Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Evaluation of Subsurface Structure at Soultz Hot Dry Rock Site by the AE Reflection Method in Time-frequency Domain

—?Because the Soultz Hot Dry Rock (HDR) site, France, is to be expanded to a scientific pilot plant of greater depth, measurement of the deep area below the predeveloped artificial reservoir is gaining importance. In this paper, we present estimates of deep subsurface structure at the Soultz HDR site, obtained by a reflection method using acoustic emission (AE) signals, that is, induced seismicity, as the wave source. First, we briefly describe the AE reflection method in the time-frequency domain with wavelet transform. Then we show estimates of the subsurface structure by using 101 high-energy AE events observed in 1993. We compare and discuss the results obtained, using the AE reflection method in two wells with other independent borehole observations. Furthermore, we present the results of an investigation of the frequency dependence of reflectors identified by hodogram linearity as a possible means of further characterizing detected structures.     

Mixing, sediment accumulation and focusing using 210Pb and 137Cs

The Portil lagoon is a natural freshwater reservoir located at the southwest of Spain, near the coast. In its surroundings an important tourist complex has been developed since the earlier 1970s. This has resulted in increased loads of nutrients, specially during summer months. In order to evaluate the impact from humans on the lagoon caused by anthropogenic activities, we have determined vertical profiles of excess ²¹⁰Pb and ¹³⁷Cs in a sediment core taken from its bottom. Vertical profile of excess ²¹⁰Pb seems to indicate that the sediment core was affected by large-scale mixing processes. Nevertheless this possibility was ruled out based on the shape of the ¹³⁷Cs vertical distribution after modelling the ¹³⁷Cs profile considering large-scale mixing. The chronology developed from ²¹⁰Pb and ¹³⁷Cs has allowed us to calculate the temporal evolution of the mass sedimentation rate during the last century. This mass sedimentation rate increased in 1973: from 0.08(2) g cm^-2 a^-1 in the period 1900-1973 to 0.17(5) g cm^-2 a^-1 in the period 1973-1995. This increase could be related to land-movements in the drainage area and to permitted sewage inputs into the lagoon, both with its origin in the growing/running of the surrounding tourist complex.     

“地球动力学”的研究现状与展望——第32届国际地质大会研究成果综述

第32届国际地质大会通过按地域和构造作用过程等形式划分11个专题会场,展示了地球动力学的研究成果。其成果主要包括特提斯域构造演化及其不同阶段的块体裂解、拼合及后期改造的细节过程,地质历史中的超大陆分布和成因,俯冲—碰撞带深部构造和变质机制,安第斯山(Andes)缓倾角平坦式俯冲过程及其地壳变形和岩浆作用的响应,显微构造对动力作用过程的影响和控制,地壳和上地幔熔融、流变学和动力学意义,大洋岩石圈构造与演化,大陆地盾区构造和再活动,稳定大陆区地震,空间大地测量学和现代板块运动等方面。这些研究成果充分显示了地球动力学研究具有多学科、多手段(如古地磁、超深钻、地球物理、大地测量和GPS等)、多尺度(宏观、微观)和多时期、全面、综合、并逐步接近定时、定位和定量地探索和研究的特点,它从地球(主要为上地幔和地壳)的组成、结构构造入手,逐步认识地球(主要为地球岩石圈)的演化和动力学。     

Bioaccumulation of heavy metals in <Emphasis Type="Italic">Limnobium laevigatum</Emphasis> and <Emphasis Type="Italic">Ludwigia peploides</Emphasis>: their phytoremediation potential in water contaminated with heavy metals

Contamination with heavy metals in surface and groundwater is a threat to human health and ecosystems. Due to this, the need arises to remediate water polluted through ecological and profitable technologies, such as phytoremediation. The objective of the work was to evaluate the concentration of lead (Pb) and zinc (Zn) in the floating macrophytes Limnobium laevigatum and Ludwigia peploides, after being exposed to contaminated water experimentally. In this way to be able to determine if these plants have mechanisms that allow them to accumulate the metals in the roots and to perform the translocation of these to different vegetative organs, L. laevigatum and L. peploides were placed in solutions contaminated with Pb ([Pb]?=?5 mg/l) and Zn ([Zn]?=?20 mg/l). The concentrations of metals in water, root and leaf samples were evaluated as a function of time (0, 1, 2 and 4 days). The determination of the metals was performed by the atomic absorption spectrophotometry technique. After 4 days of exposure to Pb and Zn, the plants showed high metal removal efficiencies of water, more to 70% in all cases. Pb was accumulated fundamentally by roots, while Zn was accumulated more in the leaves. In addition, the bioconcentration and translocation factors for each metal were calculated.     

Development of groundwater favourability map using GIS-based driven data mining models: an approach for effective groundwater resource management

The development of groundwater favourability map is an effective tool for the sustainability management of groundwater resources in typical agricultural regions, such as southern Perak Province, Malaysia. Assessing the potentiality and pollution vulnerability of groundwater is a fundamental phase of favourability mapping. A geographic information system (GIS)-based Boolean operator of a spatial analyst module was applied to combine a groundwater potentiality map (GPM) model and a groundwater vulnerability to pollution index (GVPI) map, thereby establishing the favourable zones for drinking water exploration in the investigated area. The area GPM model was evaluated by applying a GIS-based Dempster–Shafer–evidential belief function model. In the evaluation, six geoelectrically determined groundwater potential conditioning factors (i.e. overburden resistivity, overburden thickness, aquifer resistivity, aquifer thickness, aquifer transmissivity and hydraulic conductivity) were synthesized by employing the probability-based algorithms of the model. The generated thematic maps of the seven hydrogeological parameters of the DRASTIC model were considered as pollution potential conditioning factors and were analysed with the developed ordered weighted average–DRASTIC index model algorithms to construct the GVPI map. Approximately 88.8 and 85.71% prediction accuracies for the Groundwater Potentiality and GVPI maps were established using the reacting operating characteristic curve method and water quality status–vulnerability zone relationship scheme, respectively. Finally, the area groundwater favourability map (GFM) model was produced by applying a GIS-based Boolean operator on the Groundwater Potentiality and GVPI maps. The GFM model reveals three distinct zones: ‘not suitable’, ‘less suitable’ and ‘very suitable’ zones. The area analysis of the GFM model indicates that more than 50% of the study area is covered by the ‘very suitable’ zones. Results produce a suitability map that can be used by local authorities for the exploitation and management of drinking water in the area. The study findings can also be applied as a tool to help increase public awareness of groundwater issues in developing countries.     

Diabatic wind and temperature profiles obtained from a 100 m tower: A statistical comparison of model performances

More than 8000 10-min profiles of wind and temperature obtained during an extensive field experiment have been analyzed. The study was carried out in the environs of Valladolid (Spain) where a 100-m and a 6-m meteorological tower are located. Less than 20% of data were discarded due to equipment failure. Because of its exceptional flatness, the site is almost ideal for model performance comparisons.Predicted profiles of wind speed and potential temperature at 12, 26, 51, and 100 m heights were obtained using the methods proposed by Berkowicz and Prahm (1982) and San José (1983) based on values observed on a 6 m tower. Statistical t, F, and R tests were used to determine bias, scatter and correlation. The data were classified according to atmospheric stratification and height above ground. Finally, a determination was made of the predicted wind speeds and potential temperatures that fell within the 1 and 20% confidence ranges centered at the measured value. San José's method performed better than did that of Berkowicz and Prahm for the temperature profiles in both unstable and stable conditions. However, no significant differences were found for the wind speed profiles.     

Nutrient mediated stress on the marine communities of a coastal lagoon (Puerto Galera, Philippines)

Puerto Galera Bay is a coastal lagoon with a variety of marine habitats and high species diversity. It is an area in the Phillippines where the growing influence of human activities is affecting the quality of its marine resources. This study examined the distribution and behaviour of nutrients and the physical hydrography of Puerto Galera Bay and determined how its physico-chemical nature affected the condition of biotic components in the bay. The relative importance of the nitrogen and phosphorus signals were used as indicators to implicate the influence of sewage and run-off into the bay. A nutrient pool accumulated in the bay as a result of low flushing rates. The interaction of hydrodynamic forcing with the biota have implications on the phytoplankton production and coral communities in the area.     

低本底液闪仪计算机控制系统的改进

新研制改进的低本底液闪计算机控制系统，具有数据获取和数据处理、实时能谱测量、谱显示选取工作点以及测量中断后继续测量等功能，从而使液闪仪的自动化和智能化程度得到了进一步提高。     

Development and behaviour of a radar-based operational tool for hailstorms identification

Hailstorms are a common meteorological phenomenon in Spain which causes substantial economic damage especially in spring and summer. During 2000 and 2001, a radar-based application for convective monitoring was developed at STAP (Forecasting and Analysis Techniques Department); in order to improve this nowcasting tool, it is needed to include an advanced procedure to estimate the presence of hail as a complementary module in the operational application. A preliminary study, carried out during 2001, showed that the Waldvogel technique, VIL (vertical integrated liquid) density and the hail detection algorithm (HDA) are the methodologies which proved more accurate in our latitudes.Throughout the spring and summer of 2001, all available information about hail events (time, place and hail size) and about storms without hail was used for tuning an experimental module to detect severe and non-severe hailstorms, taking into account the selected algorithms. During 2002, further information about storms was gathered in order to assess the behaviour of the developed hail module. Afterwards, a new module calibration was carried out with the information of the complete storms data set of 2001 and 2002. With this new calibration, the hail module became an operational tool during the spring and summer of 2003. Currently, the verification of the operational module using the data from the storms in 2003 is being elaborated. The aim of this work is to put forward the calibration procedure carried out, the verification results of 2002, and the performance of the hail estimate module in selected cases during 2003 in Spain.