Environmental risk evaluation of the use of mine spoils and treated sewage sludge in the ecological restoration of limestone quarries

The ecologic restoration criteria in areas degraded from extraction activities require making use of their mine spoils. These materials do not meet fertility conditions to guarantee restoration success and therefore, need the incorporation of organic amendments to obtain efficient substratum. Reducing the deficiencies in the organic material and restoration material nutrients with the contribution of treated sewage sludge is proposed in this work. This experiment was based on a controlled study using columns. The work was conducted with two mine spoils, both very rich in calcium carbonate. The first mineral, of poor quality, came from the formation of aggregates of crushed limestone (Z). The other residual material examined originated in limestone extraction, formed by the levels of interspersed non-limestone materials and the remains of stripped soils (D). Two treatments were undertaken (30,000 and 90,000 kg/ha of sewage sludge), in addition to a control treatment. The water contribution was carried out with a device that simulated either short-duration rain or a flooding irrigation system in order to cover the surface and then percolate through the soil. The collection of leached water took place 24 h after the applications. Different parameters of the leached water were determined, including pH, electrical conductivity, nitrate anions, ammonium, phosphates, sulphates and chlorides. The values obtained for each irrigation application are discussed, and the nitrate values obtained were very elevated.     

The kinetics of nucleation of solid solutions from aqueous solutions: a new model for calculating non-equilibrium distribution coefficients

The nucleation kinetics of binary solid solutions, with general formula B_xC_1−xA, crystallising from aqueous solution can be described using a generalised expression for the nucleation rate: the function, J(x), in which supersaturation, interfacial free energy and other parameters of the classical nucleation rate equation are considered as functions of the solid composition. As an example, we studied the behaviour of such J(x) functions for the case of the (Ba,Sr)SO₄ and (Ba,Sr)CO₃ solid solutions. J(x) functions are very sensitive to slight changes in the composition of the aqueous solution, which result in strong modifications of the nucleation kinetics. The implications of the relationship between supersaturation and nucleation rate functions for the general nucleation behaviour in solid solution-aqueous solution (SS-AS) systems are discussed. Finally, we present a method for constructing non-equilibrium Roozeboom diagrams based on the nucleation kinetics in SS-AS systems. Our Roozeboom diagrams calculated for different departures from equilibrium conditions are consistent with previous experimental work and they can be used to predict actual distribution coefficients.     

Supersaturation functions in binary solid solution-aqueous solution systems

In this paper, we present a brief review of the thermodynamic equilibrium of binary solid solution-aqueous solution (SS-AS) systems and derive an expression that allows us to evaluate the supersaturation or undersaturation of a given aqueous solution with respect to the whole range of solid compositions: the δ(x) function. Such an expression is based on the two conditions that define the SS-AS thermodynamic equilibrium. The derivation of the new supersaturation function, δ(x), was made by considering in detail the compositional relationships between solid and aqueous phases. To represent the new formulation on Lippmann diagrams, we have defined a new thermodynamic concept: the “actual activity.” In addition, we show how our supersaturation function behaves for both ideal and subregular solid solutions. The behaviour and applicability of both the δ(x) function and a previous supersaturation function, β(x), defined by Prieto et al. (1993), is discussed.     

Studies of compaction and subsidence in the Orinoco Oil Belt

To control vertical movements in the Orinoco Oil Belt, a high-precision levelling network was installed in an area of about 100 km². Links to the National Geodetic Network were established.

A total of 190 BMs with deep pile foundations is already installed and the first measurement campaign was concluded. The accuracies obtained are those of first-order levelling works.     

Non-Linear Gravitational Clustering Using the Zel'dovich Approximation

As an alternative to computationally expensive N-body simulations for gravitional clustering, the Zel'dovich approximation (ZA) was studied in 3D, 2D and 1D. Plots of the density contrast were compared against linear theory and the exact solution. The ZA was found to perform very well in the linear regime, better than linear theory, and to give a good approximation well into the non-linear regime. This revised version was published online in July 2006 with corrections to the Cover Date.     

Mapping soil liquefaction susceptibility across Europe using the analytic hierarchy process

Bulletin of Earthquake Engineering - Mapping the susceptibility of earthquake-induced soil liquefaction at the continental scale is a challenge. Susceptibility of soils to liquefaction is the...     

Molecular-scale surface processes during the growth of calcite in the presence of manganese

This paper deals with the growth behaviour of the Mn-Ca-CO₃-H₂O solid solution-aqueous solution system on calcite {104} surfaces. This system represents a model example, which allows us to study the effect of a number of controlling factors on the crystallisation: (1) the supersaturation function, β(x), and nucleation rate function, J(x), for the Mn-Ca-CO₃-H₂O system, (2) the relationship of such functions to the molecular scale growth mechanisms operating on growing surfaces, and (3) the surface structure of the calcite {104} faces. In situ atomic force microscopy (AFM) growth experiments revealed a wide variety of surface phenomena, such as the transition between growth mechanisms, anisotropic changes in the step rates, and the influence of the Mn-bearing newly formed surface on subsequent growth (step stoppage followed by the formation of two-dimensional nuclei and the reproduction of the original calcite {104} surface microtopography). These phenomena result from the interplay between the controlling parameters and are explained in those terms.     

Hydrogeological investigation in Santiago Island (Cabo Verde) using magnetotellurics and VLF methods

A geoelectromagnetic research was carried out in the Santa Cruz region (Santiago Island, Cabo Verde) during June 2004. The survey comprised MT soundings and VLF profiles. The main purpose of the MT profile, carried out across three important valleys associated with freshwater aquifers, was to study the tectonic structures correlated to seawater infiltration. The VLF method was used inside of the valleys for investigating shallow structures related to the aquifer contamination by seawater.Numerical modelling shows that the ocean effect is not important for MT data collected at periods shorter than 1 s. The MT data were inverted using a two-dimensional approach, to obtain the sub-superficial electrical conductivity distribution. The VLF data were processed applying the Karous–Hjelt filters to obtain the equivalent current distribution and inverted using 2-D approach. The results obtained in one of the most important valleys show anomalous current concentration/low resistivity (<20 Ω m) areas at depths greater than 40 m that may correspond to an increase in seawater content.The MT data modelling show that the deep zones beneath the valley are strongly fractured representing good pathways for seawater circulation. The depth of the conductive zones increases from south to north, suggesting a northward decreasing of the seawater infiltration effect. This observation correlates very well with in situ geochemical observations.     

Stochastic evaluation of the impact of sewer inlets’ hydraulic capacity on urban pluvial flooding

Sewer inlet structures are vital components of urban drainage systems and their operational conditions can largely affect the overall performance of the system. However, their hydraulic behaviour and the way in which it is affected by clogging is often overlooked in urban drainage models, thus leading to misrepresentation of system performance and, in particular, of flooding occurrence. In the present paper, a novel methodology is proposed to stochastically model stormwater urban drainage systems, taking the impact of sewer inlet operational conditions (e.g. clogging due to debris accumulation) on urban pluvial flooding into account. The proposed methodology comprises three main steps: (i) identification of sewer inlets most prone to clogging based upon a spatial analysis of their proximity to trees and evaluation of sewer inlet locations; (ii) Monte Carlo simulation of the capacity of inlets prone to clogging and subsequent simulation of flooding for each sewer inlet capacity scenario, and (iii) delineation of stochastic flood hazard maps. The proposed methodology was demonstrated using as case study design storms as well as two real storm events observed in the city of Coimbra (Portugal), which reportedly led to flooding in different areas of the catchment. The results show that sewer inlet capacity can indeed have a large impact on the occurrence of urban pluvial flooding and that it is essential to account for variations in sewer inlet capacity in urban drainage models. Overall, the stochastic methodology proposed in this study constitutes a useful tool for dealing with uncertainties in sewer inlet operational conditions and, as compared to more traditional deterministic approaches, it allows a more comprehensive assessment of urban pluvial flood hazard, which in turn enables better-informed flood risk assessment and management decisions.     

Nanoscale dissolution and growth on anhydrite cleavage faces

In situ atomic force microscopy (AFM) was used to study the molecular-scale reactivity of anhydrite (1 0 0), (0 1 0), and (0 0 1) faces exposed to water and CaSO₄ aqueous solutions at room temperature. In pure water, dissolution occurs by step retreat and etch pit nucleation and growth. Both the kinetics of the step retreat and the shape of the etch pits are surface-specific and crystallographically controlled. In CaSO₄ aqueous solutions with concentrations ranging from 0.030 mol/l to 0.075 mol/l, the growth kinetics on anhydrite (1 0 0) and (0 1 0) faces was studied. Growth is also strongly controlled by crystallographic constraints and occurs exclusively from pre-existing step edges by highly anisotropic spreading of monolayers (3.5 Å in height). The AFM observations demonstrate that monolayer growth can occur on anhydrite (0 1 0) and (1 0 0) faces even from slightly supersaturated solutions. In addition, the comparison of the step kinetics on anhydrite faces shows that the mechanisms of step dissolution and growth are essentially the same, with the direction of migration of crystal building units being reversed at the anhydrite saturation point. Moreover, the analysis of both high resolution AFM images and lateral force microscopy (LFM) images confirms that the newly-formed monolayers are anhydrite growing in structural continuity with the original (1 0 0) and (0 1 0) surfaces. However, the formation of the first monolayers is metastable and two-dimensional nucleation and further multilayer growth of anhydrite are strongly inhibited even at high supersaturations.