Geochemical evolution of the Capim River kaolin, Northern Brazil

The Capim River kaolin, located in the eastern Brazilian Amazon, constitutes one of the most important kaolin deposits in the world. Known for its high whiteness, its noble application is in the paper industry. Studies were carried out on samples from the six facies of the deposit (sand kaolin, soft kaolin, lower transition facies, ferruginous crust, upper transition facies and flint kaolin) in order to trace its geochemical evolution. The kaolin developed at the expense of Cretaceous sandy–clayey sediments of the Ipixuna Formation. Intense lateritic processes characterized by ferruginization and deferruginization mechanisms led to the distinction of the different facies.     

Hazard mapping based on macroseismic data considering the influence of geological conditions

The object of this study is to consider directly the influence of regional geological conditions on the assessment of seismic hazard. It is assumed that macroseismic data at individual locations contain, in an average way, the influence of geological conditions.A Data Base referring to 199 historical (5) and instrumental (194, in the 1947–1993 period) events with macroseismic information in 1195 locations of Portugal was built. For any given seismic event, whenever macroseismic information was available at a location (town, village, etc.), an EMS-92 intensity value was estimated. To each one of those locations a geological unit, representing the most common type of soil, was assigned, based on the Geological Portuguese Map at a scale 1:500 000; the geological units were grouped into three categories: soft, intermediate and hard soils.The Data Base was used to determine the attenuation laws in terms of macroseismic intensity for the three different geological site conditions, using multiple linear regression analysis. The reasonability of the laws was tested by (i) checking residual distributions and (ii) comparing the map of isoseismals of important earthquakes with the isoseismals generated by the attenuation curves derived for each one of the three different soil classes, taking into consideration the soil class of each site. The main results of attenuation modeling are: high dispersion on macroseismic intensity data; all the models predict intensity values, for short hypocentral distances, lower than the ones observed; and for some important analyzed earthquakes and for the observed range of distances, the models confirm the expectancy that macroseismic intensity increases from hard to soft soil.The approach to obtain the hazard assessment at each location consisted in the use of the attenuation law specifically derived for the class of soil of that particular location. This method, which considers the influence of the regional geology, was illustrated with the mapping of hazard for the country for several return periods. Comparison with previous maps not taking into consideration the regional geological conditions emphasizes the importance of this new parameter. It can be concluded that (i) soil segmentation is clearly the cause for hazard increase in the region to the north of Lisbon, especially at sites with soft and intermediate soils as the ones in lower Tagus valley; the maximum increase on hazard is, in any case, less than one degree; (ii) when geological conditions are disregarded in the attenuation regression analysis, hazard pattern is similar to the one obtained for the case of hard soil everywhere.     

Bismuth‐melt trails trapped in cassiterite–quartz veins

Native bismuth in the form of metallic melt has been considered instrumental to the formation of some metallic ore deposits via a mechanism dubbed the “Liquid Bismuth Collector Model.” Here, we provide petrographical documentation of trail‐forming, μm‐sized blebs of native bismuth in cassiterite–quartz veins from the Santa Bárbara greisen Sn deposit in the Rondônia tin province of northern Brazil. These inclusions suggest the trapping of a Bi melt that took place during vein formation, in a mechanism similar to the entrapment of fluid inclusions.     

Lake sedimentary processes and vegetation changes over the last 45k cal a bp in the uplands of south-eastern Amazonia

This study addresses paleoclimate influences in a southern Amazonia ecotone based on multiproxy records from lakes of the Carajás region during the last 45k cal a bp. Wet and cool environmental conditions marked the initial deposition in shallow depressions with detrital sediments and high weathering rates until 40k cal a bp. Concomitantly, forest and C3 canga plants, along with cool-adapted taxa, developed; however, short drier episodes enabled expansion of C4 plants and diagenetic formation of siderite. A massive event of siderite formation occurred approximately 30k cal a bp under strong drier conditions. Afterwards, wet and cool environmental conditions returned and persisted until the Last Glacial Maximum (LGM). The LGM was marked by lake-level lowstands and subaerial exposure. The transition from the LGM to the Holocene is marked by the onset of oscillations in temperature and humidity, with an expansion of forest and canga plants. Cool taxa were present for the last time in the Carajás region ~ 9.5–9k cal a bp. After 10k cal a bp , shallow lakes became upland swamps due to natural infilling processes, but the current vegetation types and structures of the plateaus were acquired only after 3k cal a bp under wetter climatic conditions.     

Crustal structure in the southwestern part of the Iberian Peninsula

Seismic investigations to determine the crustal structure in the southwestern part of the Iberian Peninsula have been initiated in 1970. First experiments were carried out during July 1970, when a series of ten shots was fired off Cabo de Sines (Portugal) in shallow water and recorded up to distances of 185 km along a SE-profile towards Huelva (Spain). The profile was reversed in December 1970, when a series of twelve shots was fired off the south coast near Fuzeta (east of Faro) and recorded up to distances of about 260 km along a NW-profile towards Cabo da Roca west of Lisboa. A considerable increase in the seismic efficiency of the explosions could be achieved by generating standing waves in the water.

The structure deduced exhibits some peculiar features. Below the Palaeozoic sediments a fairly high velocity of 6.4 km/sec is found for the dome-shaped basement in that area. The lower crust, which is separated from the upper crust by a distinct velocity inversion (with a minimum velocity of about 5.3–5.6 km/sec), is characterized by a velocity of 7.1 km/sec. From the geological evidence and the sequence of seismic velocities it must be concluded that the upper crustal block in the southwestern part of the Iberian Peninsula has been uplifted by about 2–5 km since Permo-Triassic time, thus emphasizing the significance of vertical movement in tectonic activity.

The top of the upper mantle (8.15 km/sec) was detected at a depth of 30 km close to the Atlantic coast in the west, while near the Algarve coast in the south the depth to the M-discontinuity is about 34–35 km. This result in conjunction with studies of earthquake focal mechanisms confirms the suggestion that the Iberian block is being underthrust under the African plate.     

Granite fracture index to check suitability of granite outcrops for quarrying

A correct knowledge of fracture patterns previous to quarrying is important for economical exploitation. This work comprises the general characterization of the discontinuities of 10 granite rock masses in NE Portugal. During the study some discontinuity characteristics such as orientation, persistence, aperture, trace length and spacing were evaluated. The differences in the characteristics of the selected granites were described, and the most important exploration factors were identified. In the granites studied, most of the joints are oriented from N10°E to N50°E, which is compatible with the regional fracture pattern. Concerning joint termination, the XX type is common, while the RR type is rare; the persistence index ranges from 3.5% to 25.4%. Closed joints are predominant in the granites studied (> 72.4%), and openings of the others are about 1–2 mm as a result of superficial displacement of the granite blocks. The percentage of filled joints, usually by quartz and pegmatite, is different from one granite to another, but most are < 20%. The average joint length ranges from 11.1 m in post-tectonics granites to 4.6 m in syntectonic granites. Joint spacing varies from 0.98 to 2.8 m with higher values in post-tectonic granites. Joint-space distributions of the granites studied are close to log-normal and exponential distributions. Volumetric joint count (Jv) ranges from 0.8 to 2.1 joints/m³ and is used for categorizing the places of each granite. The relationships between Jv and other joint characteristics, such as length, spacing and number of joint sets, were investigated. A Granite Fracturing Index (GFI) is introduced, computed on the basis of volumetric joint count, number of joint sets and true joint spacing. The GFI classification of studied places allows us evaluate the suitability for profitable exploitation.     

Generative Adversarial Network Applied to Ore Type Modeling in Complex Geological Environments

Mathematical Geosciences - In complex geological environments, the spatial domain characterization of different ore types has been one of the most important challenges in the assessment of mineral...     

A global model study of natural bromine sources and the effects on tropospheric chemistry using MOZART4

Halogens in the atmosphere chemically destroy ozone. In the troposphere, bromine has higher ozone destruction efficiency than chlorine and is the halogen species with the widest geographical spread of natural sources. We investigate the relative strength of various sources of reactive tropospheric bromine and the influence of bromine on tropospheric chemistry using a 6-year simulation with the global chemistry transport model MOZART4. We consider the following sources: short-lived bromocarbons (CHBr₃, CH₂BrCl, CHBr₂Cl, CHBrCl₂, and CH₂Br₂) and CH₃Br, bromine from airborne sea salt particles, and frost flowers and sea salt on or in the snowpack in polar regions. The total bromine emissions in our simulations add up to 31.7 Gmol(Br)/yr: 63 % from polar sources, 24.6 % from short-lived bromocarbons and 12.4 % from airborne sea salt particles. We conclude from our analysis that our global bromine emission is likely to be on the lower end of the range, because of too low emissions from airborne sea salt. Bromine chemistry has an effect on the oxidation capacity of the troposphere, not only due to its direct influence on ozone concentrations, but also by reactions with other key chemical species like HO _x and NO _x . Globally, the impact of bromine chemistry on tropospheric O₃ is comparable to the impact of gas-phase sulfur chemistry, since the inclusion of bromine chemistry in MOZART4 leads to a decrease of the O₃ burden in the troposphere by 6 Tg, while we get an increase by 5 Tg if gas-phase sulfur chemistry is switched off in the standard model. With decreased ozone burden, the simulated oxidizing capacity of the atmosphere decreases thus affecting species associated with the oxidation capacity of the atmosphere (CH₃OOH, H₂O₂).