The carbohydrates in relation to mineralogic and granulometric composition of surface sediments in the karst estuary (River Krka estuary,Yugoslavia)

The investigation of mineral, granulometric and chemical composition of sediments of the River Krka estuary (Yugoslavia) were performed in order to elucidate the origin of the sediments and the pattern of sedimentation. Estuarine surface sediments were found to be fine-grained with a bimodal distribution. Environmental conditions in estuarine sediments favour conservation of the organic matter (anoxic conditions). The carbohydrates in the sediments were investigated to determine whether they are of terrigenous or authigenous origin. Glucose, galactose, mannose, xylose, rhamnose, glucosamine and glucuronic acid were detected in the sediments. Their mutual relationship indicates a preferentially terrigenous source of sedimented organic material in estuarine sediments.     

Application of the global modal approach to the spiral galaxies

We have tested the applicability of the global modal approach in the density wave theory of spiral structure for a sample of spiral galaxies with measured axisymmetric background properties. We report here the results of the simulations for four galaxies: NGC 488, NGC 628, NGC 1566, and NGC 3938. Using the observed radial distributions for the stellar velocity dispersions and the rotation velocities we have constructed the equilibrium models for the galactic disks in each galaxy and implemented two kinds of stability analyses - the linear global analysis and 2D-nonlinear simulations. In general, the global modal approach is able to reproduce the observed properties of the spiral arms in the galactic disks. The growth of spirals in the galactic disks can be physically understood in terms of amplification by over-reflection at the corotation resonance. Our results support the global modal approach as a theoretical explanation of spiral structure in galaxies. This revised version was published online in August 2006 with corrections to the Cover Date.     

Deuterated hydrogen molecule and search for early structure-formation signatures in the Universe

Possible detection of signatures of structure formation at the end of the 'dark age' epoch  ( z ∼ 40–20)  is examined. We discuss the spectral–spatial fluctuations in the cosmic microwave background radiation (CMBR) temperature produced by elastic resonant scattering of CMBR photons on deuterated hydrogen (HD) molecules located in protostructures moving with peculiar velocity. Detailed chemical kinematic evolution of HD molecules in the expanding homogeneous medium is calculated. Then, the HD abundances are linked to protostructures at their maximum expansion, whose properties are estimated by using the top-hat spherical approach and the Λ cold dark matter (ΛCDM) cosmology. We find that the optical depths in the HD three lowest pure rotational lines for high-peak protohaloes at their maximum expansion are much higher than those in LiH molecule. The corresponding spectral–spatial fluctuation amplitudes, however, are probably too weak to be detected by current and forthcoming millimetre telescope facilities. We extend our estimates of spectral–spatial fluctuations to gas clouds inside collapsed CDM haloes by using results from a crude model of HD production in these clouds. The fluctuations for the highest peak CDM haloes at redshifts ∼20–30 could be detected in the future. Observations will be important to test model predictions of early structure formation in the Universe.     

Exponential distance relations in planetary-like systems generated at random

It is often thought that the exponential distance relations that can be found amongst the distances of the planets and of the satellites of Jupiter, Saturn, and Uranus, of the form a _n = ⁿ , with a _n being the semi-major axis of the n ^th body, can be similarly represented by sequences of sorted random numbers generated with some constraints corresponding to certain physical processes. We give in this paper some indications showing that pure chance or random processes only cannot explain the planetary and satellite distance distributions, in particular the exponential spacings, by comparing the distance relations of the real systems to these of planetary-like systems generated at random.Exponential distance relations for the present planetary and satellites systems of Jupiter, Saturn and Uranus are described, considering the two cases without and with introduction of holes for the large spacings observed in the sequences of bodies.Random systems are created by generating distances at random following uniform, normal and exponential distributions, with no consideration for other orbital elements or masses as we are only interested in distance relations. Random systems without constraints are first compared to the real systems. In a following step, random systems with a corresponding number of bodies to that of the real systems and with the constraint of having a number of large spacings equivalent to that of the real systems are investigated. In a later step, we impose on the generation process the additional constraint of the closeness not too close condition, i.e. for the random systems to have distances between adjacent bodies greater than critical attraction distances calculated by considering the present masses of the real main planets and satellites.Comparisons of the regression coefficients means of the exponential distance relations of random systems to the characteristics of the real systems show that there are significant differences, in particular the coefficients of the random systems are on average smaller than for the corresponding real systems, except for some particular cases which are shown not to be significant.It is concluded that distance relations observed in the present real systems can not be compared to sequences of sorted random numbers. Furthermore, additional physical processes other than the closeness not too close, have to be considered to explain the observed distance relations and in particular the exponential spacings.     

The magnetic and thermodynamical structure of a coronal hole

A nonpolytropic model of a polar coronal hole at 2 R R 5 R is constructed. Our main assumptions are: (1) the magnetic structure of the Sun can be described by a combination of dipole-like and radial fields; (2) in the magnetically dominated region [(v ²/2) < (B ²/8)] the influence of the outflow on the magnetic structure is negligible. The magnetic and thermodynamic structures are obtained by solving the force balance equation for plasma with the observationally derived electron density. Profiles of velocities in the acceleration regime are presented and the influence of the outflow on the thermodynamic structure of the solar corona above the polar region is discussed.This paper is the first part of a joint project of the Space Environment Laboratory, the Joint Institute for Laboratory Astrophysics, and the High Altitude Observatory, NCAR. The second paper by Munro and Tzur is in preparation.Work done while at the Space Environment Laboratory, NOAA, ERL, Boulder, CO 80303, U.S.A.1982–83 Visiting Fellow at the Joint Institute for Laboratory Astrophysics, National Bureau of Standards and University of Colorado.The National Center for Atmospheric Research is sponsored by the National Science Foundation.Visitor at NCAR.     

Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia)

In this study, the molecular composition and biomarker distribution of lacustrine sediments from Val-1 drillhole in the central zone of the western part of the Valjevo-Mionica basin were investigated at depth interval of 0–400 m. Former investigations have shown that the core material can be separated into six depth intervals based on bulk geochemical, mineralogical and sedimentological characteristics. Concerning the quality of organic matter, presence of specific minerals, and high salinity and anoxicity, or alkalinity, three zones are of highest interest, defined at depth intervals of 15–75 m (A), 75–200 m (B) and 360–400 m (F). The first aim of the study was to identify which biomarkers characterize these specific intervals. The second aim, addressing the transitions zones of these intervals, was to extend the changes in the characteristics of the organic substance, to reflect the changes of conditions in the depositional environment as well as to define biomarker parameters which are the most sensitive sedimentological indicators.The sediments from the hypersaline anoxic and alkaline environment show high contribution of algal precursor biomass, what is in accordance with the good quality of organic substances in the sediments from these zones. High squalane content and low content of regular isoprenoid C₂₅ are typical for hypersaline anoxic environment, whereas sediments from alkaline environment have high regular isoprenoid C₂₅ content.Transition to specific sedimentation zones is characterized by change in total organic matter content, and of both free and pyrolysis-derived, and change in hydrogen index value. In the biomarker distributions, more significant changes were detected in distributions of n-alkanes and isoprenoids, compared to polycyclic alkanes. The most intensive changes in alkane distribution are reflected in changes in n-C₁₇ content compared to n-C₂₇, and phytane compared to n-C₁₈. In addition, significant sensitivity was seen in ratios between squalane and n-alkane C₂₆ (hypersaline depositional environment), or isoprenoid C₂₅ and n-alkane C₂₂ for high alkalinity environment.This study showed that Sq/n-C₂₆ ratio can be used to assess the quality of organic substance in immature lacustrine sediments.     

Reaction mechanism of uranyl in the presence of zero-valent iron nanoparticles

The current study provides an investigation of abiotic reduction of an oversaturated uranyl solution driven by iron nanoparticle oxidation. The reactivity of nano-scale zero-valent iron (ZVI) under mildly oxic conditions (1.2% O₂ and 0.0017% CO₂) was studied in 1000 ppm uranyl solution in the pH range 3-7, at reaction times from 10 min to 4 h. Reductive precipitation of UO₂ was observed as the main process responsible for the removal of uranium from solution with the kinetics of reaction becoming increasingly favourable at higher pH. Despite working with an oversaturated uranium solution, the precipitation of UO₂ occurred in preference to precipitation of UO₃·2H₂O (metaschoepite) at reaction times between 1 and 4 h and for uranyl solutions initially set up at pH ?5. Characterisation of both solid and solution phases was performed using X-ray photoelectron spectroscopy (XPS), focused ion beam (FIB) imaging, X-ray diffraction (XRD) and inductively coupled plasma atomic emission spectroscopy (ICP-AES).     

An aromatase inhibitor and tamoxifen decrease plasma levels of o,p'-DDT and its metabolites in Nile tilapia (Oreochromis niloticus)

The objective of this study was to determine if tamoxifen or an aromatase inhibitor (4-hydroxyandrostenedione; 4-OHA) affected plasma concentrations of o,p' -DDT and its metabolites, o,p'-DDD and o,p'-DDE, in mature tilapia. Male and female tilapia were injected 6 times intraperitoneally with o,p'-DDT (40 mg/kg) alone or in combination with 4-OHA (2 mg/kg) over a 12 day period. An additional group of male fish was injected with tamoxifen (5 mg/kg) plus o,p'-DDT. At the end of the treatment period, plasma samples were extracted and analyzed by GC/ECD. Females injected only with o,p'-DDT had significantly higher levels of o,p'-DDT compared with males. Interestingly, females and males treated concomitantly with o,p'-DDT and 4-OHA or tamoxifen had significantly lower concentrations of plasma o,p'-DDT (about 50%) compared with fish treated with only o,p'-DDT. These initial results suggest that an interaction between endocrine-active compounds occurs in vivo in tilapia and may involve alterations in metabolism of o,p'-DDT.     

Atlas of Japan (East) Sea hydrographic properties in summer, 1999

Hydrographic properties from CTD and discrete bottle sample profiles covering the Japan (East) Sea in summer, 1999, are presented in vertical sections, maps at standard depths, maps on isopycnal surfaces, and as property–property distributions. This data set covers most of the Sea with the exception of the western boundary region and northern Tatar Strait, and includes nutrients, pH, alkalinity, and chlorofluorocarbons, as well as the usual temperature, salinity, and oxygen observations.