The Magmatic–Hydrothermal Transition and Origin of Brine in the Oceanic Core Complex of the Mid-Atlantic Ridge at 13° N

New data on local mineral associations and the microheterogeneity of minerals and fluid inclusions in gabbro were obtained for the gabbro–peridotite oceanic core complex with a long-lived detachment fault controlling the hydrothermal activity. It is assumed that the hydrothermal hydrogen-bearing fluid with a NaCl content of >30 wt % is formed in the seawater/harzburgite (~1/5) reaction of serpentinization. The brine residual after serpentinization interacted with gabbro at the final stages of crystallization of an intrusion and assimilated some components (K, REEs, and Ba) from the residual melt. The interaction was resulted in metamorphic transformations of gabbro at decreasing temperature below 500°C. The reaction of the decomposition of magmatic titanomagnetite with the transition of iron reduced to Fe²⁺ into newly formed chlorinebearing amphibole at 540–450°C and logf(O₂) from–20 to–24 is shown.

     

Chemical composition of melts of the Early Eocene volcanic center at Cape Khairyuzova,western Kamchatka: Evidence from inclusions in minerals

Original authors’ data on the mineralogy and composition of melt inclusions in two samples show that the Early Eocene magmatic rocks at Cape Khairyuzova were formed by mixing melts of mafic, intermediate, and acid composition, which were derived from different sources. The mafic melt was rich in MgO, and its temperature was 1100–1150°C. The temperature of the acid melt varied from 1070 to 1130°C. The melts are also different in concentrations of trace elements and in their ratios. All three melt types are enriched in LILE and LREE and depleted in HFSE and were likely derived in suprasubductional environments. The mafic and intermediate magmas were formed by melting a mantle wedge and subsequent fractionation of the melts. The acid melts could be formed by melting crustal rocks when they were overheated in the newly formed orogen of significant thickness. When ascending, the mantle melts could mix in variable proportions with acid melts in crustal chambers.     

Recent massive sulfide deposits of the Semenov ore district, Mid-Atlantic Ridge, 13°31′ N: Associated rocks of the oceanic core complex and their hydrothermal alteration

The oceanic core complexes and large-offset detachment faults characteristic of the slow-spreading Mid-Atlantic Ridge are crucial for the structural control of large hydrothermal systems, including those forming sub-seafloor polymetallic sulfide mineralization. The structural-geological, petrographic, and mineralogical data are considered for the oceanic core complex enclosing the Semenov-1, -2, -3, -4, and -5 inactive hydrothermal sulfide fields recently discovered on the Mid-Oceanic Ridge at 13°31?? N. The oceanic core complex is composed of serpentinized and talc-replaced peridotites and sporadic gabbroic rocks, however, all hydrothermal fields reveal compositional indications of basaltic substrate. The volcanic structures superposed on the oceanic core complex are marked by outcrops of pillow lavas with fresh quenched glass. Dolerites regarded as volcanic conduits seem to represent separate dike swarms. The superposed volcanic structures develop largely along the near-latitudinal high-angle tectonic zone controlling the Semenov-1, -2, -5, and -3 hydrothermal sulfide fields. The manifestations of hydrothermal metasomatic alteration are diverse. The widespread talcose rocks with pyrrhotite-pyrite mineralization after serpentinite, as well as finding of talc-chlorite metabasalt are interpreted as products of hydrothermal activity in the permeable zone of detachment fault. Chloritization and brecciation of basalts with superposed quartz or opal, barite, and pyrite or chalcopyrite mineralization directly related to the sub-seafloor sulfide deposition. The native copper mineralization in almost unaltered basalts at the Semenov-4 field is suggested to precipitate from ore-forming fluids before they reach the level of sub-seafloor sulfide deposition. Amphibolites with plagiogranite veinlets are interpreted as tectonic fragments of the highest-temperature portions of hydrothermal systems, where partial melting of basic rocks in the presence of aqueous fluid with formation of plagiogranitic melt is possible. Silicic rocks (plagiogranite, tonalite and diorite) revealed in the tectonic zone controlling the Semenov-1, -2, -5, and -3 hydrothermal sulfide fields are related to both plutonic and subvolcanic bodies and considered to be products of partial melting of basic rocks at deep levels of the hydrothermal systems. The hydrothermal fields differ in their structural position. The giant Semenov-4 field is located at the area where the hanging-wall basalt wedges out and the detachment fault zone reaches the oceanic floor. The range of relatively small Semenov-1, -2, -3, and 5 fields develops on the oceanic core complex massif, being localized in the superposed volcanic structures within the near-latitudinal steeply dipping tectonic zone. The structural control of the hydrothermal fields at 13°31?? N is also interpreted in different ways. For the Semenov-4 field, the ascending fluid flow can be related to the permeable detachment fault zone. The root zone of the hydrothermal system with a magmatic heater could have been localized at a significant distance beneath the axial spreading zone. For the other four relatively small fields, it is suggested that the ascending fluid flows and roots of the hydrothermal systems are controlled by the volcanic structures superposed on the oceanic ore complex within the steeply dipping tectonic zone.     

Western Kamchatka-Koryak continental-margin volcanogenic belt: Age,composition, and sources

The isotope-geochemical study of the Eocene-Oligocene magmatic rocks from the Western Kamchatka-Koryak volcanogenic belt revealed a lateral heterogeneity of mantle magma sources in its segments: Western Kamchatka, Central Koryak, and Northern Koryak ones. In the Western Kamchatka segment, magmatic melts were generated from isotopically heterogeneous (depleted and/or insignificantly enriched) mantle sources significantly contaminated by quartz-feldspathic sialic sediments; higher ⁸⁷Sr/⁸⁶Sr (0.70429–0.70564) and lower ¹⁴³Nd/¹⁴⁴Nd(ɛ_Nd(T) = 0.06–2.9) ratios in the volcanic rocks from the Central Koryak segment presumably reflect the contribution of enriched mantle source; the high positive ɛ_Nd(T) and low ⁸⁷Sr/⁸⁶Sr ratios in the magmatic rocks from the Northern Koryak segment area indicate their derivation from isotopically depleted mantle source without significant contamination by sialic or mantle material enriched in radiogenic Sr and Nd. Significantly different contamination histories of the Eocene-Oligocene mantle magmas in Kamchatka and Koryakia are related to their different thermal regimes: the higher heat flow beneath Kamchatka led to the crustal melting and contamination of mantle suprasubduction magmas by crustal melts. The cessation of suprasubduction volcanism in the Western Kamchatka segment of the continentalmargin belt was possibly related to the accretion of the Achaivayam-Valagin terrane 40 Ma ago, whereas suprasubduction activity in the Koryak segment stopped due to the closure of the Ukelayat basin in the Oligocene time.     

Geodynamics and sources of preaccretionary magmatism in western Mongolia

The paper reports original isotopic and geochemical data on Early Precambrian lavas in the Ozernaya Zone in Mongolia. According to their normalized trace-element patterns, the rocks are classified into the following groups: (1) rocks similar to N-MORB; (2) rocks similar to E-MORB; (3) basalts enriched in trace elements, with HFSE minima; and (4) basalts depleted in trace elements, with HFSE minima. All of the lava types could be produced in an island arc—backarc basin system. The magmatic rocks of group (1) were likely formed in a spreading backarc basin, and those of group (2) were likely generated within the influ- ence zone of a hotspot or were derived from heterogeneous upper mantle domains. The lavas of group (3) seem to be fragments of an ensimatic, relatively primitive island arc. The basalts and basaltic andesites of group (4) were likely produced by mixing melts of groups (1) and (3). The fact that lavas of groups (1) and (4) sometimes intercalate within a single stratigraphic section suggests that the extension and subduction zones were closely spaced and operated simultaneously. The magmas of groups (1), (2), and (3) were derived from different mantle sources, which possessed different ratios of trace elements and were different in isotopic composition.     

Self-consistent problem of induced polarization of electrokinetic origin

In the first part of the paper, with some constraints, we find the analytical solution of the self-consistent problem of induced polarization (IP) for an electrokinetically polarized sphere. The stationary (on long time intervals) solution of the self-consistent problem is a set of the potential fields that are interconnected with each other: the exciting electric field, the extraneous hydrodynamical field (electroosmotic flow of a viscous incompressible fluid), and the resulting electromagnetic IP field. The extraneous field is the field of the osmotic flow of a charged liquid and the field of the charges that emerge due to the membrane effect in the narrowed segments of the pore channels. The calculations show that the IP fields derived by solving the self-consistent problem and by the Seigel-Komarov phenomenological approach are different. In the second part of the paper, by generalization of the obtained analytical solution, we formulate the self-consistent IP problem for isotropic σ-η media of arbitrary shape, which are bounded by a smooth surface. The problem can be solved by the numerical methods.     

Sources and geodynamic environments of formation of Vendian-Early Paleozoic magmatic complexes in the Daribi range,Western Mongolia

Rock complexes composing the Daribi Range were produced in Late Vendian, Early Cambrian, and Early Paleozoic suprasubduction systems. All of the studied mafic and ultramafic magmatic mantle rocks (the post-Vendian ophiolite complex, Early Cambrian pillow basalts, and Early Paleozoic picrobasalts of the sill-dike complex) have geochemical characteristics typical of early evolutionary episodes of island arcs: low LILE concentrations, horizontal REE patterns or patterns close to those of N-MORB, and HFSE minima. The magmas were derived from depleted mantle sources of variable isotopic composition with ?_Nd(T) from +2.5 to +10. The Early Paleozoic rocks of the sill-dike complex were likely produced by a complicated interaction of melts derived from different sources. The rocks of group 1 resulted from the mixing of low-K picrite and tonalite melts. The picrite melts with ?_Nd(T) from +6 to +8 were melted out of garnet lherzolite in the mantle wedge. The tonalite melts with ?_Nd(T) = ?3 seem to have been formed by the partial melting of mafic oceanic rocks of a subducted slab or the bottom of an island arc. The trondhjemite melts of group 2 with ?_Nd(T) varying from 2.5 to 7.5 could be formed via the melting of subducted metapelites or amphibolites with low sulfide concentrations. Massifs of sodic Early Paleozoic granites also occur elsewhere in western Mongolia, Tuva, and the Altai territory. The generation of sodic silicic melts was likely a common process in supra-subduction systems in CAFB. The potassic granites (group 4) could be formed by the melting of subducted pelites or by the fractionation of mantle magmas. The genesis of the basaltic andesites (group 5) was likely related to Mesozoic-Cenozoic intraplate processes.