Determining ammonia nitrogen decay rate of Malaysian river water in a laboratory flume

There is lack of information regarding ammonia nitrogen (AN), (i.e. NH₃-N) decay rate of river water in tropical regions like Malaysia. AN decay rate is a very important kinetic parameter to estimate NH₃-N, nitrate nitrogen (NO₃-N) and dissolved oxygen concentrations of river water by using computer models. This study presents determination of ammonia nitrogen decay rate of river water in the tropical environment of Malaysia. A laboratory flume was used to conduct twelve experiments. The flume was used to represent the turbulent condition of a typical river. Ammonia nitrogen decay rate for the tropical environment of Malaysia was observed to be between 0.194 and 0.554 per day. Median value of AN decay rate was 0.26 per day, which is slightly lower than the global median value of 0.295 per day. To check the accuracy of flume experiments, the AN decay rate of Pusu River obtained from the flume experiment was used to calibrate and validate ammonia nitrogen concentration of the river by using water quality analysis and simulation program (WASP). Very good calibration and validation results were achieved, which substantiated the accuracy of the flume experiments.     

Risk assessment of polycyclic aromatic hydrocarbons in the West Port semi-enclosed basin (Malaysia)

Sediment samples collected from the West Port, the west coastal waters of Malaysia, were analyzed by standard methods to determine the degree of hydrocarbon contamination and identify the sources of polyaromatic hydrocarbons (PAHs). Concentrations of PAHs in the port sediments ranged from 100.3 to 3,446.9 μg/kg dw. The highest concentrations were observed in stations close to the coastline, locations affected by intensive shipping activities and industrial input. These were dominated by high-molecular-weight PAHs (4–6 rings). Source identification showed that PAHs originated mostly pyrogenically, from the combustion of fossil fuels, grass, wood, and coal or from petroleum combustion. Regarding ecological risk estimation, only station 7 was moderately polluted, the rest of the stations suffered rare or slight adverse biological effects with PAH exposure in surface sediment, suggesting that PAHs are not considered as contaminants of concern in the West Port.     

Separation of Vanillin from Oil Palm Empty Fruit Bunch Lignin

The separation of vanillin from the lignin of empty fruit bunch oil palm is presented in this study. The lignin was extracted from soda black liquor derived from oil palm empty fruit bunches (EFB) using 20% sulfuric acid. Nitrobenzene oxidation was carried out by adding 50 mg of dry EFB lignin into a mixture of 7 mL of 2 M NaOH and 4 mL of nitrobenzene in a 15 mL steel autoclave. The autoclave was sealed tightly with a screw cap fitted with a Teflon gasket and heated to 165°C for 3 h in a preheated thermostatic oil bath. High performance liquid chromatography (HPLC) was used to determine the concentration of each compound present in the lignin. There were eight compounds detected in the HPLC chromatogram. The crystallization process was then used as a method to separate vanillin from other compounds. Based on the solubility of vanillin in acetone, 15 mL of acetone was added to the residue of the oxidized products and heated to 60°C for 10 min. A yield of 1.6% vanillin was isolated from a 50 mg lignin sample. The isolated compound was analyzed with HPLC, Fourier transform infrared spectrophotometry (FT‐IR) and nuclear magnetic resonance (¹³C‐NMR) for structural verification. The results of the characterization studies proved that the isolated compound is vanillin.     

Potential fish habitat mapping using MODIS-derived sea surface salinity,temperature and chlorophyll-a data: South China Sea Coastal areas,Malaysia

This paper demonstrates the use of moderate resolution imaging spectro-radiometer (MODIS) data for fish forecasting mapping of seasonal spatial distribution of sea surface salinity (SSS), temperature (SST) and chlorophyll-a in the ocean waters off the coast of Semporna, Malaysia. Multi-linear regression analysis was performed to estimate SSS and the Brown and Minnet algorithm was used for the SST. The extracted parameters were validated using in situ measurement taken with Hydro-Lab equipment. The extracted parameters from MODIS images reveal the signature values which establish the relationships between these parameters, and thus delineating the potential fish zonation (PFZ) map. These developed models will help for accurate monitoring of large coverage areas at low cost and within short period of time. Furthermore, such models will allow the prediction of the total fish catch in different seasons, thus contributing to fish industry management and marketing. This research recommends the use of PFZ map for mass scale fish harvesting in short time for larger areas. Finally, the research has developed a potential fish zone model amalgamating all the above parameters. The PFZ mapping was carried out off the coast of Semporna, Sabah as there were sufficient fish catch data for accuracy assessment. The R was computed as 0.93 and the higher fish catch areas have coincided very well with the higher PFZ values, meaning the tool is ready for use for operational near real-time fish forecasting.     

Predictive environmental impact assessment of total petroleum hydrocarbons in petrochemical wastewater effluent and surface sediment

The contamination level of total petroleum hydrocarbons (TPH) in wastewater and surface sediment samples from the Petrochemical Special Economic Zone (PETZONE) and adjacent coastal area in Musa Bay (in Northwest of Persian Gulf) was examined. Concentrations of TPH in the Musa Bay sediments ranged from 16.48 to 97.15 µg/g dry weight (dw) with average value of 48.98 ± 30.36 µg/g dw. The highest concentrations were estimated in stations close to the coastline, locations affected by intensive petrochemical discharges and shipping activities. The average TPH concentration in the PETZONE wastewater effluent samples was 5.22 mg/L, with a range of 0.06–35.33 mg/L. Regarding environmental impact assessment, the concentration of TPH was lower than the wastewater effluent discharge standard at most of the monitoring stations inside PETZONE companies, with the exception of stations 15, 16 (Imam Khomeini petrochemical company 1, 2) and 17 (Razi petrochemical company). These stations were considered as moderate environmental aspects, suggesting that concentration of TPH in the wastewater effluents of these petrochemical companies could be considered as contaminants of concern in the PETZONE area.     

Evaluation of tropical seaweeds as feedstock for bioethanol production

Limited resources of freshwater and decreasing fossil fuel resources are two main reasons to consider the ocean as a huge resource for producing food, feed, fertilizer and feedstock for fuel. In this study, twenty-nine tropical seaweeds (11 green, 10 red and 8 brown seaweeds) collected in Malaysia were assessed as potential feedstock for bioethanol production. Total carbohydrate content ranged from 12.16 to 71.22% dry weight (DW) with total reducing sugar content ranging from 5.17 to 34.12% DW. During hydrolysis using dilute sulphuric acid, the dominant fermentation inhibitors were 5-hydroxymethylfurfural and phenolic compounds. Overliming was found to reduce the content of fermentation inhibitors by up to 79%. The red seaweeds, Kappaphycus alvarezii (Doty) Doty ex P.C.Silva and Gracilaria manilaensis Yamamoto and Trono, were selected for optimization of saccharification and fermentation of the hydrolysate, because they had the highest carbohydrate contents and are commercially cultivated. The most suitable dilute acid conditions obtained in present study was sulphuric acid (2.5%, w v^?1) treatment at 121 °C for 40 min that produced 0.29 and 0.34 g g^?1 DW reducing sugar for K. alvarezii and G. manilaensis, respectively. Fermentation of the hydrolysates with Saccharomyces cerevisiae produced bioethanol yields of 20.90 g L^?1 (71.0% of theoretical yield) for K. alvarezii and 18.16 g L^?1 (67.9% theoretical yield) for G. manilaensis.     

Heavy metal contamination in water and sediment of the Port Klang coastal area, Selangor, Malaysia

This investigation presents the temporal and spatial distribution of heavy metals (As, Cd, Cr, Cu, Ni, Pb, Hg, and Zn), in water and in sediments of Port Klang, Malaysia. Water and sediment samples were collected from 21 stations at 3-month intervals, and contamination factor $ (C_{\text{f}} ) $ and contamination degree $ (C_{\text{d}} ) $ were calculated to estimate the contamination status at the sampling stations. Cluster analysis was used to classify the stations based on the contamination sources. Results show that concentrations of As, Cd, Hg, and Pb in sediment and As, Cd, Hg, Pb, Cr, and Zn in water were significantly higher than the background values at which these metals are considered hazardous. The main sources of heavy metal contamination in Port Klang were industrial wastewater and port activities.     

Newspapers as a validation proxy for GIS modeling in Fujairah,United Arab Emirates: identifying flood-prone areas

Prediction and control of blast-induced ground vibration is a matter of concern in mining industry since long. Several approaches ranging from scaled distance regression, different numerical methods to wave superimposition theories have been tried by many researchers for better prediction and control of blast-induced ground vibration. Signature hole analysis is one of the popular simulation methods to predict the ground vibration generated due to production blast. It superimposes the recorded signature hole waveform using a computer program to predict the production blast-induced vibration. The technique inputs the designated time of detonation of each hole and superimposes the waves generated by each hole to predict the nearest value of peak particle velocity and frequency of blast-induced ground vibration. Although a very useful approach, it requires a computer program to simulate the linear superimposition of waveforms. The simulation is not possible for every blast as it takes time and also is difficult for field engineers to simulate every time, whereas it is always easy for blasting engineers to adapt and use an empirical equation/approach for prediction and control of blast-induced ground vibration than simulation. In this paper, an attempt has been made to develop an innovative and simplified analytical approach of signature hole analysis. The simplified sinusoidal wave equation is obtained from recorded signature hole ground vibration waveform properties and is superimposed mathematically according to the multi-hole blast design to predict the production blast-induced ground vibrations. The validation of the developed approach was done in three different sites, and up to 15% more accuracy in prediction of the blast, vibrations are achieved in comparison with signature hole analysis prediction.

     

Functional relation of land surface albedo with climatological variables: a review on remote sensing techniques and recent research developments

Surface albedo has been documented as one of the Essential Climate Variables (ECV) of the Global Climate Observing System (GCOS) that governs the Earth's Radiation Budget. The availability of surface albedo data is necessary for a comprehensive environmental modelling study. Thus, both temporal and spatial scale issues need to be rectified. This study reports about the availability of surface albedo data through in-situ and remote sensing satellite observations. In this paper, we reviewed the existing models for surface albedo derivation and various initiatives taken by related environmental agencies in order to understand the issues of climate with respect to surface albedo. This investigation evaluated the major activities on albedo-related research specifically for the retrieval methods used to derive the albedo values. Two main existing albedo measurement methods are derived through in-situ measurement and remotely sensed observations. In-situ measurement supported with number of instruments and techniques such aspyrheliometers, pyranometers and Baseline Surface Radiation Network (BSRN) and remotely sensed observations using angularly integrated Bi-directional Reflectance Distribution Function (BRDF) by both geostationary and polar orbit satellites. The investigation results reveals that the temporal and spatial scaling is the major issues when the albedo values are needed for microclimatic study, i.e. high-resolution time-series analyses and at heterogeneity and impervious surface. Thus, an improved technique of albedo retrieval at better spatial and temporal scale is required to fulfil the need for such kind of studies. Amongst many others, there are two downscaling methods that have been identified to be used in resolving the spatial scaling biased issues: Smoothing Filter-based Intensity Modulation (SFIM) and Pixel Block Intensity Modulation (PBIM). The temporal issues can be resolved using the multiple regression techniques of land surface temperature, selected air quality parameters, aerosol and daily skylight.     

Copper(II) Biosorption on Soda Lignin From Oil Palm Empty Fruit Bunches (EFB)

The adsorption of Cu(II) ions from aqueous solutions by soda lignin as an absorbent using a batch adsorption system is presented in this paper. The soda lignin used in this study was extracted from black liquor derived from oil palm empty fruit bunches (EFB) using 20% v/v sulfuric acid. The effects of varying experimental parameters such as pH value, adsorbent dosage, different concentrations of Cu(II) ions, and agitation period were investigated. The results revealed that the optimum adsorption of Cu(II) onto soda lignin was recorded at a pH of 5.0 at an adsorbent dosage of 0.5 g soda lignin and an agitation period of 40 min. The adsorption capacities and rates of Cu(II) ions onto soda lignin was evaluated. The Langmuir and Freundlich adsorption models were applied to calculate the isotherm constants. It was found that the adsorption isothermal data could be well interpreted by the Freundlich model. The kinetic experimental data properly correlated with the pseudo‐second‐order kinetic model, which implies that chemical sorption is the rate‐limiting step.