Raman microspectrometry, FT-IR and inclusion characteristics of gem garnets from Tanzania and Madagascar

Chemical composition, Raman microspectrometry, and Fourier transform infrared (FT-1R) and SEM-CL (Cathodluminescence) analyses are carried out for Tanzania and Madagascar garnets for locality identification. Inclusion study was sustained after electron probe microanalysis (EPMA). Needle-like illmenites, apatites and zircons were the most common solid inclusions in Tanzania garnets. Madagascar garnets revealed rutile needles and apatites were also observed, but differences in size, shape and distribution patterns were noticed compared to Tanzania garnets. Tanzania garnets exhibited all types of observable fluid inclusions such as ““ fingerprint““ pattern, called Type Ⅰ-A, liquid-only (L) single phase fluid inclusion, called Type Ⅰ-B and Type Ⅱ-A ( L S), Type Ⅱ-B ( L V) and Type Ⅲ-A (L Sylvite even if all examined garnets from three localities retained ““fingerprint““ features, so called, partially healed fractures, in common. Chemical composition, Raman microspectrometry and Fourier transform infrared (FT-IR) analysis taken turned out to be useful methods for the purpose of this study. Using consequences of SEM-CL and inclusion study, accordingly, the locality identification of gem-quality garnets is capable of being available in further application for other kinds of gemstones.     

The sediment-water interface increment due to the complex burrows of macrofauna in a tidal flat

The architecture of macrofaunal burrows and the total area of the sediment-water interface created by biogenic structure were investigated in the Donggeomdo tidal flat on the west coast of Korea. Resin casting methods were applied to recover burrows of four dominant species, Macrophthalmus japonicus, Cleistostoma dilatatum, Perinereis aibuhitensis, and Periserrula leucophryna, and whole burrows within the casting area at three sites in different tidal levels.P. leucophryna excavated the largest burrow in terms of a surface area among them. In the case of whole burrow casting, the space occupied by the biogenic structure was extended into deeper and expanded more greatly at the higher tidal level. In the uppermost flat, the burrow wall surface area within sediment was more extensive than the sediment surface area. Increased oxygen supply through the extended interface could enhance the degradation rates of organic carbon and also change the pathways of degradation. Quantifying the relationship between the extended interface and mineralization rate and pathway requires more extensive study.     

Some stability properties of large-scale baroclinic flows with nonlinear zonal current profile

The stability properties of a baroclinic zonal current with nonlinear velocity profile are investigated. The integral method is applied to the governing eigenvalue equation having the vertical velocity as the dependent variable. Expressed in terms of the Rossby number and the Richardson number, stability criteria, unstable regions in the complexc plane, and the upper bound of the unstable wave growth rate are found. Some differences in the results are noted between the present model and the quasi-geostrophic streamfunction model, particularly in connection with the effect of the velocity profile curvature termU _zz . It is conjectured in the present model that, depending on extreme behaviors ofU _zz , the propagation speed of unstable waves can be greater thanU _max or smaller thanU _min .     

Description of the post larva of star pipefish,halicampus punctatus (syngnathidae, gasterosteiformes) first found in the southwestern east sea, Korea

Larval specimens ofHalicampus punctatus were collected off Ulsan and Uljin in December 2002 (three specimens) and off Ulsan in December 2003 (one specimen). These specimens are characterized by the following morphological characteristics: rings, 14 + 35 = 49; subdorsal rings, 1 + 3 = 4; dorsal fin rays, 19 – 20; pectoral fin rays, 14 – 15; anal fin rays, 9; head length (HL), 5.8 – 6.7 in the standard length; snout length, 1.9 in HL; snout depth, 3.7 – 5.2 in snout length. The number of caudal fin rays 9 is less than those of the other species in the same genus 10. Wide stripe bands composed of small pigments are shown in the trunk and the tail. Melanophores are not found in the dorsal fin, the pectoral fin, and the anal fin except the caudal fin. The supraoccipital crest is on the head. The frontal ridge is on the dorsal side of front trunk. The blanched ridges on the opercular are fused with a main ridge like a tree branch. A few branched ridges that are small and narrow on the trunk and the tail are fused with the main ridges. We report these specimens as the first record in Korea and name them ‘Byeol-silgo-ki’ in Korean.     

A comparison of several wave spectra for the random wave diffraction by a semi-infinite breakwater

A comparison of the diffraction of multidirectional random waves using several selected wave spectrum models is presented in this paper. Six wave spectrum models, Bretschneider, Pierson–Moskowitz, ISSC, ITTC, Mitsuyasu, and JONSWAP spectrum, are considered. A discrete form for each of the given spectrum models is used to specify the incident wave conditions. Analytical solutions based on both the Fresnel integrals and polynomial approximations of the Fresnel integrals and numerical solutions of a boundary integral approach have been used to obtain the two-dimensional wave diffraction by a semi-infinite breakwater at uniform water depth. The diffraction of random waves is based on the cumulative superposition of linear diffraction solution. The results of predicted random wave diffraction for each of the given spectrum models are compared with those of the published physical model presented by Briggs et al. [1995. Wave diffraction around breakwater. Journal of Waterway, Port, Coastal and Ocean Engineering—ASCE 121(1), 23–35]. Reasonable agreement is obtained in all cases. The effect of the directional spreading function is also examined from the results of the random wave diffraction. Based on these comparisons, the present model for the analysis of various wave spectra is found to be an accurate and efficient tool for predicting the random wave field around a semi-infinite breakwater or inside a harbor of arbitrary geometry in practical applications.     

Geophysical and geochemical observations on actively seeping hydrocarbon gases on the south-eastern Yellow Sea continental shelf

In the southeastern Yellow Sea, active seepage of hydrocarbon gases has been observed by high-resolution (3.5 kHz) seismic profiling both in 1987 and 2001, occurring through a large number of plumes from the topmost pre-Holocene sedimentary layer. It is strong enough to compensate for current speed, extending vertically up to the sea surface. The gas seepage often appears to be explosive to form craters and diapirs, although pockmarks are rare due to the redistribution of mobile palimpsest sands. In core-top seawater and sediments, the gases are characterized by high amounts of C₂, homogenous ¹³C₁ values and a large difference (19.7 on average) between ¹³C₁ (–55.2 to –53.6 PDB) and ¹³C₂ (–36.8 to –32.5 PDB) values. The gases are considered to be generated with a smaller amount of C₁ at the early thermal cracking stage of labile source materials, after which the C₂ gas is enriched in ¹³C by diffusion or biological alternation at the generation or accumulation site. The homogenous ¹³C₁ values may be one of the geochemical characteristics of gases acquired at depth which are less altered in the case of rapid diffusive gas migration to the seafloor.     

Bacterioplankton growth and production at the Louisiana hydrocarbon seeps

The growth rate and potential production of bacterioplankton in cold hydrocarbon seeps located along the Louisiana coast were determined using a pulse-labeling technique. Surprisingly, community doubling times are on the order of 1.1 h, which compares to laboratory-grown cultures. We also found that there are differences in growth rates on relatively small geographic scales, suggesting the influence of site-specific geological features (e.g., gas hydrate mounds). Proceeding downslope to deeper waters, methane-oxidizing bacteria appeared to play a more significant role in community productivity. These preliminary experiments indicated, quite unexpectedly, that water column microbes are growing at a more rapid rate than in any other marine system so far studied and that methane may serve as a primary nutrient (carbon) source in these seep-associated microbial assemblages.     

Evaluation of bending moments and shear forces at unit connections of very large floating structures using hydroelastic and rigid body analyses

This paper investigates the characteristics of bending moments, shear forces and stresses at unit connections of very large floating structures (VLFS) under wave loads. The responses of VLFS are calculated by solving multi-body motion equation considering hydroelasticity and connection stiffness. Hydroelastic responses are calculated by the direct method. Higher-order boundary element method (HOBEM) is used for fluid analysis and finite element method (FEM) is introduced for structural analysis. The equation of motion is modified to describe the unit connections by employing spring elements. Bending moments and shear forces at the connections are obtained from the dynamic equilibrium condition for pressures and inertia forces. Two types of VLFS units such as tandem arranged units and side-by-side arranged units are considered in the numerical examples. The influences of connection stiffness, wave frequency and heading angle on responses of VLFS are investigated through the numerical examples. Rigid body analysis along with hydroelastic analysis is also carried out in the numerical analysis and comparison of those two approaches is discussed.     

硫酸皮肤素寡糖的分离与制备

利用软骨素酶 ABC (Chondroitinase ABC,EC4 .2 .2 .4 )对硫酸皮肤素 (Dermatan Sul-fate,DS)进行控制降解。对得到的混合寡糖首先采用低压凝胶渗透色谱 (L PGPC)进行分级 ,然后对每一组分再利用强阴离子交换高压液相色谱 (SAX- HPL C)进行分离 ,最终制备出聚合度为 2 ,4 ,6 ,8,10 ,12的寡糖纯品。寡糖纯度采用 SAX- HPL C,毛细管电泳 (CE)以及聚丙烯酰胺凝胶电泳(PAGE)进行检验 ,结构采用电喷雾离子化质谱 (ESI- MS)以及核磁共振波谱 (NMR)技术确定     

Species composition and spatial distribution of euphausiids of the yellow sea and relationships with environmental factors

We investigated species composition and spatial distribution of the euphausiid community in the Yellow Sea and identified the relationship with environmental factors (temperature, salinity, chlorophyll a, nitrate, phosphate, and silicate) using bimonthly data from June, 1997 to April, 1998. The environment varied during the sampling period. In warm seasons, thermocline was well developed rendering lower temperature and higher salinity and nutrient concentrations in the bottom layer. During cold seasons the water column was well mixed and no such vertical stratification was noted. Horizontal distribution of temperature, however, differed slightly between near-coast and offshore areas because of the shallow depth of the Yellow Sea, and between southern and northern areas because of the intrusion of water masses such as Yellow Sea Warm Current and Changjiang River Diluted Water. Four euphausiid species were identified:Euphausia pacifica, E. sanzoi, Pseudeuphausia sp. andStylocheron affine. E. sanzoi andS. affine were collected, just one juvenile each, from the southern area in June and December, respectively.Pseudeuphausia sp. were collected in the eastern area all the year round except June.E. pacifica occurred at the whole study area and were the predominant species, representing at least 97.6% of the euphausiid abundance. Further, the distribution pattern of the species was varied in regards to developmental stages (adult, furcilia, calyptopis, egg). From spring to fall,E. pacifica adults were abundant in the central area where the Yellow Sea Bottom Cold Water prevailed. Furcilia and calyptopis extended their distribution into nearly all the study area during the same period. From late fall to winter, adults were found at the near-coastal area with similar pattern for furcilia and calyptopis. The distribution pattern ofE. pacifica was consistent regarding temperature, salinity, and three nutrients during the sampling period, whereas chlorophyll a showed a different pattern according to the developmental stages. The nutrients should indirectly affect via chlorophyll a and phytoplankton concentration. With respect to these results, we presented a scenario about how the environmental factors along with the water current affect the distribution ofE. pacifica in the Yellow Sea.