Diamondiferous eclogites from Yakutia,Siberia: evidence for a diversity of protoliths

Major-element and REE compositions of 14 diamondiferous eclogites from the Udachnaya kimberlite in Yakutia, Siberia have been determined by electron microprobe and secondary ion mass spectrometer (SIMS). Based on previous clinopyroxene classification schemes (e.g., Taylor and Neal 1989), all of these eclogite xenoliths belong to Group B/C, although some of the garnet compositions and mineral REE abundances are inconsistent with the indicated groups. This demonstrates the inadequacy of the classification scheme based on African eclogites for application to Siberian samples. Because of the coarse grain size of the Udachnaya nodules, meaningful modal abundances could not be obtained. However, reconstructed REE compositions using various garnet: clinopyroxene ratios demonstrate relative insensitivity to changes in mode for common eclogitic assemblages. Many of these reconstructed REE compositions show LREE depletions. Some depletions are consistent with an origin (either directly or through partial melting) as normal or Type-I ocean floor basalt. Others, however, require material of eclogitic or pyroxenitic affinities to undergo partial melting; this facilitates the depletion of LREE while leaving the HREE at nearly original levels. Many of the eclogites of South Africa are consistent with a protolith of anomalous or Type II ocean floor basalt. This fundamental difference between the two regions is the likely cause of the inconsistencies with the chemicallybased classification.     

Gated communities of the Moscow green belt: newly segregated landscapes and the suburban Russian environment

The transition from the Soviet to the post-Soviet period in and near Moscow manifested itself in increasing production of segregated space both in the urban core and suburban areas outside of the beltway to accommodate the preferences of the new Russian business and governmental elite. This paper focuses on the residential single-family housing inside old and new settlements, which are frequently gated. Approximately 260 of such suburban communities have been developed within 30 km of the beltway during the past few years, of which a majority have some form of exclusion mechanism in place, typically tall solid fences, gates, closed-circuit video surveillance and guarded entry checkpoints. The difference in exclusivity varies from the most exclusive older communities inside Moscow Serebryany Bor enclave and Rublevskoe highway mansions to less exclusive new developments along Novorizkhskoe and Dmitrovskoe highways. Despite high rates of construction, based on sociological surveys in 2003, only about 11% of Russia’s upper class claimed to live in such new “cottages,” with the rest owning condos and luxury apartments in the inner city or older detached homes in villages and small towns. Therefore, not all the needs have been accommodated and more development is certain to take place. The environmental impact of such developments is profound. Based on preliminary LANDSAT image analysis, almost 22% of suburban “green belt” forested land within 30 km zone has been converted to new construction from 1991 to 2001. New construction is now focusing on the remaining fragments of natural vegetation, which will likely lower air quality and water quality available for the city. Ironically, the new developments advertise themselves as “clean and green” with massive investments in unnatural landscaping (seeded lawns, exotic shrubs, river and lake shore “improvements”). This investment highlights the well-known paradox of development in which people move out of town to live near nature, while destroying the wild nature they come to enjoy. “We left city for the weekend It was raining, saw no stars There were fences everywhere Our chiefs behind the bars.” Gennady Shpalikov     

Seismic anisotropy within the uppermost mantle of southern Germany

This paper presents an updated interpretation of seismic anisotropy within the uppermost mantle of southern Germany. The dense network of reversed and crossing refraction profiles in this area made it possible to observe almost 900 traveltimes of the P_n phase that could be effectively used in a time-term analysis to determine horizontal velocity distribution immediately below the Moho. For 12 crossing profiles, amplitude ratios of the P_n phase compared to the dominant crustal phase were utilized to resolve azimuthally dependent velocity gradients with depth. A P -wave anisotropy of 3–4 per cent in a horizontal plane immediately below the Moho at a depth of 30 km, increasing to 11 per cent at a depth of 40 km, was determined. For the axis of the highest velocity of about 8.03 km s⁻¹ at a depth of 30 km a direction of N31°F was obtained. The azimuthal dependence of the observed P_n amplitude is explained by an azimuth-dependent sub-Moho velocity gradient decreasing from 0.06 s⁻¹ in the fast direction to 0 s⁻¹ in the slow direction of horizontal P -wave velocity. From the seismic results in this study a petrological model suggesting a change of modal composition and percentage of oriented olivine with depth was derived.     

Mineral inclusions in diamonds from the Sputnik kimberlite pipe, Yakutia

The Sputnik kimberlite pipe is a small “satellite” of the larger Mir pipe in central Yakutia (Sakha), Russia. Study of 38 large diamonds (0.7-4.9 carats) showed that nine contain inclusions of the eclogitic paragenesis, while the remainder contain inclusions of the peridotitic paragenesis, or of uncertain paragenesis. The peridotitic inclusion suite comprises olivine, enstatite, Cr-diopside, chromite, Cr-pyrope garnet (both lherzolitic and harzburgitic), ilmenite, Ni-rich sulfide and a Ti-Cr-Fe-Mg-Sr-K phase of the lindsleyite-mathiasite (LIMA) series. The eclogitic inclusion suite comprises omphacite, garnet, Ni-poor sulfide, phlogopite and rutile. Peridotitic ilmenite inclusions have high Mg, Cr and Ni contents and high Nb/Zr ratios; they may be related to metasomatic ilmenites known from peridotite xenoliths in kimberlite. Eclogitic phlogopite is intergrown with omphacite, coexists with garnet, and has an unusually high TiO₂ content. Comparison with inclusions in diamonds from Mir shows general similarities, but differences in details of trace-element patterns. Large compositional variations among inclusions of one phase (olivine, garnet, chromite) within single diamonds indicate that the chemical environment of diamond crystallisation changed rapidly relative to diamond growth rates in many cases. P-T conditions of formation were calculated from multiphase inclusions and from trace element geothermobarometry of single inclusions. The geotherm at the time of diamond formation was near a 35 mW/m² conductive model; that is indistinguishable from the Paleozoic geotherm derived by studies of xenoliths and concentrate minerals from Mir. A range of Ni temperatures between garnet inclusions in single diamonds from both Mir and Sputnik suggests that many of the diamonds grew during thermal events affecting a relatively narrow depth range of the lithosphere, within the diamond stability field. The minor differences between inclusions in Mir and Sputnik may reflect lateral heterogeneity in the upper mantle.     

Database of molecular masers and variable stars

We present the database of maser sources in H2 O, OH and Si O lines that can be used to identify and study variable stars at evolved stages. Detecting the maser emission in H2 O, OH and Si O molecules toward infrared-excess objects is one of the methods for identifing long-period variables(LPVs, including miras and semiregulars), because these stars exhibit maser activity in their circumstellar shells. Our sample contains 1803 known LPV objects. Forty-six percent of these stars(832 objects) manifest maser emission in the line of at least one molecule: H2 O, OH or Si O. We use the database of circumstellar masers in order to search for LPVs which are not included in the General Catalogue of Variable Stars(GCVS). Our database contains 4806 objects(3866 objects without associations in GCVS) with maser detection in at least one molecule. Therefore it is possible to use the database in order to locate and study the large sample of LPV stars. The database can be accessed at http://maserdb.net.     

The formation of graphite upon the interaction of subducted carbonates and sulfur with metal-bearing rocks of the lithospheric mantle

Experimental studies of the Fe⁰–(Mg, Ca)CO₃–S system were carried out during 18–20 h at 6.3 GPa, 900–1400°C. It is shown that the major processes resulting in the formation of free carbon include reduction of carbonates upon redox interaction with Fe⁰ (or Fe₃C), extraction of carbon from iron carbide upon interaction with a sulfur melt/fluid, and reduction of the carbonate melt by Fe–S and Fe?S–C melts. Reconstruction of the processes of graphite formation indicates that carbonates and iron carbide may be potential sources of carbon under the conditions of subduction, and participation of the sulfur melt/fluid may result in the formation of mantle sulfides.