An analysis of 3.5 kHz acoustic reflections and sediment physical properties

Near-bottom normal incidence acoustic reflection data and sediment physical property data are used to study the relationships between acoustic reflections and sediment physical properties. A pinger-hydrophone experiment was performed to obtain the necessary acoustic reflection data. In addition, a standard piston core was retrieved in the acoustic survey area for physical property analysis. The piston core was sampled and 13 properties were measured at 55 locations within the top 12 m of the core. Correlation studies amongst the sediment physical properties resulted in the following strong correlations: acoustic impedance ($\text{Z}$) and porosity ($\text{N}$), (0.96); water content ($\text{WC}$) and $\text{Z}$, (0.95); bulk density ($\text{BD}$) and $\text{Z}$, (0.99).The empirical orthonormal function (EOF) method was employed for acoustic signal analysis. This method assumes no a-priori models of the sediment or causality. The EOF method reduced the acoustic data to 8 functions that contained 97.6% of the sample variance. The EOFs were subsequently analysed by using cepstrum analysis which reveals time delay information and enhances detecting zones of reflectivity. The result of the sediment physical property and cepstrum analysis indicates that zones of reflectivity are essentially zones of relatively high acoustic impedance, low porosity, and low phi (high mean grain size).     

A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.     

Simulation of seismic response in a city-like environment

We study the seismic response of idealized 2D cities, constituted by non-equally spaced, non-equally sized homogenized blocks anchored in a soft layer overlying a hard half space. The blocks and soft layer are occupied by dissipative media. To simulate such response, we use an approximation of the viscoelastic modulus by a low-order rational function of frequency and incorporate this approximation into a first-order-in-time scheme. Our results display spatially variable, strong, long-duration responses inside the blocks and on the ground, which qualitatively match the responses observed in some earthquake-prone cities of Mexico, France, the USA, etc.     

Evaluation of antifouling properties of non-toxic marine paints

The most common way to prevent biofouling of immersed surfaces is to coat the exposed surfaces with a paint containing a biocide acting on marine organisms by diffusion into the surrounding water. However diffusion of toxins into the marine environment causes pollution and serious economic problems. This paper outlines the anti-microfouling properties of some insolubilized quaternary ammonium salts (grafted onto a vinyl copolymer by means of a covalent non-hydrolyzable bond). After immersion times in sea-water up to 4 months, the microbial cover was limited to bacterial forms, without microalgae or cyanobacteria as observed on the untreated, or tin-salt painted surfaces. Bacteria are mostly on unicell forms and numerous areas appear free of any microorganisms. As microbiofouling is an obligate step to macrofouling, this unleachable antifouling treatment could result in a prolonged protection.     

Aeromagnetic evidence for the rotation of Sardinia (Mediterranean Sea): comparison with the paleomagnetic measurements

The aeromagnetic survey of Sardinia (western Mediterranean) delineated a large magnetic anomaly located in the western part of the island. The shape of the anomaly is improved and simplified by upward continuation, and modelling in terms of three-dimensional structure gives a westward remanent magnetization. Some tests have been carried out to suppress ambiguities on the magnetic dual aspect “magnetization distribution-shape of sources”. The optimal declination obtained after a few testings is 30° west which is ascribed to the rotation of Sardinia. This value confirms the results provided by paleomagnetic investigations and is significant because it characterizes a large and deep-rooted structure involved in the rotation of Sardinia. Our results thus illustrate another interesting application of aeromagnetic surveys.     

Abundance and degree of residency of humpback dolphins Sousa plumbea in Mossel Bay,South Africa

Indian Ocean humpback dolphins Sousa plumbea inhabit nearshore waters from South Africa to eastern India. Humpback dolphins are vulnerable to conservation threats due to their naturally small population sizes and use of nearshore habitats, where human activities are highest. We investigated the abundance and residency of this species inhabiting Mossel Bay, South Africa, using photographic mark-recapture. Data were collected during 81 surveys in Mossel Bay between 2011 and 2013. Open population modelling using the POPAN parameterisation produced a ‘super-population’ estimate of 125 individuals (95% CI: 61–260) and within-year estimates of between 33 and 86 individuals (2011: 71 [95% CI: 30–168]; 2012: 33 [15–73], 32 [15–70]; 2013: 46 [20–108]). Although less appropriate, closed capture models were also run for comparison with previous studies in the region and generated similar, but slightly smaller, population estimates within each year. We compared our catalogue with opportunistic data collected from East London, Plettenberg Bay, De Hoop and Gansbaai. The only catalogue matches attained were between Plettenberg Bay (n = 44 identified) and Mossel Bay (n = 67 identified), separated by 140?km. Population exchange was moderate, with nine individuals resighted in multiple years between these two areas. This study supports previous findings of long-range movements for this species and provides a baseline from which to assess future impacts on the population.     

Comparing the patterns of 20–70 days intraseasonal oscillations over Central Africa during the last three decades

In this paper, we used the Outgoing Longwave Radiation (OLR) data to compare the intraseasonal atmospheric variability patterns over Central Africa, during the last three decades. The spectral analysis indicates that for the three decades, the intraseasonal variability is dominated by 20–80 days periods band with the center near 40–50 days. The results of Empirical Orthogonal Functions (EOFs) analysis have shown that the amount of variance explained by the three retained EOFs are 41.6 % for 1981–1990, 44.2 % for 1991–2000 and 42.6 % for 2001–2010. For the three decades, the three leading EOFs retained exhibit high spatial loadings over Northern Congo, Southern Ethiopia, and Southwestern Tanzania. The power spectra of the leading principal components have their peaks near 40 days for the three decades, indicating MJO signal. The PCs time series revealed that the amplitude of intraseasonal oscillations (ISO) globally decreases from decade to another. The plot of ISO and El Niño-Southern Oscillation (ENSO) indices revealed that the lowest values of ISO strength generally correspond to the relatively large values of ENSO indices and inversely. The mean ISO strength and ISO fluctuations were highest during 1981–1990, and this period also corresponds to the highest fluctuations of ENSO signal.     

Geometry and Properties of the Excavation-Induced Fractures at the Meuse/Haute-Marne URL Drifts

The performance and safety assessment and technology demonstration are the main objectives of research programs for feasibility studies for deep geological repository of radioactive waste. In this context, the French national radioactive waste management agency (ANDRA) started to develop the Meuse/Haute-Marne underground research laboratory (URL) at Bure, nearly 300 km East of Paris. The host formation consists of a Callovo-Oxfordian claystone found between 420 and 550 m below ground, overlain and underlain by poorly permeable carbonate formations. One of the major concerns related to performance assessment is the excavation-induced fractures which may provide groundwater preferential pathway for radionuclide migration. The extent of the fractures possibly acting significantly in the radionuclide migration is known as the excavation damaged zone (EDZ). A scientific study on the EDZ characterization is performed at the main level of the URL (?490 m). Observations such as structural analysis on core, overcored resin-filled samples, geological survey of the drift face and sidewalls, were made to better understand the fracture network characteristics, extent and its generation. Pulse and constant head test hydraulic conductivity measurements were performed with multi packer system to estimate the extension of the EDZ hydraulic conductivity. Fractures exhibited high transmissivity near the excavation walls, but farther from the exaction walls, shear fractures showed hydraulic conductivity values reflecting values of undisturbed or slightly disturbed rock mass condition. The major findings in terms of geometry and properties of excavation-induced fractures are discussed in detail in this paper. For example, it is observed that the shape of the fracture network depends on the orientation of the drift in relation to the orientation of the in situ stress field.     

Numerical investigation of road salt impact on an urban wellfield

The impact of road salt on a wellfield in a complex glacial moraine aquifer system is studied by numerical simulation. The moraine underlies an extensive urban and industrial landscape, which draws its water supply from >20 wellfields, several of which are approaching or have exceeded the drinking water limit for chloride. The study investigates the mechanisms of road salt infiltration, storage, and transport in the subsurface and assesses the effectiveness of mitigation measures designed to reduce the impact. The three-dimensional transport model accounts for increases in salt loading, as well as growth of the urbanized area and road network over the past 50 years. The simulations, which focus on one impacted wellfield, show chloride plumes originating mainly at arterial roads and migrating through aquitard windows into the water supply aquifers. The results suggest that the aquifer system contains a large and heterogeneously distributed mass of chloride and that concentrations in the aquifer can be substantially higher than the concentrations in the well water. Future impact scenarios indicate that although the system responds rapidly to reductions in salt loading, the residual chloride mass may take decades to flush out, even if road salting were discontinued. The implications with respect to urban wellfields in typical snow-belt areas are discussed.