Mediterranean outflow through the Strait of Gibraltar since 18,000 Years B.P.: Mineralogical and geochemical arguments

Data obtained from mineralogical and geochemical analyses of piston and gravity cores, recovered from an area off Lisbon (Portugal) to the Alboran Sea (Mediterranean), serve as a basis for better understanding the past 18,000 years of hydrological exchanges at Gibraltar. Tracers used in this study are smectite, kaolinite, Ta, Th, La. One of the primary sources of particles both into and out of the Mediterranean is the Guadalquivir River. These particles are transported back into the Atlantic in the Mediterranean outflow water, and deposited along the Iberian slope. No evidence for reversal of this outflow current was found in those cores, since 18,000 years B.P.     

P‐wave stacking‐velocity tomography for VTI media

A major complication caused by anisotropy in velocity analysis and imaging is the uncertainty in estimating the vertical velocity and depth scale of the model from surface data. For laterally homogeneous VTI (transversely isotropic with a vertical symmetry axis) media above the target reflector, P‐wave moveout has to be combined with other information (e.g. borehole data or converted waves) to build velocity models for depth imaging. The presence of lateral heterogeneity in the overburden creates the dependence of P‐wave reflection data on all three relevant parameters (the vertical velocity V_P0 and the Thomsen coefficients ε and δ) and, therefore, may help to determine the depth scale of the velocity field. Here, we propose a tomographic algorithm designed to invert NMO ellipses (obtained from azimuthally varying stacking velocities) and zero‐offset traveltimes of P‐waves for the parameters of homogeneous VTI layers separated by either plane dipping or curved interfaces. For plane non‐intersecting layer boundaries, the interval parameters cannot be recovered from P‐wave moveout in a unique way. Nonetheless, if the reflectors have sufficiently different azimuths, a priori knowledge of any single interval parameter makes it possible to reconstruct the whole model in depth. For example, the parameter estimation becomes unique if the subsurface layer is known to be isotropic. In the case of 2D inversion on the dip line of co‐orientated reflectors, it is necessary to specify one parameter (e.g. the vertical velocity) per layer. Despite the higher complexity of models with curved interfaces, the increased angle coverage of reflected rays helps to resolve the trade‐offs between the medium parameters. Singular value decomposition (SVD) shows that in the presence of sufficient interface curvature all parameters needed for anisotropic depth processing can be obtained solely from conventional‐spread P‐wave moveout. By performing tests on noise‐contaminated data we demonstrate that the tomographic inversion procedure reconstructs both the interfaces and the VTI parameters with high accuracy. Both SVD analysis and moveout inversion are implemented using an efficient modelling technique based on the theory of NMO‐velocity surfaces generalized for wave propagation through curved interfaces.     

Thorium and uranium isotopes in a manganese nodule from the Peru basin determined by alpha spectrometry and thermal ionization mass spectrometry (TIMS): Are manganese supply and growth related to climate?

Thorium- and uranium isotopes were measured in a diagenetic manganese nodule from the Peru basin applying alpha- and thermal ionization mass spectrometry (TIMS). Alpha-counting of 62 samples was carried out with a depth resolution of 0.4 mm to gain a high-resolution²³⁰Th_excess profile. In addition, 17 samples were measured with TIMS to obtain precise isotope concentrations and isotope ratios. We got values of 0.06–0.59 ppb (²³⁰Th), 0.43–1.40 ppm (²³²Th), 0.09–0.49 ppb (²³⁴U) and 1.66–8.24 ppm (²³⁸U). The uranium activity ratio in the uppermost samples (1–6 mm) and in two further sections in the nodule at 12.5±1.0 mm and 27.3–33.5 mm comes close to the present ocean water value of 1.144±0.004. In two other sections of the nodule, this ratio is significantly higher, probably reflecting incorporation of diagenetic uranium. The upper 25 mm section of the Mn nodule shows a relatively smooth exponential decrease in the²³⁰Th_excess concentration (TIMS). The slope of the best fit yields a growth rate of 110 mm/Ma up to 24.5 mm depth. The section from 25 to 30.3 mm depth shows constant²³⁰Th_excess concentrations probably due to growth rates even faster than those in the top section of the nodule. From 33 to 50 mm depth, the growth rate is approximately 60 mm/Ma. Two layers in the nodule with distinct laminations (11–15 and 28–33 mm depth) probably formed during the transition from isotopic stage 8 to 7 and in stage 5e, respectively. The Mn/Fe ratio shows higher values during interglacials 5 and 7, and lower ones during glacials 4 and 6. A comparison of our data with data from adjacent sediment cores suggests (a) a variable supply of hydrothermal Mn to sediments and Mn nodules of the Peru basin or (b) suboxic conditions at the water sediment interface during periods with lower Mn/Fe ratios.     

Effet du vieillissement des céramiques poreuses sur leur capacité à évaluer la concentration de pesticide en solution

The soil solution sampling by ceramic cups allows pesticide transfer monitoring in the soil during long times. The ageing of material involves a bias in the sampling results. In laboratory, the comparison of two types of ceramic suction cups, new and installed in situ during four years, shows a modification of the hydrodynamic properties and a possible evolution of the adsorption capacity of the matrix. The passage rate, as well qualitative as quantitative, is better for the old material. Recommendations about site management are finally exposed. To cite this article: N. Domange et al., C. R. Geoscience 336 (2004).     

The two-step shape and timing of the last deglaciation in Antarctica

The two-step character of the last deglaciation is well recognized in Western Europe, in Greenland and in the North Atlantic. For example, in Greenland, a gradual temperature decrease started at the Bölling (B) around 14.5 ky BP, spanned through the Alleröd (A) and was followed by the cold Younger Dryas (YD) event which terminated abruptly around 11.5 ky BP. Recent results suggest that this BA/YD sequence may have extended throughout all the Northern Hemisphere but the evidence of a late transition cooling is still poor for the Southern Hemisphere. Here we present a detailed isotopic record analyzed in a new ice core drilled at Dome B in East Antarctica that fully demonstrates the existence of an Antarctic cold reversal (ACR). These results suggest that the two-step shape of the last deglaciation has a worldwide character but they also point to noticeable interhemispheric differences. Thus, the coldest part of the ACR, which shows a temperature drop about three times weaker than that recorded during the YD in Greenland, may have preceded the YD. Antarctica did not experienced abrupt changes and the two warming periods started there before they started in Greenland. The links between Southern and Northern Hemisphere climates throughout this period are discussed in the light of additional information derived from the Antarctic dust record.     

ESR dating of fluvial quartz: Estimate of the minimal distance transport required for getting a maximum optical bleaching

An ESR experimental study of artificial optical bleaching of sedimentary quartz has shown that the aluminum center was maximally bleached after a 6-month illumination equivalent to natural light. This duration seems too long to apply in natural conditions. Nevertheless, the measurement of the ESR intensity of aluminum centers in quartz extracted from modern sediments and deposited in sandy bars shows that the maximum bleaching has effectively been reached.

In order to determine the relationship between the bleaching and the distance covered by a quartz grain in a river, samples were collected along the Creuse River (France) from its spring to about 170 km downstream, where maximum bleaching levels were observed in previous studies. The ESR intensities of the aluminum and titanium centers in quartz were measured, using X-band spectroscopy, before and after artificial bleaching. The difference measured between these sub-samples shows that the maximum bleaching level is obtained in the course of the first kilometer. Hence, the assumption that ESR dating of fluvial sediment is based on the optical bleaching was validated.     

ESR dating in Song Terus cave (East Java, Indonesia)

Electron spin resonance (ESR) dating on teeth has been used to determine the antiquity of the human presence in the area of Gunung Sewu (East Java, Indonesia). The Song Terus cave is one of the archaeological sites located in this area, which has yielded an important collection of fossil bones and prehistoric lithic industry. ESR dating shows that this cave belongs to a karstic system which has been in place since Middle Pleistocene. The results of coupled ESR/Uranium-series dating indicates closed system for uranium in tooth tissues yielding ages of between 216 and 392 ka for the oldest archaeological levels, confirming the possibility of finding Middle Pleistocene human occupations in such karstic sites in Java.     

On the interest and the limits of using combined ESR/U-series model in the case of very late uranium uptake

Before ESR/U-series models were applied to ungulate teeth, it is generally assumed that calculated ages are close to the “real” ages when they range between the values obtained with the EU and LU models. When the samples show signs of uranium-leaching, a realistic mathematical modelling of the age is not possible. On the other hand, some samples have undergone a very late U-uptake “affecting” directly the U-series ages and rendering the calculated ages younger.

We present results obtained on two open-air sites, which show the limits of such combined models in the case of late uranium incorporation. For the Middle Pleistocene site of Isernia la Pineta (Italy), the ESR dates are expected to fall within the limits imposed by the Ar–Ar results. The other site, the Lower Palaeolithic deposits of Ambrona (Spain), yielded two sets of samples: some at the top of the sequence with uranium uptake ranging between EU and LU limits and thus giving a good idea of the “real” age of the site; others at the base displaying a very late U-uptake, which render an age determination difficult.     

Tableau de répartition stratigraphique des Grands Foraminifères caractéristiques du Crétacé moyen de la région Méditerranéenne

Le Groupe de Travail Européen des Grands Foraminifères présente un tableau de répartition stratigraphique de 42 espèces bien définies du Crétacé moyen de la région méditerranéenne. La répartition stratigraphique proposée pour chaque espèce est fondée soit sur des propres observations soit sur des données de la littérature supprimer et est contrôlée par la présence d'Ammonites ou de Foraminifères planctoniques.A summarizing account is presented of the deliberations of the research group for Large Foraminifers of the IGCP Project “Mid-Cretaceous Events”. Large Foraminifers are of incontestable value for dating carbonate platform sequences owing to the absence of many other diagnostic groups of organísms. A table of stratigraphical distributions for 42 species is presented.     

Distribution and spatial variation of hydrothermal faunal assemblages at Lucky Strike (Mid-Atlantic Ridge) revealed by high-resolution video image analysis

Whilst the fauna inhabiting hydrothermal vent structures in the Atlantic Ocean is reasonably well known, less is understood about the spatial distributions of the fauna in relation to abiotic and biotic factors. In this study, a major active hydrothermal edifice (Eiffel Tower, at 1690 m depth) on the Lucky Strike vent field (Mid-Atlantic Ridge (MAR)) was investigated. Video transects were carried out by ROV Victor 6000 and complete image coverage was acquired. Four distinct assemblages, ranging from dense larger-sized Bathymodiolus mussel beds to smaller-sized mussel clumps and alvinocaridid shrimps, and two types of substrata were defined based on high definition photographs and video imagery. To evaluate spatial variation, faunal distribution was mapped in three dimensions. A high degree of patchiness characterizes this 11 m high sulfide structure. The differences observed in assemblage and substratum distribution were related to habitat characteristics (fluid exits, depth and structure orientation). Gradients in community structure were observed, which coincided with an increasing distance from the fluid exits. A biological zonation model for the Eiffel Tower edifice was created in which faunal composition and distribution can be visually explained by the presence/absence of fluid exits.