Ostracode carbonate δ18O- and δ13C-signature of hydrological and climatic changes affecting Lake Neuchâtel,Switzerland, since the latest Pleistocene

Floating and grounded peat plateaus were studied in fens in the Yukon Territory (Canada). The peat deposit may be over 4 m thick and consists of a lower bed of aquatic peat overlain by humic fen peat, mesic fen peat and woody peat. Permafrost in the grounded peat plateaus is older than the 1200 year old White River Ash, whereas permafrost in the floating peat plateau is younger.Peat accumulation rates since 1200 years B.P. were greater in the fens (85–100 cm) than on the surface of the peat plateaus (25–55 cm). Where the peat plateau is free-floating, it will persist until the climate changes, causing the icy core to thaw. Where the peat plateau is frozen to the mineral substrate, it slowly drowns since the fen peat accumulates faster than the woody peat. This drowning results in degradation of the landform independently of the climate. Only degradation of floating peat plateaus can be used to identify climatic changes.This publication is the first paper in a series of papers presented at the session on Past Climatic Change and the Development of Peatlands at the ASLO and SWS Meetings in Edmonton, Canada, May 30–June 3, 1993. Dr. P. Kuhry and Dr S. C. Zoltai are serving as Guest Editors.     

Determination of spectral properties of earthquakes from their magnitudes

Following the recommendation of the “IASPEI Commission on Magnitudes” from 1967, P-wave magnitudes of distant earthquakes are being computed with the aid of the calibration functions of Gutenberg and Richter (1956). With the development of the instrumental seismology, especially in view of the availability of broad-band recordings, the question arises whether the functions are still adequate.In this investigation new calibration functions for P- and S-waves are presented, which are not only dependent on epicentral distance and focal depth, but also on the period of the spectral component of the wave. The determination of calibration functions is based on the currently most plausible global models for the velocity and anelasticity distribution. Taking into account the effective bandwidth of the instruments employed, eventually leads to the so-called spectral magnitudes.From the spectral magnitudes m(T) , the energy density spectrum E(T) of the respective wave can readily be computed. The corresponding formula is E(T) = 10^{2m(T)− 1.4}, with E(T) in joules per hertz.     

Spectral magnitude and seismic radiated energy computed from CDSN records

We have employed 10 digital records and computed the spectral magnitude and the seismic radiated energy for 18 large earthquakes (M _s≥6) occurred in Eur-asian belt during 1986–1989. The nine digital stations (CD-SN) distribute all over China and one in Germany. The spectral magnitudes of various period have different stability among stations. The stability is better for maximum spectral magnitudemi and seismic radiated energyE, their differences among stations are smaller, especially for the stations where the ray path main penetrates the low mantle. But the stability of corner period is usually not good. The relation between seismic radiated energy and seismic moment magnitudeM _w is lg (E)=1.5Mw+c, wherec is a constant. The maximum spectral magnitudemi=M _w+0.1, it is consistant with theoretical prediction. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,15, 418–426, 1993. This work supported by the Deutsche Forschungsgemeinschaft, Bonn, F. R. Germany. The support is grateful acknowledge.     

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.     

Numerical Modeling of the Observed Wiechert Seismograph Magnification

—The paper presents results of experiments designed to measure the actual dynamic magnification of the Wiechert 1000 kg horizontal seismometer when excited by seismic waves. This is accomplished by comparing 51 digital records of seismic events recorded by the Wiechert and a well calibrated reference seismometer. The results obtained indicate that the magnification of the Wiechert seismometer is influenced by the interaction of its mass and frame, especially for high frequencies. This interaction has been modeled by considering a system of two coupled pendulums, yielding a theoretical dynamic magnification curve which exhibits main features of the observed magnification. The dis crepancy between the nominal and the actual response of the Wiechert seismograph may lead to errors in studies involving spectral analyses of recorded seismograms, and to overestimation of local earth quake magnitudes.     

A modeling study of acoustic propagation through movingshallow-water solitary wave packets

Propagation of 400-Hz sound through continental-shelf internal solitary wave packets is shown by numerical simulation to be strongly influenced by coupling of normal modes. Coupling in a packet is controlled by the mode coefficients at the point where sound enters the packet, the dimensions of the waves and packet, and the ambient depth structures of temperature and salinity. In the case of a moving packet, changes of phases of the incident modes with respect to each other dominate over the other factors, altering the coupling over time and thus inducing signal fluctuations. The phasing within a moving packet varies with time scales of minutes, causing coupling and signal fluctuations with comparable time scales. The directionality of energy flux between high-order acoustic modes and (less attenuated) low-order modes determines a gain factor for long-range propagation. A significant finding is that energy flux toward low-order modes through the effect of a packet near a source favoring high-order modes will give net amplification at distant ranges. Conversely, a packet far from a source sends energy into otherwise quiet higher modes. The intermittency of the coupling and of high-mode attenuation via bottom interaction means that signal energy fluctuations and modal diversity fluctuations at a distant receiver are complementary, with energy fluctuations suggesting a source-region packet and mode fluctuations suggesting a receiver-region packet. Simulations entailing 33-km propagation are used in the analyses, imitating the SWARM experiment geometry, allowing comparison with observations     

Methane and sulfide fluxes in permanent anoxia: In situ studies at the Dvurechenskii mud volcano (Sorokin Trough, Black Sea)

The Dvurechenskii mud volcano (DMV) is located in permanently anoxic waters at 2060 m depth (Sorokin Trough, Black Sea). The DMV was studied during the RV Meteor expedition M72/2 as an example of an active mud volcano system, to investigate the significance of submarine mud volcanism for the methane and sulfide budget of the anoxic Black Sea hydrosphere. Our studies included benthic fluxes of methane and sulfide, as well as the factors controlling transport, consumption and production of both compounds within the sediment. The pie-shaped mud volcano showed temperature anomalies as well as solute and gas fluxes indicating high fluid flow at its summit north of the geographical center. The anaerobic oxidation of methane (AOM) coupled to sulfate reduction (SR) was repressed in this zone due to the upward flow of sulfate-depleted fluids through recently deposited subsurface muds, apparently limiting microbial methanotrophic activity. Consequently, the emission of dissolved methane into the water column was high, with an estimated rate of 0.46 mol m⁻² d⁻¹. On the wide plateau and edge of the mud volcano surrounding the summit, fluid flow and total methane flux were lower, allowing higher SR and AOM rates correlated with an increase in sulfate penetration into the sediment. Here, between 50% and 70% of the methane flux (0.07-0.1 mol m⁻² d⁻¹) was consumed within the upper 10 cm of the sediment. The overall amount of dissolved methane released from the entire mud volcano structure into the water column was significant with a discharge of 1.3 × 10⁷ mol yr⁻¹. The DMV maintains also high areal rates of methane-fueled sulfide production and emission of on average 0.05 mol m⁻² d⁻¹. This is a difference to mud volcanoes in oxic waters, which emit similar amounts of methane, but not sulfide. However, based on a comparison of this and other mud volcanoes of the Black Sea, we conclude that sulfide and methane emission into the hydrosphere from deep-water mud volcanoes does not significantly contribute to the sulfide and methane inventory of the Black Sea.     

Developments in solid earth geophysics volume 15: Proceedings of the Seventeenth Assembly of the European Seismological Commission Budapest, 24–29 August 1980. E. Bisztricsany and Gy. Szeidovitz (Editors). Elsevier Scientific Publishing Company,Amsterdam-Oxford-New York, 1983, XVIII + 689 pages,ISBN 0-444-99662-1.

Various methods for the prediction of secular variation are tested by applying them to data for a single element at a single station. None of them is of any use for more than a few years.     

Coupled acoustic mode propagation through continental-shelfinternal solitary waves

Three techniques are used to investigate mode coupling as acoustic energy passes through continental-shelf internal solitary waves (ISW's). Results from all techniques agree. The waves considered here are single downward undulations of a thermocline layer separating upper and lower well-mixed layers. Two techniques are numerical: parabolic equation (PE) solution and a sudden approximation joining range-invariant regions at sharp vertical interfaces. The third technique is an analytic derivation of ISW scale lengths separating adiabatic (at large scale) and coupled-mode propagation. Results show that energy is exchanged between modes as ISW's are traversed. The sharp interface solutions help explain this in terms of spatially confined coupling and modal phase interference. Three regimes are observed: 1) for short ISW's, coupling upon wave entrance is reversed upon exit, with no net coupling; 2) for ISW scales of 75-200 m, modal phase alteration averts the exit reversal, giving net coupling; transparent resonances yielding no net coupling are also observed in this regime; and 3) for long ISW's, adiabaticity is probable but not universal. Mode refraction analysis for nonparallel acoustic-ISW alignment suggests that these two-dimensional techniques remain valid for 0° (parallel) to 65° (oblique) incidence, with an accordant ISW stretching     

Normal fault growth influenced by basement fabrics: The importance of preferential nucleation from pre‐existing structures

Reactivation of pre‐existing intra‐basement structures can influence the evolution of rift basins, yet the detailed kinematic relationship between these structures and overlying rift‐related faults remains poorly understood. Understanding the kinematic as well as geometric relationship between intra‐basement structures and rift‐related fault networks is important, with the extension direction in many rifted provinces typically thought to lie normal to fault strike. We here investigate this problem using a borehole‐constrained, 3D seismic reflection dataset from the Taranaki Basin, offshore New Zealand. Excellent imaging of intra‐basement structures and a relatively weakly deformed, stratigraphically simple sedimentary cover allow us to: (a) identify a range of interaction styles between intra‐basement structures and overlying, Plio‐Pleistocene rift‐related normal faults; and (b) examine the cover fault kinematics associated with each interaction style. Some of the normal faults parallel and are physically connected to intra‐basement reflections, which are interpreted as mylonitic reverse faults formed during Mesozoic subduction and basement terrane accretion. These geometric relationships indicate pre‐existing intra‐basement structures locally controlled the position and attitude of Plio‐Pleistocene rift‐related normal faults. However, through detailed 3D kinematic analysis of selected normal faults, we show that: (a) normal faults only nucleated above intra‐basement structures that experienced late Miocene compressional reactivation, (b) despite playing an important role during subsequent rifting, intra‐basement structures have not been significantly extensionally reactivated, and (c) preferential nucleation and propagation of normal faults within late Miocene reverse faults and folds appears to be the key genetic relationship between contractionally reactivated intra‐basement structures and rift‐related normal faults. Our analysis shows that km‐scale, intra‐basement structures can control the nucleation and development of newly formed, rift‐related normal faults, most likely due to a local perturbation of the regional stress field. Because of this, simply inverting fault strike for causal extension direction may be incorrect, especially in provinces where pre‐existing, intra‐basement structures occur. We also show that a detailed kinematic analysis is key to deciphering the temporal as well as simply the spatial or geometric relationship between structures developed at multiple structural levels.