. Howewer, compression of the trapped gas phase in neoprene foam seriously reduces its insulation performance on exposure to high ambient pressure. With conventional wet suits equipped with heating, the necessary level of power required at depths greater than about 30 m is too high, and also unsafe without the back up that increased insulation would provide. One approach to the goal of depth-insensitive insulation is to use a wet suit with a continuous internal gas space pressurized nominally to ambient pressure, so that its thickness remains substantially constant at all depths. The composite material properties required are: outer skins that are tough, flexible and free of pin holes; an open foam internal structure capable of resisting, without significant dimensional change, the relatively small pressure changes that occur over the height of a man; and a high bond strength.Samples of a composite material that meets these requirements have been developed, and a prototype suit has been successfully fabricated by conventional techniques. 相似文献