Speciation of adsorbed yttrium and rare earth elements on oxide surfaces

The distribution of yttrium and the rare earth elements (YREE) between natural waters and oxide mineral surfaces depends on adsorption reactions, which in turn depend on the specific way in which YREE are coordinated to mineral surfaces. Recent X-ray studies have established that Y³⁺ is adsorbed to the rutile (1 1 0) surface as a distinctive tetranuclear species. However, the hydrolysis state of the adsorbed cation is not known from experiment. Previous surface complexation models of YREE adsorption have suggested two to four cation hydrolysis states coexisting on oxide surfaces. In the present study, we investigate the applicability of the X-ray results to rare earth elements and to several oxides in addition to rutile using the extended triple-layer surface complexation model. The reaction producing a hydrolyzed tetranuclear surface species

     

Second-order wave loading on a horizontal rectangular cylinder of substantial draught

Approximate first- and second-order analytical solutions of wave diffraction of a semi-submerged horizontal cylinder of rectangular cross-section are presented. The solutions are based on the assumption that the pressure in the fluid domain underneath the cylinder is linearly dependent on the horizontal space coordinate. Basically, this approach is valid when the clearance between the bottom of the cylinder and the sea bottom is small in comparison with the wave length and is recommended for a cylinder of substantial draught where due to the small clearance other methods are difficult to apply. Boundary conditions are satisfied by a choice of a proper form of the potential functions and by making use of the properties of matching conditions. Theoretical results reveal that the magnitude of the vertical second-order time-dependent loads could be significant and even exceed the corresponding first-order quantities. This phenomenon, which occurs even at moderate steepnesses, as well as the assumption of a linear pressure distribution, are confirmed by experiments performed in a wave tank.     

Prediction of UT1–UTC,LOD and AAM χ<Subscript>3</Subscript> by combination of least-squares and multivariate stochastic methods

This article presents the application of a multivariate prediction technique for predicting universal time (UT1–UTC), length of day (LOD) and the axial component of atmospheric angular momentum (AAM χ ₃). The multivariate predictions of LOD and UT1–UTC are generated by means of the combination of (1) least-squares (LS) extrapolation of models for annual, semiannual, 18.6-year, 9.3-year oscillations and for the linear trend, and (2) multivariate autoregressive (MAR) stochastic prediction of LS residuals (LS + MAR). The MAR technique enables the use of the AAM χ ₃ time-series as the explanatory variable for the computation of LOD or UT1–UTC predictions. In order to evaluate the performance of this approach, two other prediction schemes are also applied: (1) LS extrapolation, (2) combination of LS extrapolation and univariate autoregressive (AR) prediction of LS residuals (LS + AR). The multivariate predictions of AAM χ ₃ data, however, are computed as a combination of the extrapolation of the LS model for annual and semiannual oscillations and the LS + MAR. The AAM χ ₃ predictions are also compared with LS extrapolation and LS + AR prediction. It is shown that the predictions of LOD and UT1–UTC based on LS + MAR taking into account the axial component of AAM are more accurate than the predictions of LOD and UT1–UTC based on LS extrapolation or on LS + AR. In particular, the UT1–UTC predictions based on LS + MAR during El Niño/La Niña events exhibit considerably smaller prediction errors than those calculated by means of LS or LS + AR. The AAM χ ₃ time-series is predicted using LS + MAR with higher accuracy than applying LS extrapolation itself in the case of medium-term predictions (up to 100 days in the future). However, the predictions of AAM χ ₃ reveal the best accuracy for LS + AR.     

Probabilistic seismic hazard evaluation in underground mines

Stress concentrations produced by rock deformation due to extraction in underground mines induce seismicity that can take the shape of violent and quite dangerous rockbursts.The hazard evaluation presented in this paper is based on a Bayesian probabilistic synthesis of information determined from mining situations during excavation, with previous and present data from microseismicity and seismoacustics.The method proposed in this study is an example of time-dependent on-line seismic hazard evaluation. All results presented were obtained retrospectiely for different underground coal mines in Poland and Czechoslovakia.On leave from Institute of Geophysics, Polish Academy of Sciences 01-452 Warszawa, ul. Ksiecia Janusza 64, Poland.     

Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.     

Redbed-type gold mineralisation, Kupferschiefer, south-west Poland

A new type of gold mineralisation containing minor amounts of platinum and palladium has been found proximal to the secondary redox interface located below the Cu-Ag Kupferschiefer orebody of the Polkowice-Sieroszowice mine in the south-western part of the Lubin-Sieroszowice district, Poland. This deposit can be classified as redbed-type gold. Our study shows that gold, platinum and palladium occur in secondary red-coloured sections of the basal Zechstein sedimentary rocks and in the uppermost Weissliegendes sandstone. Noble metal mineralisation occurs within an average interval of 0.22 m, which lies directly below the copper ores. The average grade of the horizon is 2.25 ppm Au, 0.138 ppm Pt and 0.082 ppm Pd with a metal content of several tens of tonnes of gold. A transition zone has been recognised between the gold-bearing horizon and the copper deposit. This transition zone is characterised by the presence of low grades of copper (<0.2 wt%) and elevated gold contents (>0.5 ppm). Native gold accompanied by electrum, mercury-bearing gold, haematite, covellite, chalcocite, bornite and chalcopyrite has been identified in the gold-bearing horizon. In some sections, Pd-arsenides, tetra-auricupride, Co-arsenides, clausthalite, tennantite, digenite, yarrowite, spionkopite and galena have also been noted.     

Pollution history and recovery of a boreal lake exposed to a heavy bleached pulping effluent load

We examined the effects of heavy pulp mill discharges on the Lake Lievestuoreenjärvi ecosystem and the later recovery of diatom and chironomid communities from age-dated short core samples. Beginning in 1927 the lake received a heavy effluent load from a sulphite pulp mill. Except for the recession during the Second World War and the temporary closure of the mill from 1967 to 1971, the industrial load, containing large quantities of nutrients, organic matter and toxic compounds, increased continuously. In the early 1980s, laboratory documents were falsified by the directors of the mill and the systematic illegal effluent overload led to a collapse of the whole lake ecosystem. In 1985, the outdated plant was finally closed down. Based on the assessment of chemical properties and biological remains of the sediment, we distinguished five developmental phases in the ecological state of the lake. In the pre-industrial phase, the pelagic and profundal benthic communities were dominated by species preferring ultraoligotrophic or oligotrophic lakes. Concomitant with the increasing discharge and deposition of chlorine compounds, resin acids, and mercury, as well as strong acidity and hypolimnetic and epilimnetic anoxia, the ecological status changed in a short period from excellent to bad. Finally, in the early 1960s, the majority of the lake was virtually dead and the aquatic life survived only in the uppermost littoral zone. Since 1985, a fast recovery in the water quality has led to a strong, but temporary eutrophy in pelagic communities. The main peak of eutrophication was caused by the invasion of a species new to the lake,Aulacoseira granulata var.angustissima. Later, the pelagic communities shifted towards oligotrophy, but the original, pre-industrial status has not been re-established. The profundal benthic communities have not achieved the pre-industrial structure, but at present indicate mesotrophy.     

Deciphering late Devonian–early Carboniferous P–T–t path of mylonitized garnet-mica schists from Prins Karls Forland,Svalbard

Quartz-in-garnet inclusion barometry integrated with trace element thermometry and calculated phase relations is applied to mylonitized schists of the Pinkie unit cropping out on the island of Prins Karls Forland, western part of the Svalbard Archipelago. This approach combines conventional and novel techniques and allows deciphering of the pressure–temperature (P–T) evolution of mylonitic rocks, for which the P–T conditions could not have been easily deciphered using traditional methods. The results obtained suggest that rocks of the Pinkie unit were metamorphosed under amphibolite facies conditions at 8–10 kbar and 560–630°C and mylonitized at ~500 to 550°C and 9–11 kbar. The P–T results are coupled with in-situ Th–U-total Pb monazite dating, which records amphibolite facies metamorphism at c. 359–355 Ma. This is the very first evidence of late Devonian–early Carboniferous metamorphism in Svalbard and it implies that the Ellesmerian Orogeny on Svalbard was associated with metamorphism up to amphibolite facies conditions. Thus, it can be concluded that the Ellesmerian collision between the Franklinian margin of Laurentia and Pearya and Svalbard caused not only commonly accepted brittle deformation and weak greenschist facies metamorphism, but also a burial and deformation of rock complexes at much greater depths at elevated temperatures.     

A Holocene high-resolution record of aquatic productivity,seasonal anoxia and meromixis from varved sediments of Lake Łazduny,North-Eastern Poland: insight from a novel multi-proxy approach

Anthropogenic eutrophication and spreading anoxia in freshwater systems is a global concern. Little is known about anoxia in earlier historic times under weaker human impact, or under prehistoric natural conditions with different trophic, land cover and climatic regimes. We use a novel approach that combines high-resolution hyperspectral imaging with µ-XRF and HPLC-pigment data, which allows us to assess chloropigments (productivity) and bacteriopigments (anoxia) at seasonal subvarve-scale resolution. Our ~9700 cal a bp varved sediment record from NE Poland suggests that productivity increased stepwise from oligotrophic Early Holocene conditions (until ~9200 cal a bp ) to mesotrophic conditions in the Mid- and Late Holocene. Natural eutrophication was mainly a function of progressing landscape evolution with intense weathering under dense forest and warm-moist climatic conditions. Generally, anoxia increased with increasing productivity. Seasonal anoxia and some multi-decadal periods of meromixis were the common mixing patterns throughout the Holocene except for a period of persisting meromixis between ~5200 and 2000 cal a bp. Anthropogenic deforestation around 400 cal a bp resulted in substantially better lake oxygenation despite high productivity. In this small lake, aquatic productivity and lakeshore forest cover (wind shield) were more important factors controlling oxic/anoxic conditions than Holocene temperature variability.