Petrology of the Baszkówka L5 chondrite: A record of surface‐forming processes on the parent body

Abstract— We review the petrology of Baszkówka, present new microprobe data on mineral constituents, and propose a model for surface properties of the parent body consistent with these data. The low shock index and high porosity of the Baszkówka L5 chondrite mean that considerable primary textural and petrographic detail is preserved, allowing insight into the structure and evolution of the parent body. This meteorite formed in a sedimentary environment resembling that in which pyroclastic rocks are deposited. The origin of the component chondrules, achondritic fragments (mostly olivine and pyroxene aggregates), chondritic‐achondritic aggregates, and compound chondrules can be explained by invoking collision of 2 melted or partially melted planetesimals, each covered with a thin crust. This could have happened at an early stage in the evolution of the solar system, between 1 and 2 Myr after its origin. The collision resulted in the formation of a cloud containing products of earlier magmatic crystallization (chondrite and achondrite fragments) from which new chondrules were created. Particle collision in this cloud produced fragmented chondrules, chondritic‐achondritic aggregates, and compound chondrules. Within this low‐density medium, these particles were accreted on the surface of the larger of the planetesimals involved in the collision. The density of the medium was low enough to prevent grain‐size sorting of the components but high enough to prevent the total loss of heat and to enable the welding of fragments on the surface of the body. The rock material was homogenized within the cloud and, in particular, within the zone close to the planetesimal surface. The hot material settled on the surface and became welded as molten or plastic metal, and sulfide components cemented the grains together. The process resembled the formation of welded ignimbrites. Once these processes on the planetesimal surface were completed, no subsequent recrystallization occurred. The high porosity of the Baszkówka chondrite indicates that the meteorite comes from a near‐surface part of the parent body. Deeper parts of the planetesimal would have been more massive because of compaction.     

Composition of brines in halite‐hosted fluid inclusions in the Upper Ordovician,Canning Basin,Western Australia: new data on seawater chemistry

Analyses of primary and early diagenetic fluid inclusions in the halite from the Late Ordovician Mallowa Salt, Canning Basin, Western Australia indicate a Ca‐rich composition and high concentration of parent brines in the basin which were close to sylvite and carnallite precipitation. The salt‐bearing series in the sampled interval was overheated up to 62 °C. The recorded differences in gas compositions result from the input of several gas sources including dispersed organic matter in the salt series and hydrocarbon deposits in the underlying rocks. The high concentration of the brines in fluid inclusions does not allow quantitative reconstruction of the chemical composition of Late Ordovician parent seawater. Using the information from Early Cambrian and Late Silurian basins as a proxy, however, the new data indicate that Late Ordovician seawater was undoubtedly Ca‐rich and, in comparison with modern seawater, had a similar K content, considerably lower Mg content (c. 30%), approximately three times the Ca content and one‐third the SO₄ content.     

Alkaline and ultramafic carbonate lamprophyres in Central Bohemian carboniferous basins,Czech Republic

Summary Dykes of alkaline and ultramafic carbonate lamprophyres (monchiquite-ouachitite and aillikite) intrude the Carboniferous sediments of Central Bohemia. Their characteristic feature is the presence of substantial amounts of a sodalite group mineral (presumably haüyne), carbonate and barite. Isotopic compositions of ¹³C (–3.4 to –6.2) and ¹⁸O ( + 13.5 to + 15.9) indicate that the carbonate is of primary magmatic origin and that fluids were formed at temperatures of 500 to 350°C. High contents of CO₂ (3.6 to 17.6 wt.%) and incompatible elements, high LREE/HREE ratios (30.0 to 57.7), and low Rb/Sr (0.025 to 0.078) and⁸⁷Sr/⁸⁶Sr (0.7038 to 0.7042) ratios suggest the ultramafic lamprophyres are related to deep-seated carbonated magmas of mantle origin. Low degree of partial melting ( < 1%) of the mantle peridotite is envisaged, with additional transport of fluids rich in incompatible elements into the crustal chamber. Alkaline lamprophyres are fractionated derivatives which originated from the same source. Magma intrusion from different levels of a magma chamber into fracture zones under horizontal tension without a central intrusion could result in variability in lamprophyre composition (cumulates or evolved derivatives).

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Alkalische und ultramafische Karbonat-Lamprophyre der zentralen böhmischen Karbonbecken, Tschische Republik

Zusammenfassung Alkalische und ultramafische Karbonat-Lamprophyrgänge (Monchiquit-Ouachitit und Aillikit) intrudieren in karbonische Sedimente Zentralböhmens. Sie sind charakterisiert durch das Auftreten von beträchtlichen Mengen an Mineralen der Sodalith-Gruppe (v.a. Haüyn), Karbonaten und Baryt. Ihre Isotopenzusammensetzung von ¹³C (–3.4 bis –6.2) und ¹⁸O (13.5 bis 15.9) zeigt, daß die Karbonate primär magmatischen Ursprungs sind und daß assoziierte Fluide in einem Temperaturbereich von 350 bis 500°C gebildet wurden. Hohe Gehalte an CO₂ (3.6 bis 17.6 Gew. %), inkompatiblen Elementen, hohe LREE/HREE-Verhältnisse (30.0 bis 57.7), sowie niedrige Rb/Sr—(0.025 bis 0.078) und⁸⁷Sr/⁸⁶Sr-(0.7038 bis 0.7042) Verhältnisse lassen vermuten, daß die ultramafischen Lamprophyre mit karbonatischen Magmen des Mantels in Beziehung stehen. Eine niedrige Aufschmelzungsrate ( < 1%) von Mantelperidotit mit zusätzlichem Transport von, an inkompatiblen Elementen angereicherten Fluiden, in die krustale Magmenkammer wird diskutiert. Alkalische Lamprophyre sind als stärker fraktionierte Magmen, die derselben Quelle entstammen, zu verstehen. Die Intrusion der aus verschiedenen Bereichen der Magmenkammer stammenden Magmen in durch horizontale Dehnung verursachte Störungszonen könnte das Fehlen eines zentralen Intrusionskörpers und die unterschiedliche Zusammensetzung der Lamprophyre (Kumulate oder entwickelte Derivate) erklären.

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With 8 Figures     

Verification of the dualism ordering method by the canonical correspondence analysis: fish community samples

Two ordination techniques (Romaniszyn diagram, RD, and Canonical correspondence analysis, CCA) were applied to the same data set (fish assemblage composition along two Paraná river tributaries and associated environmental variables), to identify spatial community patterns and further to evaluate the performance of RD. The major patterns in these Brazilian streams were successfully revealed by both methods (i.e. clear separation of both tributaries on the basis of fish assemblage composition and environmental factors), but more complex situations may limit the application of RD in comparison with CCA.     

Complex behaviour of a coal sample in a large scalein situ compression test

Summary A large scalein situ compression test of a laminated coal cube is described. The cube was uniformly loaded by a system of hydraulic jacks supplied simultaneously from one pump. At the same time both load and deformations were controlled. Deformations were measured by 60 longitudinal gauges located at the side surface of the cube in the regular net. Due to the heterogeneity of the rock the readings showed scatter. As a first approximation, the scattered data were fitted to the plane using the least square method. Orientations of the planes were analysed and show permanent relative movement between adjacent lamina indicating complex behaviour of the cube under loading. Detailed analysis of this behaviour indicated that the cube was subjected to both bending and twisting.     

Studies on Intercorrelation between Ions Co-Occurring in Precipitation in the Gdańsk-Sopot-Gdynia Tricity (Poland)

The paper presents monitoring results and environmental pollution assessment for the Gdask-Sopot-Gdynia Tricity (Poland), based onanalysis of precipitation. Precipitation samples were collected over a period of 12 months (January–December 1998) at ten locations in the Tricity. The following selected ions were determined in the samples:SO₄ ^2–, F^–, Cl^–, NO₃ ^–,PO₄ ^3–, NH₄ ⁺, Na⁺,Mg²⁺, Ca²⁺, K⁺. The results were subjected to full statistical evaluation. Values of the parameters determined were correlated with each other. An attempt was made to explain co-occurrences of certain ions and the significance of their mutual effects. Pollutant concentrations and loads in precipitation were also correlated with data on wind direction and temperature in the region.Deposition of pollutants was very high in spring due to the prevailing air circulation patterns and low temperatures. Analysis of the correlations between co-occurring ions confirmed the significant impact of the location (sea coast) on the composition of rain water. Ionic ratios in rainwater were similar to those observed for sea salt samples. In addition, heavy traffic was most probably responsible for high concentrations of various forms of nitrogen and sulphates in the vicinity of major highways.     

Amazonite from the alkali granite of the Avdar Massif,Mongolia

Summary The green feldspar in alkali granite from the Avdar deposit of decoration stone (150 km W of Ulan-Bator) has been identified by means of physical and chemical methods as amazonite. Its structural state corresponds to that of microcline with a high degree of triclinicity and displaying the following anomalous dimensions of the unit cell (nm):a=0.8568,b=1.2967,c=0.7217 nm, =90.732, =115.851, =87.702°;V=0.72115 nm³.The amazonite contains in increased amount of Pb (1950 ppm) as well as of Rb (1.15 mass %). The genesis of this amazonite is associated with younger metasomatic processes in the alkali granite.

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Amazonit aus dem Alkali-Granit des Avdar-Massivs, Mongolei

Zusammenfassung Der grüne Feldspat im Alkaligranit aus der Dekorationsstein-Lagerstätte im Avdar Massiv (150 km W von Ulan-Bator) wurde auf Grund physikalischer und chemischer Methoden als Amazonit bestimmt. Sein Strukturzustand entspricht demjenigen eines Mikroklins, der eine hohe Triklinität und anomale Elementarzelle aufweist (in nm):a=0.8568,b=1.2967,c=0.7217 nm, =90.732, =115.851, =87.702°;V=0.72115 nm³.Der Amazonit hat einen erhöhten Gehalt an Pb (1950 ppm) und an Rb (1.15 Gew.-%). Die Genesis dieses Amazonits ist mit jüngeren metasomatischen Prozessen im Alkaligranit verknüpft.

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With 1 Figure     

Significance of stromatolites for the environmental interpretation of the Buntsandstein (Lower Triassic) rocks

When interpreting the depositional environment of the Buntsandstein sequence, thin stromatolite layers, if present, were often overlooked or given short shrift. The present paper provides evidence of value of stromatolites for the environmental interpretation of the Buntsandstein rocks. Algal stromatolites found in western Poland occur in form of thrombolites, LLH-type structures, SH-type structures, and rarely as oncolites. Stromatolites are usually associated with oolites. Very often stromatolites show important traces of scouring and channelling action of water. Since stromatolites occurred in the zone of clastic-carbonate deposition they were covered up by continuous sheet of detrital grains. Periodic catastrophic erosion and deposition was produced by hurricanes and severe storms in the peritidal and shallow subtidal zone. It is possible to distinguish the peritidal and subtidal stromatolites. In the vicinity of stromatolites are of frequent occurrence spirorbids, conchostracs, gastropods, and rare foraminifers. Besides, spirorbids are associated with stromatolites — they constituted the initial hard substratum for the stromatolitic structures and sometimes they also occur inside stromatolites. The not-hypersaline sedimentary environment of the Buntsandstein rocks can be compared with modern environments of the Persian Gulf and the Gulf of Aqaba.     

5-alkylsalicylaldoximes as collectors in flotation of sphalerite,smithsonite and dolomite in a Hallimond tube

Flotation tests for sphalerite, smithsonite and dolomite were carried out in a Hallimond tube at various pH values and two concentrations of collector.Adsorption of 5-alkylsalicylaldoximes on the surface of minerals was examined and isotherms for 5-butylsalicylaldoxime plotted.It was shown that sorption intensity of 5-alkylsalicylaldoximes on the surface of minerals decreased in the order: smithsonite, sphalerite and dolomite.Relationship between length of aliphatic chain and collecting activity of 5-alkylsalicylaldoximes was investigated in microflotation tests in a Hallimond tube.5-Propylsalicylaldoxime proved to have the best selectivity in flotation for the range of parameters studied, taking the difference in flotation rates of smithsonite and dolomite as a criterion.It was found that modifications of pH value resulted in changes in both adsorption and flotation.