西秦岭与赛什塘铜矿床有关的花岗质岩石岩浆源区特征及大地构造背景探讨

西秦岭赛什塘铜矿区内出露的三叠纪花岗质岩石有闪长玢岩、石英闪长岩、石英闪长玢岩、花岗斑岩和石英斑岩,其岩浆源区与形成构造环境可为古特提斯洋演化和区域成矿作用研究提供证据。岩石地球化学特征共同表明,这些花岗质岩石属于准铝质钙碱性-高钾钙碱性系列,为I型花岗岩;Mg#值变化较大(39~68),LREE富集,HREE亏损,(La/Yb)N比值介于8.50~22.9,具有Eu负异常,δEu介于0.28~0.78,同时富集大离子亲石元素Cs、Rb、K、Pb,亏损高场强元素Nb、Ta、Ti,呈现出与典型俯冲作用密切相关岛弧花岗岩相一致地球化学特征。石英闪长玢岩和石英斑岩SHRIMP锆石U-Pb年龄分别为219.0±2.3Ma和220.0±2.0Ma,锆石εHf(t)分别为-4.5~-2.1和-2.5~+1.0,对应二阶段模式年龄分别为1392~1544Ma和1190~1415Ma。结合前人对西秦岭三叠纪花岗岩以及其南侧阿尼玛卿蛇绿混杂带研究成果,本文认为赛什塘铜矿区花岗质岩石与西秦岭同时期花岗岩形成于与古特提斯洋向北俯冲密切相关的大陆边缘弧环境,其岩浆源区为中元古代下地壳变基性岩,且岩浆可能受到地幔物质混染。     

南祁连拉脊山口增生楔的结构与组成特征

造山带内增生楔/增生杂岩结构与组成的精细研究可为古洋盆演化和古板块构造格局重建提供最直接证据。北祁连构造带发育多条增生杂岩带,记录了阿拉善和中祁连地块之间原特提斯洋的俯冲和闭合过程,然而南祁连构造带大地构造演化长期存在争议。地质填图结果表明,南祁连构造带拉脊山口地区存在一套强烈片理化的玄武岩、灰黑色和红色硅质岩、砂岩和泥岩组合,它们与一套呈现"块体裹夹于基质"结构特征的混杂岩共同构成了增生杂岩,发育双重逆冲构造、逆冲断层、无根褶皱、紧闭褶皱和透入性面理。该增生杂岩与蛇绿岩之间为断层接触,并位于断层下盘。混杂岩是由斜长花岗岩(561Ma)、斜长岩(507Ma)、辉绿岩、玄武岩、硅质岩和砂岩等外来或原地岩块与浊流成因的细碎屑岩基质共同组成;基质和砂岩块体均发育同沉积构造,呈现出滑塌堆积典型特征。空间上,拉脊山口增生杂岩与上覆蛇绿岩被断层所分割且共同仰冲于中祁连南缘青石坡组浊积岩之上,具有与东侧昂思多地区增生杂岩和蛇绿岩相似的岩石组成、构造变形和时空结构特征。它们与南侧的岛弧带共同构成了南祁连构造带寒武纪-早奥陶世沟-弧体系,指示了寒武纪-早奥陶世时期南祁连洋盆向南俯冲。     

The components and carbon isotope of the gases in inclusions in reservoir layers of Upper Paleozoic gas pools in the Ordos Basin,China

The components and carbon isotope of gases in inclusions are one of the most important geochemical indexes for gas pools. The analysis results of the components and carbon isotope of gases from inclusions in reservoir layers of Upper Palaeozoic gas pools in the Ordos Basin show that most inclusions grown in reservoir sandstone are primary inclusions. There is only a little difference about the components and carbon isotope between the well gases and the secondary inclusions gases. This indicated that the epigenetic change of gas pools is little. This difference between the well gases and the secondary inclusions gases is caused by two reasons: (i) The well gases come from several disconnected sand bodies buried in a segment of depth, while the inclusion gases come from a point of depth. (ii) The secondary inclusions trapped the gases generated in the former stage of source rock gas generation, and the well gases are the mixed gases generated in all the stages. It is irresponsible to reconstruct the palaeo-temperature and palaeo-pressure under which the gas pool formed using carbon dioxide inclusions.     

拉脊山口蛇绿混杂岩中辉绿岩的地球化学特征及SHRIMP锆石U-Pb年龄

拉脊山口蛇绿混杂岩是分布于中祁连和南祁连构造带之间蛇绿混杂带的重要组成部分。该混杂带中的岩石种类相对齐全,各岩性间为构造接触;其中辉绿岩以岩块和岩墙两种形式产出。辉绿岩块SiO₂含量为49.80%~50.13%,MgO含量为5.43%~5.64%,FeO^T为10.96%~11.52%,TiO₂含量较高（2.38%~2.62%）;辉绿岩墙SiO₂含量为43.41%~45.74%,MgO含量为9.04%~10.64%,FeO^T为8.39%~9.96%,TiO₂含量较低（0.89%~1.02%）,二者均属拉斑玄武岩系列。其中辉绿岩块ΣREE为135.4×10^-6~150.9×10^-6,（La/Yb）_N=3.51~4.03,具有右倾型稀土配分模式,富集Rb、Ba、K、Sr等大离子亲石元素及Th、Nb、Ta、Zr、Hf、Ti等高场强元素,呈现洋岛拉斑玄武岩特征;辉绿岩墙ΣREE为36.10×10^-6~43.72×10^-6,（La/Yb）_N=1.12~1.20,稀土配分曲线相对平坦,呈现出与洋中脊玄武岩相似的稀土和微量元素配分模式。这两类辉绿岩样品均缺乏Nb、Ta和Ti负异常,可能分别形成于洋岛/海山和洋中脊环境。SHRIMP锆石U-Pb测年结果显示,辉绿岩块形成时代为491.0±5.1Ma。这些不同构造属性的辉绿岩可能形成于原特提斯洋向北俯冲消减过程。     

Numeric modelling and risk assessment of pollutions in the Chinese Bohai Sea

To simulate the dynamic process of total nitrogen (TN) in seas, numerical modelling combined with the adjoint method is implemented in this study. Because nonpoint source terms (ST) and initial values (IV) of TN are essential but difficult to determine, the adjoint method was applied to a numerical model, and the ST and IV terms of TN were inverted via routine monitoring data in the Bohai Sea. In twin experiments, the adjoint method was capable of inverting the prescribed spatio-temporally distributed ST and the spatial distributed IV. In practical experiments, the results demonstrated that the simulation precision with ST inversion was higher than that with IV inversion and was accurate with joint initial values and source term (IST) inversion. This result indicates that nonpoint source TN is essential for the simulation of TN concentration. Furthermore, the simulated results indicate that the pollution in three bays of the Bohai Sea is rather severe. The model in this study is not specific to the Bohai Sea and can be generalized to other areas, such as the Beibu Gulf. These findings may assist in the development of cost-effective controls for accidental or planned industrial pollutant releases into coastal waters.     

库鲁克塔格地区新元古代沉积物源分析:来自碎屑锆石年代学的证据

库鲁克塔格位于南天山和塔里木盆地接合部,保留相对较完整的地层记录。新元古代贝义西组主要为一套火山-沉积组合序列,育肯沟组为浊流成因的砂岩和粉砂岩组合。对取自两个地层的沉积岩样品,分别进行了碎屑锆石LA-ICP-MS U-Pb测年,并分别获得了93组和71组U-Pb有效年龄。其中贝义西组锆石U-Pb年龄主峰值为821Ma、次峰值为861Ma的碎屑锆石(761~847Ma)具有显著优势,育肯沟组年龄值为768Ma(次峰值为800Ma和741Ma)的碎屑锆石比较集中,说明库鲁克塔格地区在741Ma、768Ma、800Ma、821Ma和861Ma有大规模的岩浆活动。10个太古代碎屑锆石年龄以及综合已有的研究成果,确认库鲁克塔格存在中-新太古代基底。贝义西组砂岩主要源自761~847Ma、851~972Ma和1808~2498Ma岩石。育肯沟组主要来自734~845Ma、858~963Ma和1708~2486Ma的岩石。     

西秦岭谢坑矽卡岩型铜金矿床地质特征与矿区岩浆岩年代学研究

谢坑铜金矿床位于西秦岭造山带西段,区域内主要出露下二叠统大关山群和下三叠统隆务河群,构造和岩浆活动发育.岩石学研究表明,谢坑铜金矿区内出露侵入岩主要为辉长闪长岩和辉长岩,它们是岗察岩体的重要组成部分.在辉长闪长岩与二叠纪灰岩接触带部位发育铜金和铁矿化并形成相关工业矿体.矿石类型主要有块状、脉状和浸染状三类.磁铁矿、磁黄铁矿表现为块状,黄铜矿为脉状和浸染状;脉状和浸染状黄铜矿穿插于块状磁铁矿矿石现象十分普遍,含金碳酸盐石英脉主要沿着矿石裂隙发育.围岩蚀变呈现清晰的蚀变分带现象,自岩体向外依次表现为钾化、青磐岩化和矽卡岩化.其中矽卡岩化主要发育于辉长闪长岩与灰岩接触带部位,与成矿关系密切,磁铁矿矿化主要发育于晚期矽卡岩阶段,磁黄铁矿、黄铁矿、黄铜矿等金属硫化物以及毒砂等矿物主要形成于早期硫化物阶段,金矿化主要发育于石英硫化物阶段.LA-ICP-MS锆石U-Pb测年结果表明,辉长闪长岩和角闪安山岩分别形成于243.8±1.0Ma和242.1±1.2Ma.该成岩、成矿时代与区城构造岩浆、成矿事件相一致.这些结果表明,谢坑铜金矿床为与西秦岭中三叠世孤岩浆作用密切相关的矽卡岩型矿床.     

山阳-柞水矿集区李家砭Ti-Fe矿床成矿构造背景研究

李家砭Ti-Fe矿床位于南秦岭山阳-柞水矿集区内南侧山阳-凤镇构造混杂带内,主要表现为钛磁铁矿和钛铁矿化,含矿围岩为堆晶辉长岩。矿物组合特征及结构分析表明,该矿床为典型的岩浆分异型矿床。矿物成分和岩石地球化学分析结果共同表明李家砭杂岩体具有岛弧钙碱性和大洋板内玄武岩双重岩浆性质。辉长岩SHRIMP锆石U-Pb测年结果表明,李家砭辉长岩和Ti-Fe矿床形成于621±6Ma,其中所含有的继承性锆石来自新元古代晚期岛弧中酸性岩浆岩,以上特征表明李家砭Ti-Fe矿床形成于新元古代晚期弧后盆地构造背景下。     

The surface geochemical exploration of oil and gas in the Gangbatong-Ya’anxiang and the Dongqiao-Nam Co of the Qinghai-Tibet region

Due to the complexity of geological background and the adverseness of natural geographical environment in the Qinghai-Tibet Plateau, it is very difficult to carry out petroleum geological study in this region. The Qinghai-Tibet Plateau is the only blank space of petroleum exploration on a large scale. The authors carried out the surface geochemical exploration of oil and gas in the Gangbatong-Ya’anxiang and Dongqiao-Nam Co of the Qinghai-Tibet region. Based on the data of actual detection and experiments in the studied area, the characteristics of concentration and profile distribution of the main geochemical exploration indicators (total adsorbed hydrocarbon, altered carbonate, thermal released mercury, etc.) were discussed. The origin of hydrocarbon was also discussed. Moreover, the oil and gas potential of different sections in the Qiangtang Basin and the Biru Basin were evaluated, which could provide references for the exploration and prediction of oil and gas in this region. The concentrations of total adsorbed hydrocarbons in the Ya’anxiang of Suoxian County-Zadong of Baqing County and the Jiecha-Dangxiong of Anduo County in the Qinghai-Tibet region are high, averaging 312.64 μL·kg⁻¹ and 164.36 μL·kg⁻¹. Their altered carbonate concentrations are relatively low, averaging 0.11% and 0.56%. Their concentrations of thermal released mercury are relatively high, averaging 13.09×10⁻⁹ and 1.94×10⁻⁹. Geochemical exploration results in fact reflect hydrocarbon information in the underground, which are mainly petroleum associated gas and over-matured cracking gas. The Jiecha-Charenluma and the Xiamaya’ertong-Suoba sections in the Qiangtang Basin are the most favorable ones for oil and gas and the Ekou-Zadong section is relatively favorable one, while the Nam Co and the Zigetangcuo-Dongqiao sections in the Biru Basin are the favorable ones for oil and gas, and the Jiang Co-Nading Co and the Ya’anxiang-Ya’ertong sections are relatively favorable ones.

     

江苏句容-黄桥地区有机包裹体形成期次和捕获温度、压力的PVTsim模拟计算

据流体包裹体显微镜观测和石油包裹体群的气体色谱和全烃色谱、色谱-质谱分析结果，句容和黄桥地区三叠系和下二叠系地层中的石油包裹体明显不同，句容地区三叠系灰岩储层中的石油包裹体的个体较大，在透光下为黄色一棕黄色，荧光显微镜下发亮黄色荧光，包裹体中气态烃的C1／C2-5，比值较低，液态烃中三环萜炕、五环三萜烷和规则甾烷系列的生物标志物化合物含量比较丰富，而句容和黄桥地区下二叠系石油包裹体比较细小，发黄色-黄绿色荧光，包裹体中气态烃的C1／C2-5。比值较高，液态烃中均难检测到甾萜烷系列的生物标志物。由流体包裹体均一温度等观测资料与捕获温度、捕获压力的PVTsim的模拟计算结果：句容地区三叠系储层的石油包裹体捕获温度Tr=107．9℃，捕获压力Pr=289bar，约相当于白垩纪晚期（90～83Ma）充注成藏。句容地区下二叠深灰色灰岩中分布的油包裹体的捕获温度Tr=123℃，捕获压力Pr=305．95bar，反映白垩系晚期还有一期温度比较高的含烃流体充注的现象。黄桥地区在含CO2气藏的下二叠系存在有交切关系的，黄色和黄绿色两种荧光性质不同的石油包裹体，前者模拟计算的捕获温度Tr=97．3℃，捕获压力Pr=184．75bar，后者模拟计算的捕获温度Tr=145．5℃，捕获压力Pr=220．05bar，分别相当于白垩纪晚期（95～90Ma）和白垩纪末期（65～60Ma）有合烃流体运聚现象。但是，由于在白垩纪末-第三纪的抬升作用阶段，油气大量散失，因此在喜山期大量无机CO2充注成藏时期，储层中已不合烃类流体。