Regional distribution pattern of groundwater heavy metals resulting from agricultural activities

Contaminations of groundwater by heavy metals due to agricultural activities are growing recently. The objective of this study was to evaluate and map regional patterns of heavy metals (Cd, Zn and Cu) in groundwater on a plain with high agricultural activities. The study was conducted to investigate the concentration of heavy metals and distribution in groundwater in regions of Shush Danial and Andimeshk aquifers in the southern part of Iran. Presently, groundwater is the only appropriate and widely used source of drinking water for rural and urban communities in this region. The region covers an area of 1,100 km² between the Dez and Karkhe rivers, which lead to the Persian Gulf. For this study, the region was divided into four sub-regions A, B, C and D. Additionally, 168 groundwater samples were collected from 42 water wells during the earlier months of 2004. The flame atomic absorption spectrometry (AAS-Flame) was used to measure the concentration of heavy metals in water samples and the Surfer software was used for determination of the contour map of metal distribution. The results demonstrated that in all of the samples, Cd and Zn concentrations were below the EPA MCLG and EPA secondary standard, respectively. However, the Cu contents of 4.8 % of all samples were higher than EPA MCL. It is also indicated that the concentrations of metals were more pronounced at the southern part of the studied region than at the others. The analysis of fertilizers applied for agricultural activities at this region also indicated that a great majority of the above-mentioned heavy metals were discharged into the environment. Absence of confining layers, proximity to land surface, excess agricultural activities in the southern part and groundwater flow direction that is generally from the north to the southern parts in this area make the southern region of the Shush plain especially vulnerable to pollution by heavy metals than by other contaminants.     

Mantle flow patterns at the Neyriz Paleo-spreading center, Iran

The mantle peridotites of Neyriz record two successive episodes of plastic deformations; the first one related to the igneous accretion of the lithosphere and the second one developed during the first stage of the emplacement of the peridotites. These two events have been distinguished on the basis of microstructural criteria. The diapiric pattern, particularly relevant to the mantle process beneath spreading ridges, features vertical flow lines and elliptic flow plane trajectories in a pipe and extends along the ridge axis about 5 km. These structures rotate to horizontal and diverge in every direction in a narrow transition zone, a few hundred meters thick, below the Moho discontinuity. Such a diapiric pattern has been recognized in a few places along the Neyriz paleo-ridge. A large amount of magma passed through these mantle diapirs that were probably the main zones feeding the overlying magma chamber. The most common pattern features very regular structures over several kilometers along the strike of the paleo-ridge: the flow plane dips away from the ridge axis, and the flow line is parallel to the spreading direction. This flow pattern is frozen during the gradual accretion of the lithospheric mantle away from the ridge in a steady-state spreading regime. A shear-sense inversion at just below the Moho is commonly observed, pointing to forced asthenospheric flow. The reconstructed orientation of the Neyriz paleo-spreading center is 105°, compatible with the geometry and orientation of harzburgite foliations and lineations and sheeted dikes.     

Lake Neor reveals how mountain vegetation responded to 7000 years of hydroclimate variability in northwestern Iran

Palynological and geochemical analyses provide valuable information about modern and past climatic regimes and vegetation. The impact of climate and humans on past vegetation in the semi-arid areas of northwestern Iran has received increased interest in the wake of warming temperatures in the Middle East. Palynological and down-core XRF elemental abundances from a peat core from Lake Neor enabled a reconstruction of vegetational changes of the past 7000 years over the highlands of northwestern Iran. Periods of increased arboreal pollen (AP) types and high (Artemisia + Poaceae)/Chenopodiaceae ratios along with low titanium abundances, high percentages of total organic carbon, more negative δD values, and higher carbon accumulation rates suggest a relatively wet climate. These conditions have persisted during the periods 6700–6200, 5200–4450 and 3200–2200 cal a bp. The overall low AP values, substantial rise of Chenopodiaceae, high Ti abundances and low values of palaeo-redox proxies, are all evidences of a drier climate, as has been reconstructed for the periods 6200–5200 and 4030–3150 cal a bp and the last 2200 years. An important feature of the last centuries is the increase of anthropogenic and pastoral indicator pollen types. Our results may provide basic data to predict future trends in vegetation dynamics under future climate change in western Asia.     

Hydrodynamic Tidal Model of the Persian Gulf Based on Spatially Variable Bed Friction Coefficient

The aim of this study is to develop a two-dimensional hydrodynamic tidal model for the Persian Gulf (PG2017) using 2D-MIKE21 software. The advantages of present study is accounting for the spatial variation of bed friction coefficient besides a precise bathymetry together with a 23-year of combined records of satellite altimetry data. We found that the bed friction coefficient has a significant effect on sea level changes in the region under our modeling consideration. Since the tidal behavior in the northern part of the Qeshm Island is significantly different from the other parts of the Persian Gulf, to present a more accurate hydrodynamic tidal model, the Gulf is divided into two regions where the bed friction coefficient is modeled separately for each region. The root mean square value of the differences between the amplitude of dominant constituents; M2, S2, K1, and O1 derived from the PG2017 model and that of 98 altimetry and coastal tide gauge stations are respectively equal to 1.6, 1.9, 2.8, and 1.3?cm. Moreover, comparing the PG2017 model efficiency with the FES2014, OSU12, EOT11a, DTU10, and Admiralty models shows that the PG2017 model has an improvement of 22.1%, 47.2%, 43.2%, 44.2%, and 57.6% in terms of relative error, respectively.     

Experimental studies to constrain parental magma of Malangtoli volcanics from Singhbhum craton of the eastern Indian shield

Malangtoli volcanics of the Singhbhum craton of the eastern Indian shield is one of the important Proterozoic lava suites. Experimental studies on 1 atmosphere pressure constrain the parental magma type and temperature range of crystallization of the parent magma (deduced to be in the range of 1500°C to 1200°C). The experimental studies show that at 1500°C, plagioclase is the first phase to crystallize, followed by few opaques which join along with plagioclase at 1450°C. At subsequent lower temperature (1400°C-1300°C), plagioclase and opaque continue to crystallize. At 1250°C plagioclase and opaque still persist while pyroxene appears first and liquid (glass) still remains. Appearance of opaque minerals (magnetite and illmenite) at both ~1400°C and ~1300°C indicate oscillation of oxygen fugacity in the parent magma, petrographically documented by coarser phenocrysts as well as finer or peripheral tiny grains. Use of tectonic discrimination diagrams (based on discrimination factors F₁-F₂ and FeO^t/MgO vs. TiO₂) shows an island arc tholeiitic affinity for Malangtoli volcanic, suggests that the role of proto-plate convergence in Singhbhum architecture played an important role to build up Malangtoli volcanics during Proterozoic.     

Prediction of Seaward Slope Recession in Berm Breakwaters Using M5' Machine Learning Approach

In the design process of berm breakwaters, their front slope recession has an inevitable rule in large number of model tests, and this parameter being studied. This research draws its data from Moghim’s and Shekari’s experiment results. These experiments consist of two different 2D model tests in two wave flumes, in which the berm recession to different sea state and structural parameters have been studied. Irregular waves with a JONSWAP spectrum were used in both test series. A total of 412 test results were used to cover the impact of sea state conditions such as wave height, wave period, storm duration and water depth at the toe of the structure, and structural parameters such as berm elevation from still water level, berm width and stone diameter on berm recession parameters. In this paper, a new set of equations for berm recession is derived using the M5'' model tree as a machine learning approach. A comparison is made between the estimations by the new formula and the formulae recently given by other researchers to show the preference of new M5'' approach.     

Local site effect of a clay site in Shiraz based on seismic hazard of Shiraz Plain

Propagation of seismic waves through soil layers would drastically change the frequency content and amplitude-based features of ground motions at the surface. These alterations are known as seismic site effects. Computation of site effects of high-populated areas such as large cities is of great importance (e.g., it is used in development of seismic microzonation of a region). Shiraz is one of the most populous cities of Iran and is located in a high seismic hazardous region. A representative clay site in this city is selected to assess local site effects. The time series and random vibration theory procedure in the frequency domain are implemented to analyze the aforementioned site. Furthermore, the nonlinear dynamic soil behavior is simulated by the equivalent linear method and the nonlinear method via DEEPSOIL program. Three types of soil column uncertainties such as shear wave velocity, modulus reduction, and damping ratio of soil layers as well as depth of underlying rock half-space (D _bed) are considered herein. The mean amplification and standard deviation of natural logarithm of amplification factors are computed for a variety of analysis types. The results of the current study show that the computed mean and standard deviation of amplification factor in ln units by considering only V _S uncertainty are in good agreement with the corresponding ones by considering V _S and modulus reduction and damping ratio variabilities simultaneously for the studied site. Furthermore, it seems that the effect of bedrock depth in definition of spectral shapes of the Iranian seismic building code should be taken into account.