Contribution of Sponge Spicules to the Composition of Biogenic Silica in the Ligurian Sea

Abstract. The importance of sponge spicules in the turnover of biogenic silica (BSi) in the detritic bottoms of the Eastern Ligurian Riviera was evaluated by studying sediment cores and the detrital matter collected by a trap over a one year period.
This study made evident that: i) Sponge spicules represent the main component of the BSi both in the sediments and in the trapped matter; ii) A correlation exists between the sponge biomass present on the overhanging cliff and the amount of sponge spicules found in the sediment below; iii) Inside the sediments, a superficial layer (10 cm deep) characterized by intensive silica dissolution processes can be observed; and iv) The amount of spicules collected using the trap is not constant throughout the year, but shows a characteristic trend with low values in spring and summer and high values in autumn and winter.     

Assumption and elimination of trace elements in Adélie penguins from Antarctica: a preliminary study

The concentration and distribution of some trace elements were determined in stomach contents, excreta and feathers of Adélie penguins (Pygoscelis adeliae) breeding at Edmonson Point (Terra Nova Bay-Antarctica). In these materials obtained by non-destructive methods, concentrations of mercury, cadmium and lead measured were used to establish natural levels of these metals in the penguins' diet. An intake-excretion hypothesis was formulated.     

Biomarkers of Exposure and Effects for Assessing Toxicological Risk of Endocrine Disrupters in Top Predators of the Mediterranean Sea

Abstract. Endocrine Disrupting Chemicals (EDCs) have the potential to alter hormone pathways that regulate reproductive processes in wildlife and fisheries. In this research the unexplored hypothesis that Mediterranean top predator species (such as large pelagic fish and marine mammals) are potentially at risk due to EDCs is investigated. In the Mediterranean environment, top predators accumulate high concentrations of polyhalogenated aromatic hydrocarbons (PHAHs) and toxic metals, incurring high toxicological risk. Here we illustrate the need to develop sensitive biomarkers for evaluation of toxicological risk in top marine predators (Xiphias gladius, Thunnus thynnus thynnus) and non-lethal techniques, such as non-destructive biomarkers, for the hazard assessment of threatened species exposed to EDCs, such as marine mammals ( Stenella coeruleoalba, Tursiops truncatus, Delphinus delphis and Balaenoptera physalus ).     

New unspiked K–Ar ages of volcanic rocks of the central and western sector of the Aeolian Islands: reconstruction of the volcanic stages

A geochronological study of the Filicudi, Salina, Lipari and Vulcano Islands (Aeolian Archipelago) using the unspiked potassium–argon technique provides new age data which, combined with stratigraphic correlation, better constrain the temporal evolution of volcanism. The unspiked K–Ar age of the oldest exposed lavas on Filicudi, 219±5 ka, is significantly younger than the previous estimation of 1.02 Ma. In the general context of Aeolian volcanism, this new date suggests that the volcanism of the western sector of the Aeolian Archipelago is younger than previously thought. Geochronological data point out on the rapid transition from calc–alkaline to potassic volcanism. The distribution of the K–Ar ages within the Salina–Lipari–Vulcano group shows that the volcanism started on Lipari and propagated over time northward on Salina and southward on Vulcano. Geochronological and geophysical data suggest that the onset of volcanism in the central sector of the Aeolian Arc may be due to a mantle upwelling structure located below Lipari. A change in the style of the eruptions occurred in the Salina–Lipari–Vulcano system at about 100 ka from the present. Low-energy magmatic eruptions occurred between 188 and about 100 ka. From about 100 ka to the present, higher-energy eruptions and low-energy events due to magma–water interaction also occurred. This change in the style of activity, together with the appearance of evolved products (i.e. rhyolites) during the last 50 ka, is consistent with the formation of magmatic reservoirs located at shallower depth with respect to those of the 188–100-ka period. The new geochronological data and available petrological models reveal that a change in the deep source of the primary magmas occurred in a relatively short time interval.     

Petrology of the Izmir-Karaburun volcanic area (West Turkey)

The Izmir-Karaburun region is located on the West coast of Turkey. In this area volcanic rocks of the late Miocene-Pliocene age outcrop. On the basis of the collected petrographic and geochemical data it has been possible to subdivide these rocks in to three series:a) calc-alkaline series of Karaburun-Koca dag-Izmir (quantitatively the most important). This series is formed by latite-andesites-dacites-rhyodacites.b) Silicic series of Izmir-Lebedos, mainly constituted by alkali rhyolitic rocks.c) Urla series, formed by alkali trachytes and alkali rhyolites, associated with scarce basic lavas of hawaiitic type. A different genesis is assumed for these series. In a first phase the latite-andesitic magma was formed by a partial melting in the lower crust or in the upper mantle. Afterwards a subcrustal magma with alkali basaltic affinity rose slowly through the crust forming an intermediate reservoir and differentiating predominantly towards alkali trachytic terms. Finally silicic magma of Izmir-Lebedos was formed by an anatectic process. It is possible that the fusion has been favoured by the presence of basic magma in the upper crust.     

Geochronology and petrology of recent volcanics in the eastern Aegean Sea (West Anatolia and Lesvos Island)

During the lower and middle Miocene the western Anatolia and the eastern Aegean Sea were dominated by a calcalkaline volcanism associated with minor acid and basic volcanics. The basic subcrustal volcanics consist mainly of alkali basalts and hawaiites (9.7–11.9 m.y.), nepheline hawaiites and nepheline trachyandesites (Kula area from 1.1 m.y. to the recent times). The rhyolitic volcanics (12.5 m.y.) derived by a partial melting process in the upper crust (⁸⁷Sr/⁸⁶Sr=0.7121). The calcalkaline suite (16.2–21.5 m.y., mean value⁸⁷Sr/⁸⁶Sr=0.708) shows a trend from latite-andesites to dacites and rhyodacites; a latite andesite system related to a sinking slab of lithosphere and constituted by a mixing of oceanic crust (tholeiite), oceanic sediments and/or tectonic fragments of sialic crust is envisaged.     

Plio-Quaternary volcanotectonic activity in the northern sector of the Main Ethiopian Rift: relationships with oblique rifting

Deformation and magmatism within the 90 km wide northern Ethiopian Rift system is concentrated along a narrow zone - the Wonji Fault Belt. Two key areas (the Nazret-Dera and Asela-Ziway areas), located along the eastern margin of the north-northeast to northeast trending Main Ethiopian Rift, have been investigated in order to reconstruct the recent tectonomagmatic evolution of the northern branch of the Main Ethiopian Rift. In these areas, Early Pleistocene volcanic products (Wonji Group) overlie Pliocene volcanic rocks (Eastern Margin Unit). Detailed stratigraphical reconstructions have revealed the presence of several tectonomagmatic units which can be correlated between the two study areas. The stratigraphical and petrological study of these units outlined (1) the bimodal composition (basalts-pantellerites) of the oldest and youngest units and the unimodal character (pantellerites) of the products erupted during the intervening period; (2) the mainly fissural origin of the ignimbrites and oldest basalts; and (3) a mafic/felsic volumetric ratio of 1:5.The geological data suggest that, around the Pliocene-Quaternary boundary, a change in the stress field occurred in this Main Ethiopian Rift sector, passing from a direction of extension roughly orthogonal to the rift shoulders, to oblique rifting related to an east-west trending extension. In this framework the change in the style of volcanism observed in the Nazret-Dera and Asela-Ziway areas can be related to the change of the stress field. A new geodynamic model is presented for the Late Pliocene to Recent evolution of this sector of the Main Ethiopian Rift. According to this model, a large volume of rhyolitic products was erupted during an oblique rifting phase, following a previous period of pure extension. The change in the tectonic regime favoured partial melting of the underplated basalts as a decrease in the pressure and an elevation of isotherms occurred.     

Characterization of volcanic thermal anomalies by means of sub-pixel temperature distribution analysis

The simultaneous solution of the Planck equation (involving the widely used “dual-band” technique) using two shortwave infrared (SWIR) bands allows for an estimate of the fractional area of the hottest part of an active lava flow (f _h) and the background temperature of the cooler crust (T _c). The use of a high spectral and spatial resolution imaging spectrometer with a wide dynamic range of 15 bits (DAIS 7915) in the wavelength range from 0.501 to 12.67 μm resulted in the identification of crustal temperature and fractional areas for an intra-crater hot spot at Mount Etna, Italy. This study indicates the existence of a relationship between these T _c and f _h extracted from DAIS and Landsat TM data. When the dual band equation system is performed on a lava flow, a logarithmic distribution is obtained from a plot of the fractional area of the hottest temperature vs. the temperature of the cooler crust. An entirely different distribution is obtained over active degassing vents, where increases in T _c occur without any increase in f _h. This result indicates that we can use scatter plots of T _c vs. fh to discriminate between different types of volcanic activity, in this case between degassing vents and lava flows, using satellite thermal data.     

Monte guardia sequence: a late-pleistocene eruptive cycle on Lipari (Italy)

This paper documents a complex sequence of interbedded lapilli-fall, base-surge, and pyroclastic-flow deposits, here named the Monte Guardia sequence, that erupted from volcanic centers in the southern part of Lipari (Aeolian Island Arc). Radiocarbon data from ash-flow tuffs above and below this sequence bracket its eruption between 22,600 and 16,800 years ago. Geologic evidence, however, suggests that this single eruptive cycle had a more restricted duration of years to tens-of-years. The basis for our interpretations comes from data measured at 38 detailed sections located throughout the island. The Monte Guardia sequence rests on a series of lower rhyolitic endogenous domes in the southern part of Lipari and it covers the oldest lavas, lahars, and pyroclastic flows in the north. Only in the northeast part of the island is it covered by younger deposits which there consist of lapilli tuffs and lavas of the Monte Pilato rhyolitic cycle. The deposit ranges in thickness from more than 60 m surrounding the vents in the south to less than a few decimeters at 10 km distance in the north. Throughout most of the island the Monte Guardia sequence overlies a thin andesitic lapilli-fall layer which is a key bed for correlation. This lapilli tuff probably erupted from a volcanic center on another island of the Aeolian Arc (possibly Salina). The principal activity of the Monte Guardia sequence started with an explosion that formed a continuous breccia blanket covering most of the island. Some pumiceous blocks within this breccia are composed of alternating bands of acidic and andesitic composition suggesting that the initiation of pyroclastic activity could have been triggered by magma mixing. Typical Monte Guardia sequence consists of explosive products that grade from magmatic (pumice-fall) to phreatomagmatic (base-surge) character. The eruptive cycle is characterized by a number of energy decreasing megarhythms that start with a lapilli-fall bed and end with a base-surge set that progresses through sand-wave, massive, and planar beds. Isopach maps of the fall and surge deposits indicate that both types were directed to the northwest by prevailing winds. Existing topographic relief was an additional factor that affected the emplacement of surge products. At the end of the cycle andesitic pyroclastic flows and rhyolitic endogenous domes were emplaced above the Monte Guardia deposits near the vent.