Butyltins in marine waters of The Netherlands in 1988 and 1989; Concentrations and effects

Specific effects of tributyltin (TBT) on Crassostrea gigas—valve thickening, and Nucella lapillus—imposex, were measured on local populations, relatively clean unaffected species from England were transferred to the Netherlands and exposed during six weeks to ambient TBT concentrations. Near marinas 50% of the exposed species were sterile after six weeks. In general, no dissolved butyltins were detected in the Rhine and Scheldt estuaries. In 1988 TBT concentrations in marinas ranged from 120 to 4000 ng litre⁻¹. In sediments (fraction <60 μm) and suspended particulate matter TBT concentrations reached up to 1200 ng g⁻¹. TBT concentrations in mussel tissue ranged from <1 to 2300 ng g⁻¹ based on a dry weight. In 1989 concentrations of dissolved TBT ranged from <0·1 to 7200 ng litre⁻¹. In 1989 a seasonal study in the marina of Colijnsplaat showed that dissolved butyltins increased from April to the end of May due to the launching of freshly painted boats, and decreased afterwards.     

Residues of 14C-4n-nonylphenol in mosquitofish (Gambusia holbrooki) oocytes and embryos during dietary exposure of mature females to this xenohormone

In order to assess in fish the maternal transfer of alkylphenolic compounds to the progeny, the identification and quantification of the labelled compounds present in oocytes and embryos was conducted after dietary exposure of mature female mosquitofish to 14C-4n-nonylphenol during vitellogenesis and embryogenesis respectively. Radioactivity found in bile and liver extracts accounted for 0.9-0.6 and 0.2-0.1% of ingested radioactivity for females exposed during vitellogenesis and embryogenesis respectively. The amount of extractable radioactivity present in oocytes and embryos was 0.19 and 0.07% of the ingested dose respectively. The radio-HPLC profiles obtained from bile, liver, oocyte and embryo extracts were similar. They showed the presence of 4n-NP-glucuronide as the major metabolite and traces of unchanged 4n-NP. The other metabolites corresponded to 8-hydroxynonylphenol, 9-(4-hydroxyphenyl)-nonanoic acid and para-hydroxybenzoic acid which is the final product of the alkyl chain oxidation. Our results indicate that exposure of ovoviviparous female fish to 4-NP during vitellogenesis and embryogenesis leads to the contamination of the progeny by 4-NP and its metabolites.     

An experimental study on active tendon control of cable-stayed bridges

Active tendon control of cable-stayed bridges subject to a vertical sinusoidal force is experimentally and analytically studied. Emphasis is placed on the effects of linear and non-linear internal resonances on the control (due to the presence of the cable vibration). A simple cable-supported cantilever beam is used as a model. It is found that active tendon control is very effective in vertical girder motion with small cable vibration (girder dominated motion), whereas it is not effective in vertical girder motion with large cable vibration (cable dominated motion). Analytical prediction is very satisfactory except for the latter case.     

Dissolved organic nitrogen dynamics in the North Sea: A time series analysis (1995–2005)

Dissolved organic nitrogen (DON) dynamics in the North Sea was explored by means of long-term time series of nitrogen parameters from the Dutch national monitoring program. Generally, the data quality was good with little missing data points. Different imputation methods were used to verify the robustness of the patterns against these missing data. No long-term trends in DON concentrations were found over the sampling period (1995–2005). Inter-annual variability in the different time series showed both common and station-specific behavior. The stations could be divided into two regions, based on absolute concentrations and the dominant times scales of variability. Average DON concentrations were 11 μmol l⁻¹ in the coastal region and 5 μmol l⁻¹ in the open sea. Organic fractions of total dissolved nitrogen (TDN) averaged 38 and 71% in the coastal zone and open sea, respectively, but increased over time due to decreasing dissolved inorganic nitrogen (DIN) concentrations. In both regions intra-annual variability dominated over inter-annual variability, but DON variation in the open sea was markedly shifted towards shorter time scales relative to coastal stations. In the coastal zone a consistent seasonal DON cycle existed with high values in spring–summer and low values in autumn–winter. In the open sea seasonality was weak. A marked shift in the seasonality was found at the Dogger Bank, with DON accumulation towards summer and low values in winter prior to 1999, and accumulation in spring and decline throughout summer after 1999. This study clearly shows that DON is a dynamic actor in the North Sea and should be monitored systematically to enable us to understand fully the functioning of this ecosystem.     

Spectroscopic anatomy of a meteor trail cross section with the European Southern Observatory Very Large Telescope

Abstract— A meteor spectrum was recorded serendipitously at the European Southern Obrervatory (ESO) Very Large Telescope (VLT) during a long exposure in long‐slit spectroscopic mode with FORS1. The ?8 magnitude fireball crossed the narrow 1Î × 7î slit during the observation of a high z supernova in normal service mode operation on May 12, 2002. The spectrum covered the range of 637–1050 nm, where the meteor's air plasma emissions from N₂, N, and O dominate. Carbon atom emission was not detected in the relatively unexplored wavelength range above 900 nm, but the observed upper limit was only 3 sigma less than expected from the dissociation of atmospheric CO₂. The meteor trail was resolved along the slit, and the emission had a Gaussian distribution with a dimension of FWHM = 7.0 (±0.4) * sin(α) * H (km)/90 m, where α is the unknown angle between the orientation of the meteor path and slit and H the assumed altitude of the meteor in km. To our knowledge, this is the first observation of a spatially resolved spectrum across a meteor trail. Unlike model predictions, the plasma excitation temperature varied only from about 4,300 to 4,365 K across the trail, based on the ratio of atomic and molecular nitrogen emissions. Unfortunately, we conclude that this was because the meteor at 100 km altitude was out of focus.     

Influence of pH on the fluorescence of dissolved organic matter

During two surveys (June, 1980 and March, 1981) the influence of the pH on the fluorescence (mFl) was studied in the Ems-Dollart estuary. In the natural pH range (7–9) the fluorescence (mFl) increased by 16.4%. To express the fluorescence (mFl) at a fixed pH, a formula was derived (see eq. 1). From the results it is concluded that an increase in fluorescence (mFl) does not necessarily include an increase in the concentration of fluorescent matter. For areas where pH changes are possible, it is premature to infer from the increase in fluorescence that the fluorescent matter is produced in situ.