Analytical prediction of aggregates' effects on the ITZ volume fraction and Young's modulus of concrete

In order to evaluate analytically the ITZ volume fraction (f_ITZ) in concrete, a three phase model is proposed for the random concrete microstructure using the Voronoï tessellation. Within this model, the ITZ local thickness is a statistical variable depending on the local paste thickness available between each couple of neighbouring aggregates. The f_ITZ is found to not exceed 7% for typical concretes. Then, the concrete Young's modulus is predicted analytically using a four‐phase generalized self consistent model but in which the proposed f_ITZ is considered. It is found that the concrete Young's modulus increases when increasing aggregates volume fraction, aggregates maximum size and the proportion of coarse aggregates and when decreasing the ITZ thickness and Young's modulus. Finally, the validity of the proposed model is discussed based on a comparison between its predictions and three sets of experimental results related to normal and high strength concretes taken from literature. Copyright © 2016 John Wiley & Sons, Ltd.     

Multichannel analysis of surface waves (MASW) for seismic site characterization using 2D genetic algorithm at Bahrah area,Wadi Fatima,Saudi Arabia

The present study deals with the seismic site classification of Bahrah area, Wadi Fatima, to characterize the local site conditions. The dynamic behavior of sediments was studied by the application of surface wave inversion. The multichannel analysis of surface waves (MASW) shallow geophysical technique was utilized for site classification. MASW survey was carried out at 66 sites along with 13 seismic refraction profiles at suitable localities. MASW and seismic refraction profiles were processed and compared with the available borehole data. The integration of MASW techniques with seismic refraction and borehole data progressively enhanced the subsurface visualization and reliability of the shear wave velocity estimation in the subsurface in the study area. The subsurface shear-wave velocity model was achieved by the solution of an inverse problem-based dispersion of surface waves and propagation in a vertically heterogeneous medium. The 2D genetic algorithm was employed for the inversion of dispersion curves to obtain velocity and thickness of subsurface layers. The depth to engineering bedrock and velocity of shear waves in the first 30 m was deciphered and mapped. The depth of bedrock in study area varies from 4 to 30 m, and V _{S 30} ranges from 320 to 800 m/s. The most of study area falls in B and C class categories in addition to few sites of D class according to the NEHRP guidelines.     

Modelling of Soil Degradation in Semi-arid Area Using Remote Sensing and GIS Techniques,Southern Jordan As Case Study

Doklady Earth Sciences - This research dealt with the topic of modeling the soil lost in a semi-arid desert area in the Ma’an watershed and its surroundings in Ma’an Governorate using...     

Geoheritage values of one of the largest maar craters in the Arabian Peninsula: the Al Wahbah Crater and other volcanoes (Harrat Kishb, Saudi Arabia)

Al Wahbah Crater is one of the largest and deepest Quaternary maar craters in the Arabian Peninsula. It is NW-SE-elongated, ～2.3 km wide, ～250 m deep and surrounded by an irregular near-perpendicular crater wall cut deeply into the Proterozoic diorite basement. Very few scientific studies have been conducted on this unique site, especially in respect to understanding the associated volcanic eruption processes. Al Wahbah and adjacent large explosion craters are currently a research subject in an international project, Volcanic Risk in Saudi Arabia (VORiSA). The focus of VORiSA is to characterise the volcanic hazards and eruption mechanisms of the vast volcanic fields in Western Saudi Arabia, while also defining the unique volcanic features of this region for use in future geoconservation, geoeducation and geotourism projects. Al Wahbah is inferred to be a maar crater that formed due to an explosive interaction of magma and water. The crater is surrounded by a tephra ring that consists predominantly of base surge deposits accumulated over a pre-maar scoria cone and underlying multiple lava flow units. The tephra ring acted as an obstacle against younger lava flows that were diverted along the margin of the tephra ring creating unique lava flow surface textures that recorded inflation and deflation processes along the margin of the post-maar lava flow. Al Wahbah is a unique geological feature that is not only a dramatic landform but also a site that can promote our understanding of complex phreatomagmatic monogenetic volcanism. The complex geological features perfectly preserved at Al Wahbah makes this site as an excellent geotope and a potential centre of geoeducation programs that could lead to the establishment of a geopark in the broader area at the Kishb Volcanic Field.     

The contribution of geographic information systems and remote sensing in determining priority areas for hydrogeological development, Darb el-Arbain area, Western Desert, Egypt

The Darb el-Arbain study area is in the southern Western Desert of Egypt and has been attracting increasing developmental interest in the last few decades, especially since agricultural development of the southern Baris area, where the groundwater resources of the Nubian Sandstone Aquifer System (NSAS) have been utilized for the cultivation of valuable lands. Due to the proven high potential of both groundwater and land resources, determining the priority areas for sustainable hydrogeological development becomes a necessity. A geographic information system, as a platform for geospatial modeling techniques, has been built, which depends on the recently collected data about the NSAS, in addition to the published databases. Certain criteria of practical value, like depth to groundwater, hydraulic conductivity, groundwater salinity, sodium adsorption ratio, and the safe yield of wells, were selected as decisive parameters for hydrogeological prioritization. The model pinpoints areas characterized by favorable hydrogeological conditions, which could be used for future development and implementation of an artificial storage and recovery (ASR) program. The designated priority areas for hydrogeological development occur at the southern, middle southern and some localized northern parts of the Darb el-Arbain area. The newly formed Tushka Lakes represent a suitable and excellent natural source of freshwater for implementing an ASR program.     

Groundwater potentiality mapping in the Sinai Peninsula, Egypt, using remote sensing and GIS-watershed-based modeling

Systematic planning for groundwater exploration using modern techniques is essential for the proper utilization, protection and management of this vital resource. Enhanced Thematic Mapper Plus (ETM+) images, a geographic information system (GIS), a watershed modeling system (WMS) and weighted spatial probability modeling (WSPM) were integrated to identify the groundwater potential areas in the Sinai Peninsula, Egypt. Eight pertinent thematic layers were built in a GIS and assigned appropriate rankings. Layers considered were: rainfall, net groundwater recharge, lithology or infiltration, lineament density, slope, drainage density, depth to groundwater, and water quality. All these themes were assigned weights according to their relative importance to groundwater potentiality and their corresponding normalized weights were obtained based on their effectiveness factors. The groundwater potentiality map was finally produced by WSPM. This map comprises five gradational groundwater potentiality classes ranging from very high to very low. The validity of this unbiased GIS-based model was tested by correlating its results with the published hydrogeological map of Egypt and the actual borehole yields, where a concordant justification was reached. The map declared that the Sinai Peninsula is generally of moderate groundwater potentiality, where this class encompasses an area of 33,120?km² which represents 52% of its total area.     

Off-line solid-phase extraction procedure for the determination of polycyclic aromatic hydrocarbons from aqueous matrices

An off-line solid-phase extraction procedure followed by high-performance liquid chromatography with ultraviolet detection for the determination of 16 priority polycyclic aromatic hydrocarbon pollutants in aqueous matrices was described. Diverse aspects determining extraction efficiency such as packing type (disk or cartridge), elution solvents and addition of organic modifiers to the sample were evaluated. Elution with acetonitrile yields the highest recoveries. Rinsing the sample bottle with acetonitrile and combining the rinse with the sample extract avoids the adsorption of polycyclic aromatic hydrocarbons on the walls of the water containers. The use of isopropanol or methanol 10 % (V/V) was the most appropriate amount for the enrichment of 2- to 6-ring aromatic compounds only on C18 cartridge. The recoveries for all studied polycyclic aromatic hydrocarbons are ranged from 71.4 to 95.2 % for a treated water samples of 500 mL. The proposed method gives very low detection limits (subnanograms per liter) and it has been applied to drinking water, surface water and industrial effluent (oil refinery) samples with good results.     

Determining groundwater protection zones for the Quaternary aquifer of northeastern Nile Delta using GIS-based vulnerability mapping

The area of study lies at the northeastern part of Nile Delta. Global shoreline regression and sea-level rise have their own-bearing on the groundwater salinization due to seawater intrusion. A new adopted approach for vulnerability mapping using the hydrochemical investigations, geographic information system and a weighted multi-criteria decision support system (WMCDSS) was developed to determine the trend of groundwater contamination by seawater intrusion. Six thematic layers were digitally integrated and assigned different weights and rates. These have been created to comprise the most decisive criteria used for the delineation of groundwater degradation due to seawater intrusion. These criteria are represented by the total dissolved solids, well discharge, sodium adsorption ratio, hydrochemical parameter (Cl/HCO₃), hydraulic conductivity and water types. The WMCDSS modeling was tried, where a groundwater vulnerability map with four classes ranging from very low to high vulnerability was gained. The map pinpointed the promising localities for groundwater protection, which are almost represented by the very low or low vulnerability areas (53.69 % of the total study area). The regions having high and moderate groundwater vulnerability occupy 46.31 % of total study area, which designate to a deteriorated territory of groundwater quality, and needs special treatment and cropping pattern before use. However, the moderate groundwater vulnerability class occupies an area of about 28.77 % of the total mapped area, which highlighted the need for certain management practices to prevent the saltwater intrusion from expanding further to the south. There was a good correlation of the constructed vulnerability map with the recently gathered water quality data and hydrochemical facies evolution. The plotting of water quality data on Piper trilinear diagram revealed the evolution of freshwater into the mixing and the saline zones as an impact of seawater intrusion, which validates the model results.     

Coral reefs as a tool for monitoring environmental and radiation hazards

Analysis of coral reef species enables characterization of the coral reefs and the degree to which human activities influence the reef composition. Geochemical characteristics, X-ray diffraction, and natural radionuclides analyses of four common coral reef species representing the branching and massive forms were conducted at the three areas under threat (Quseir Harbor, Safaga Harbor, and El-Esh area) along the Red Sea coast. Branching recorded higher carbonates and lower organic matter than the massive forms. Stylophora pistillata at Safaga Harbor and El-Esh area and Acropora humilis at Qusier Harbor recorded the highest carbonate percentages (96.88, 96.24, and 96.89%, respectively) meanwhile Platygyra daedalea at Safaga Harbor recorded the highest organic matter contents (5.07 and 4.91%). The highest Ca contents were observed in S. pistillata and Porites solida (65.87 and 64.87%), the highest Mg was in Acropora humilis and P. daedalea (1.06 and 0.88%) at Qusier Harbor, whilst the highest Sr was in S. pistillata and P. daedalea at Safaga Harbor. Then highest value of ²²⁶Ra recorded in A. humilis and P. solida (71 ± 3.5 Bq/kg and 63 ± 3.1 Bq/k) and ²³²Th in S. pistillata at El-Esh area may attribute to petroleum exploration activities. A. humilis and P. daedalea at Safaga Harbor recorded significant high ⁴⁰K values (505 ± 30 and 472 ± 13 Bq/kg, respectively) relative to the other localities. The low Ca and High Sr as well as the highest averages of ²³²Th and ⁴⁰K at Safaga Harbor indicated that the coral reef communities were highly affected by the terrestrial inputs from phosphate shipments.