河台金矿床垂深及横向剖面Au及伴生微量元素地球化学特征及矿床深部评价

不少韧性剪切带金矿床已由勘探转入开采，当前生产上急需解决的问题是矿床深部矿体延深评价。对河台金矿床矿山资料进行了二次开发，并在矿床沿垂深及横向剖面进行了系统取样分析，研究了河台金矿床Au与伴生微量元素在垂深及横向剖面上的地球化学行为。结果表明，Au及伴生微量元素在垂深及横向上含量变化具有不均匀性。矿床垂深剖面Au品位自上而下升高，Ag趋向于下降，Au/Ag比值升高，大部分变化范围为0.5-4.0,0m以下为0.38-7.0。据此判断目前揭露矿体属中上部。在矿床垂深剖面Au及伴生微量元素Bi,Se和S具有自上而下高的趋势；Ag和W自160m至0m则下降，Au/Ag,S/Se和Bi/Au比值自上而下升高，这可以作为矿体延深评价及找矿地球化学的指示剂。本矿床特征元素组合为Au-Ag-Bi-S-Cu-Se-As-W。矿床横向剖面中，Au,Ag,As,S,Cu,Bi,Se和W具有升高的规律，Au/Ag,S/Se,Cu/(Pb Zn)和W/Sn比值在上述序列岩石中具有升高的规律，而W／Au,Pb/Zn和Bi/Au则下降，这可以作为本矿找矿找矿地球化学指标。根据本矿床成矿地质条件及综合Au及微量元素的地球化学特征诸因素分析，本矿床成矿物质来源于混合岩，并与基底建造具密切关系。可以认为在0m中段往深部仍有具工业价值的矿体，河台金矿可发展成为超大型金矿床。     

粤西河台金矿床富硫化物石英脉Rb-Sr等时线年龄讨论

河台金矿床产于河台韧性剪切带中 ,成矿作用分为韧性剪切变质成矿期的韧性剪切变质成矿阶段和热液蚀变成矿期金石英脉阶段、金硫化物阶段和方铅矿闪锌矿碳酸盐脉阶段。金的成矿主要发生在金石英脉阶段和金硫化物阶段 ,形成的矿石有蚀变糜棱岩型和富硫化物石英脉型。富硫化物石英脉单矿物石英中富含以富CO2 液相为主的流体包裹体、流体熔融包裹体及熔融包裹体。与以往用流体包裹体热爆法和压碎法提取Rb、Sr的方法不同 ,本文用石英全溶法测得富硫化物石英脉中石英的Rb Sr等时线年龄为 172± 2Ma(1σ) ,初始比值为 0 .72 816± 0 .0 0 0 96 ,对比已有的同位素年龄数据及区域成矿特征 ,认为这一年龄值可能代表了河台金矿床的成矿年龄。     

Study on the Physical and Chemical Conditions of Ore Formation of Hetai Ductile Shear Zone—Hosted Gold Deposit and Discovery of Melt Inclusions

The Hetai ductile shear zone-hosted gold deposit occurs in the deep-seated fault mylonite zone of the Sinian-Silurian metamorphic rock series. In this study there have been discovered melt inclusions, fluid-melt inclusions and organic inclusions in ore-bearing quartz veins of the ore deposit and mylonite for the first time. The homogenization temperatures of the various types of inclusions are 160℃, 180 - 350℃, 530℃ and 870℃ for organic inclusions, liquid inclusions, two-phase immiscible liquid inclusions and melt inclusions, respectively. Ore fluid is categorized as the neutral to basic K+ -Ca2+ -Mg2+ -Na+ - SO2- 4-HCO3-Cl- system. The contents of trace gases follow a descending order of H2O＞CO2＞CH4＞(or ＜ ) H2＞CO＞C2H2＞C2I-I6＞O2＞N2.The concentrations of K , Ca2 + ,SO2-4,HCO3-,Cl- H2O and C2H2 in fluid inclusions are related to the contents of gold and the Au/Ag ratios in ores from different levels of the gold deposit. This is significant for deep ore prospecting in the region. Daughter minerals in melt inclusions were analyzed using SEM. Quartz, orthoclase, wollastonite and other silicate minerals were identified. They were formed in different mineral assemblages.This analysis further proves the existence of melt inclusions in ore veins. Sedimentary metamorphic rocks could form silicate melts during metamorphic anatexis and dynamic metamorphism, which possess melt-solution characteristics. Ore formation is related to the multi-stage forming process of silicate melt and fluid.     

韧性剪切带型金矿床矿物中熔融包裹体与矿床成因研究

在新疆乔尕山及广东河台韧性剪切带金矿床的含金石英脉及糜棱岩中首次发现熔融包裹体及流体一熔融包裹体，其均一化温度分别为780～960℃与600℃。用电子探针及扫描电镜能谱对熔融包裹体子矿物成分进行分析，通过56个熔融包裹体231个测点分析，鉴定出石英、白云母、黑云母、磁铁矿等十种子矿物，组成不同的矿物组合。子矿物常含Si、Al、Na、K、Au、Ag、Cu等元素。剪切带金矿床中熔融包裹体的发现为其成因研究提供了新依据，表明成矿与多阶段硅酸盐熔体及流体作用有关。