Low‐energy helium ion irradiation‐induced amorphization and chemical changes in olivine: Insights for silicate dust evolution in the interstellar medium

Abstract— We present the results of irradiation experiments aimed at understanding the structural and chemical evolution of silicate grains in the interstellar medium. A series of He+ irradiation experiments have been performed on ultra‐thin olivine, (Mg,Fe)₂SiO₄, samples having a high surface/volume (S/V) ratio, comparable to the expected S/V ratio of interstellar dust. The energies and fluences of the helium ions used in this study have been chosen to simulate the irradiation of interstellar dust grains in supernovae shock waves. The samples were mainly studied using analytical transmission electron microscopy. Our results show that olivine is amorphized by low‐energy ion irradiation. Changes in composition are also observed. In particular, irradiation leads to a decrease of the atomic ratios O/Si and Mg/Si as determined by x‐ray photoelectron spectroscopy and by x‐ray energy dispersive spectroscopy. This chemical evolution is due to the differential sputtering of atoms near the surfaces. We also observe a reduction process resulting in the formation of metallic iron. The use of very thin samples emphasizes the role of surface/volume ratio and thus the importance of the particle size in the irradiation‐induced effects. These results allow us to account qualitatively for the observed properties of interstellar grains in different environments, that is, at different stages of their evolution: chemical and structural evolution in the interstellar medium, from olivine to pyroxene‐type and from crystalline to amorphous silicates, porosity of cometary grains as well as the formation of metallic inclusions in silicates.     

Petrography and textural development of inorganic and biogenic lithotypes in a relict barite tufa deposit at Flybye Springs, NT, Canada

A relict mound of Holocene barite (BaSO₄) tufa underlies the Flybye Springs, a small, barium‐rich, cold sulphur spring system in the Northwest Territories of Canada. The tufa is composed of relatively pure barite with ≤0·34 wt% Ca²⁺ and ≤0·77 wt% Sr²⁺. The mound is made up of coated bubble, raft, undulatory sheet, stromatolitic, coated grain and detrital conglomerate barite tufa. Although previously unreported in barite, these lithotypes are akin to facies found in many carbonate spring deposits. Raft and ooid‐coated grain tufa was formed via ‘inorganic’ barite precipitation in spring water ponds and tributaries where rapid oxidation of sulphide to sulphate established barite supersaturation. Undulatory sheet tufa may have formed by the reaction of dissolved barium with sulphate derived from the oxidation of extracellular polysaccharide‐rich colloidal sulphur films floating in oxygenated, barite‐saturated spring water ponds. Coated bubble, oncoid‐coated grain and stromatolitic tufa with filamentous microfossils was formed in close association with sulphur‐tolerant microbes inhabiting dysoxic and oxygenated spring water tributaries and ponds. Adsorption of dissolved barium to microbial extracellular polysaccharide probably facilitated the development of these ‘biogenic’ lithotypes. Detrital conglomerate tufa was formed by barite cementation of microdetrital tufa, allochthonous lithoclasts and organic detritus, including caribou hair. Biogenic textures, organic artefacts and microfossils in the Flybye barite tufa have survived diagenetic aggradational recrystallization and precipitation of secondary cements, indicating the potential for palaeoecological information to be preserved in barite in the geological record. Similarities between the Flybye barite tufa and carbonate spring deposits demonstrate that analogous textures can develop in chemical sedimentary systems with distinct mineralogy, biology and physiochemistry.     

Sequence stratigraphy of a Late Devonian ramp-situated reef system in the Western Canada Sedimentary Basin: dynamic responses to sea-level change and regressive reef development

The Alexandra Formation, located in the Northwest Territories of Canada, is formed of a Late Devonian (Frasnian) reef system that developed on a gently sloping, epicontinental ramp in the Western Canada Sedimentary Basin. High‐resolution sequence stratigraphic analysis of its deposits delineates two reef complexes that are separated by a Type I sequence boundary. The second reef complex developed on the outer ramp, basinward of the first, after sea‐level fell ≈17 m. Stratigraphic complexity of the second reef complex was a result of its initiation during forced regression, and its development through an entire cycle of sea‐level rise followed by sea‐level fall. Its highstand systems tract was not characterized by high rates of carbonate production or sediment shedding. Rather, these features took place as sea‐level fell, after its highstand systems tract. The sequence stratigraphic framework of this regressive reef system highlights a number of depositional parameters that differ from high‐relief, shelf‐situated reef systems with steep, narrow margins. These have implications for understanding the controls on the development of ramp‐situated reef systems, and the nature of reef systems with gently sloping profiles. This study demonstrates that the development of stromatoporoid reef systems may be far more complex than generally realized, and that high‐resolution sequence stratigraphy may provide the tools for better understanding of complex, often enigmatic, aspects of these systems.     

Transition and Diversity in Rural Housing Provision: The case of Narrogin,Western Australia

The purpose of this paper is to examine the changing dynamics of housing markets in an Australian rural community. With reference to the case of Narrogin, Western Australia, it argues that there is an increasing disjuncture between the social and demographic characteristics of rural residents and the modal form of housing in country towns, namely the detached family house. Factors contributing to this disjuncture include the ageing of the population, the loss of traditional blue-collar employment, sub-regional restructuring of service provision, retirement migration patterns, and growing acceptance of the particular housing needs of groups such as the aged, the disabled, young and indigenous people. While it is clear that there is currently something of a mismatch between the characteristics of the population and the housing stock in Narrogin, it is also evident that a combination of political, cultural and economic factors form a significant barrier to adjustment in the local housing market.     

Growth patterns and implications of complex dendrites in calcite travertines from Lýsuhóll, Snæfellsnes, Iceland

Calcite dendrite crystals are important but poorly understood components of calcite travertine that forms around many hot springs. The Lýsuhóll hot-spring deposits, located in western Iceland, are formed primarily of siliceous sinters that were precipitated around numerous springs that are now inactive. Calcite travertine formed around the vent and on the discharge apron of one of the springs at the northern edge of the area. The travertine is formed largely of two types (I and II) of complex calcite dendrite crystals, up to 1 cm high, that grew through the gradual addition of trilete sub-crystals. The morphology of the dendrite crystals was controlled by flow direction and the competition for growth space with neighbouring crystals. Densely crowded dendrites with limited branching characterize the rimstone dams whereas widely spaced dendrites with open branching are found in the pools. Many dendrite bushes in the pools nucleated around plant stems. Growth of the dendrite crystals was seasonal and incremental. Calcite precipitation was driven by rapid CO₂ degassing of CO₂-rich spring waters during the spring and summer. During winter, when snow covered the ground and temperatures were low, opal-A precipitated on the exposed surfaces of the dendrites. Segmentation of dendrite branches by discontinuities coated with opal-A and overgrowth development around sub-crystals resulted from this seasonal growth cycle. The calcite dendrite crystals in the Lýsuhóll travertine differ in morphology from those at other hot springs, such as those at Lake Bogoria, Kenya, and Waikite in New Zealand. Comparison with the calcite dendrite crystals found at those sites shows that dendrite morphology is site-specific and probably controlled by carbonate saturation levels that, in turn, are controlled by the rate of CO₂ degassing and location in the spring outflow system.     

Regional Variations in the Mineralogy of Metasomatic Assemblages in Mantle Xenoliths from the West Eifel Volcanic Field, Germany

Xenoliths record two distinct events in the mantle below theQuarternary West Eifel Volcanic Field, Germany. The first, duringthe Hercynian Orogeny, led to widespread formation of secondary,Ti-poor amphibole, clinopyroxene and phlogopite. The signatureof the second event, related to Quaternary volcanism, variesacross the field. At Dreiser Weiher and Meerfelder Maar, thisevent is characterized by amphibole–phlogopite–clinopyroxeneveins, hosted in lherzolite and harzburgite xenoliths broughtto the surface by sodic olivine nephelinite–basanite suitelavas. These veins formed from crystallization of sodic magmathat flowed along fractures in the mantle. At Rockeskyller Kopf,Gees and Baarley, the Quaternary event is characterized by wehrlitexenoliths, many of which have phlogopite–clinopyroxeneveins, that were transported by potassic foid suite lavas. Wehrliteformed by reaction of lherzolite–harzburgite, with a largevolume of potassic magma that flowed along grain boundariesrather than in fractures. During reaction, orthopyroxene wasconsumed and secondary clinopyroxene, olivine and phlogopiteprecipitated. Veins formed in wehrlites only during periodicover-pressure events. The composition of the magmas parentalto the veins is similar to the lavas that carried the xenolithsto surface, indicating that the source of foid and olivine nephelinite–basanitesuite magma is domainal, as was the flow regime and magma flux. KEY WORDS: Eifel; mantle xenoliths; metasomatism; trace elements     

Metamorphic Evolution of the Seward Peninsula Blueschist Terrane

Blucschists and greenschists of the central Seward Peninsula(the Nome Group) crop out over an 8000 km² area. The protolithpackage for the mid-Jurassic high P/T metamorphism consistedlargely of Cambrian, possibly also Precambrian, to Devoniansedimentary rocks (limestones, marls, pelites, carbonaceoussiltites, quartzites) of shallow water miogeoclinal origin,which maintained a coherent lithostratigraphy during metamorphismand concurrent high-strain, noncoaxial deformation. Several experimentally and empirically calibrated geothermobarometershave been integrated with textural and microstructural observationsin order to derive a pressure-temperature (P-T) path for themetamorphism of the Nome Group. These data, coupled with previouslyobtained Rb-Sr phengite-whole-rock isochron ages, yield a P-T-tpath showing a steep burial segment followed by a prolongedperiod ({small tilde}55 Ma) of isothermal decompression. Peakpressures, obtained from the jadeite content of clinopyroxenein rare, isofacial eclogites, and from the celadonite contentin phengite yield {small tilde}12 kb. Temperatures at this pressure,gained from garnet-clinopyroxene and microcline-plagioclasepairs, were 460?30?C. Decompression temperatures were essentiallythe same, as evidenced by calcite-dolomite and garnet-biotitethermometry. Uniformity of metamorphic conditions throughoutthe Seward Peninsula blueschist terrane coupled with the miogeoclinalnature of the protolith package indicate burial beneath a flat-lying(A-type) subduction zone. The derived P-T-t path is difficultto reconcile with one-dimensional thermal models of collisionalblueschists, where peak P and T are not generally coincident.     

Bedload transport of mud as pedogenic aggregates in modern and ancient rivers

Abundant sand-sized mud aggregates in the Cooper and Diamantina Rivers, Lake Eyre Basin, Australia are attributed to bedload transport of aggregates formed in deeply-cracked floodplain soils. The conditions required for formation of pedogenic mud aggregates are: (i) abundant clay containing at least minor swelling clay, and (ii) a climate with at least seasonally hot dry periods. The worldwide distribution of these soils (Vertisols) suggests that a significant amount of mud is transported as pedogenic aggregates by modern rivers. Ancient analogues in which mud aggregates and Vertisol profiles have been recognized are the Jurassic East Berlin Formation (Connecticut, USA) and the Carboniferous Maringouin Formation (New Brunswick and Nova Scotia, Canada). The dominant red mudstones of these formations are interpreted as mainly bedload sediments deposited by sheet floods in semi-arid palaeoclimates. The Triassic Hawkesbury Sandstone (NSW, Australia) also contains sand-sized mudstone aggregates, thought to be pedogenic, but its paleosol and other facies point to formation in a wetter palaeoclimate. The indications are that bedload transport of mud as pedogenic aggregates was as significant a process in ancient rivers as it is at present.     

Early Cambrian reefs, reef complexes, and associated lithofacies of the Shackleton Limestone, Transantarctic Mountains

The Shackleton Limestone formed a carbonate platform that bordered part of the Greater Antarctic craton in middle and late Early Cambrian time. In the Holyoake Range of the central Transantarctic Mountains, this unit records deposition on a stable shelf on which flourished ecological reefs composed of microorganisms and archaeocyathans. Burrow-mottled lime mudstone, wackestone and packstone with patch reefs represent accumulation in shelf areas of relatively low to moderate energy. Thick ooidal grainstone units reflect deposition in higher energy shoals and as sand sheets that were associated with extensive reef complexes. The framework of these reefs was principally the product of micro-organisms, by inference mostly cyanobacteria. Archaeocyathans constitute as much as 30% of some reefs, but commonly they form less than 10% and are absent from some. On the basis of microbial composition, three reef types are recognized. The first type is a Renalcis boundstone that lacks archaeocyathans. Within these, abundant upward-directed thalii of Renalcis formed a framework that trapped fine-grained sediment. The second type, which forms the core of some larger reefs, is composed of stromatactis-bearing, microbial boundstone. The third, yet most common, reef type is variable in composition. It is characterized by the presence of abundant Epiphyton, but may include archaeocyathans, and the microbial microfossils Girvanella and Renalcis as well as cryptomicrobial clotted micrite. In this type of reef, frame-building organisms typically constructed highly porous structures that had small interparticle and fenestral pores and large growth-framework cavities, as well as rare metre-sized caverns. Within these spaces, Epiphyton and, less commonly Renalcis, encrusted framework elements, fine-grained sediments accumulated, and pervasive sea-floor cements were precipitated. Boundstone fabrics in the Shackleton Limestone are highly complex, with fabrics analogous to younger, more metazoan-rich reefs, as well as deep-water stromatactis-bearing mud-mounds. The Epiphyton-Girvanella-archaeocyathan frameworks and stromatactis-bearing boundstones, both of which seemingly first appeared in the middle Early Cambrian, are regarded as the precursors, in structure, composition, and preferred hydrologic setting, of the more extensive reefs and complex framework styles of later Phanerozoic time.