WR 7a: a V Sagittae or a qWR star?

The star WR 7a, also known as SPH 2, has a spectrum that resembles that of V Sagittae stars although no O  vi emission has been reported. The Temporal Variance Spectrum – TVS – analysis of our data shows weak but strongly variable emission of O  vi lines which is below the noise level in the intensity spectrum.
Contrary to what is seen in V Sagittae stars, optical photometric monitoring shows very little, if any, flickering. We found evidence of periodic variability. The most likely photometric period is   P _phot= 0.227(±14) d  , while radial velocities suggest a period of   P _spec= 0.204(±13) d  . One-day aliases of these periods can not be ruled out. We call attention to similarities with HD 45166 and DI Cru (= WR 46), where multiple periods are present. They may be associated to the binary motion or to non-radial oscillations.
In contrast to a previous conclusion by Pereira et al., we show that WR 7a contains hydrogen. The spectrum of the primary star seems to be detectable as the N  v 4604 Å  absorption line is visible. If so, it means that the wind is optically thin in the continuum and that it is likely to be a helium main sequence star.
Given the similarity to HD 45166, we suggests that WR 7a may be a qWR – quasi Wolf–Rayet – star. Its classification is WN4h/CE in the Smith, Shara & Moffat three-dimensional classification system.     

Dissolution/precipitation kinetics of boehmite and gibbsite: Application of a pH-relaxation technique to study near-equilibrium rates

The dissolution and precipitation rates of boehmite, AlOOH, at 100.3 °C and limited precipitation kinetics of gibbsite, Al(OH)₃, at 50.0 °C were measured in neutral to basic solutions at 0.1 molal ionic strength (NaCl + NaOH + NaAl(OH)₄) near-equilibrium using a pH-jump technique with a hydrogen-electrode concentration cell. This approach allowed relatively rapid reactions to be studied from under- and over-saturation by continuous in situ pH monitoring after addition of basic or acidic titrant, respectively, to a pre-equilibrated, well-stirred suspension of the solid powder. The magnitude of each perturbation was kept small to maintain near-equilibrium conditions. For the case of boehmite, multiple pH-jumps at different starting pHs from over- and under-saturated solutions gave the same observed, first order rate constant consistent with the simple or elementary reaction: .

This relaxation technique allowed us to apply a steady-state approximation to the change in aluminum concentration within the overall principle of detailed balancing and gave a resulting mean rate constant, (2.2 ± 0.3) × 10⁻⁵ kg m⁻² s⁻¹, corresponding to a 1σ uncertainty of 15%, in good agreement with those obtained from the traditional approach of considering the rate of reaction as a function of saturation index. Using the more traditional treatment, all dissolution and precipitation data for boehmite at 100.3 °C were found to follow closely the simple rate expression:

R_net,boehmite=10^-5.485{m_OH^-}{1-exp(ΔG_r/RT)}, with R_net in units of mol m⁻² s⁻¹. This is consistent with Transition State Theory for a reversible elementary reaction that is first order in OH⁻ concentration involving a single critical activated complex. The relationship applies over the experimental ΔG_r range of 0.4–5.5 kJ mol⁻¹ for precipitation and −0.1 to −1.9 kJ mol⁻¹ for dissolution, and the pH_m ≡ −log(mH⁺) range of 6–9.6. The gibbsite precipitation data at 50 °C could also be treated adequately with the same model:R_net,gibbsite=10^-5.86{m_OH^-}{1-exp(ΔG_r/RT)}, over a more limited experimental range of ΔG_r (0.7–3.7 kJ mol⁻¹) and pH_m (8.2–9.7).     

The influence of the coast on the dynamics of upwelling fronts: Part II. Numerical simulations

We investigated the dynamics of upwelling fronts near a coast. This work was first motivated by laboratory experiments [Bouruet-Aubertot, Linden, Dyn. Atmos. Oceans, 2002] in which the front is produced by the adjustment of a buoyant fluid initially confined within a bottomless cylinder. It was shown that cyclonic eddies consisting of coastal waters are enhanced when the front is unstable near the coast (the outer vertical boundary). The purpose of this paper is to provide further insights into this process. We reproduced the experimental configuration using a three-dimensional model of the primitive equations. We first show that for coastal fronts more potential energy, in terms of the maximum available potential energy, is released than for open-ocean fronts. Therefore, waves of larger amplitude are generated during the adjustment and the mean flow that establishes has a higher kinetic energy in the former case. Then as baroclinic instability starts and wave crests reach the boundary, cyclonic eddies are enhanced as in the laboratory experiments and in a similar way. However, in contrast to the laboratory experiments, offshore advection of cyclonic eddies can occur in two stages, depending on the spatial organization of the baroclinic wave. When the baroclinic wave consists of the sum of different modes and is thus highly asymmetric, the offshore advection of cyclonic eddies occurs just after their enhancement at the boundary, as in the laboratory experiments. By contrast, when a single-mode baroclinic wave develops, neighboring cyclonic eddies first merge before being advected offshore. Very different behavior is observed for open-ocean fronts. First a mixed baroclinic–barotropic instability grows. Then the eddies transfer their energy to the mean flow and the barotropic and baroclinic instabilities start again. An excellent agreement is obtained with the main result obtained in the laboratory experiments: the ratio between growth rates of surface cyclonic and anticyclonic vorticity increases as the instability develops nearer to the coast.     

Hydrologic and water isotope characterization of a regulated Canadian Shield river basin

Stable water isotope surveys have increasingly been integrated into river basins studies, but fewer have used them to evaluate impact of hydropower regulation. This study applies hydrologic and water isotope survey approaches to a Canadian Shield river basin with both regulated and natural flows. Historical streamflow records were used to evaluate the influence of three hydroelectric reservoirs and unregulated portions of the basin on downstream flows and changes in water level management implemented after an extreme flood year (1979). In 2013, water isotope surveys of surface and source waters (e.g., rainfall, groundwater, snowmelt) were conducted to examine spatial and temporal variation in contributions to river flow. Seasonal changes in relative groundwater contribution were assessed using a water‐isotope mass balance approach. Within the basin, two regulated reservoirs exhibited inverted hydrographs with augmented winter flows, whereas a third exhibited a hydrograph dominated by spring snowmelt. In 2013, spatial variation in rain‐on‐snow and air temperatures resulted in a critical lag in snowmelt initiation in the southern and northern portions of the basin resulting in a dispersed, double peak spring hydrograph, contrasting with 1979 when a combination of rain‐on‐snow and coincident snowmelt led to the highest flood on record. Although eastern basin reservoirs become seasonally enriched in δ¹⁸O and δ²H values, unregulated western basin flows remain less variable due to groundwater driven baseflow with increasing influence downstream. Combined analysis of historical streamflow (e.g., flood of 1979, drought of 2010) and the 2013 water isotope surveys illustrate extreme meteorological conditions that current management activities are unable to prevent. In this study, the influence of evaporative fractionation on large surface water reservoirs provides important evidence of streamflow partitioning, illustrating the value of stable water isotope tracers for study of larger catchments.     

Resilience and seismic risk perception at school: a geoethical experiment in Aiello Calabro,southern Italy

The last few years have seen the debate on the geoethics of environmental and climatic protection growing to include resilience as a central idea within this new discipline, which holds many similarities with geography. Resilience analysis often looks at the capacity to re-establish conditions of equilibrium within a system which has been hit by a serious shock, e.g. a natural or man-made disaster. Geoethics works, in tandem with geological analyses and the geography of risk, to inform a population and develop integrated risk management in such a way as to strengthen a community’s resilience. The aim of this work is to study some people’s capacity to overcome what was potentially a disastrous event and, through a process of reconstruction, turn it into an occasion for growth. The experiment, carried out in the primary and middle schools in Aiello Calabro (Calabria, southern Italy), was conducted on the basis of the belief that there is a close relationship between a population’s having a realistic understanding of the risk of such an event, e.g. an earthquake, and high levels of resilience. We also tried to gain an insight into the relationship that may exist between resilience in primary and secondary school children and methods of coping which give an appropriate management of seismic risk. To be more precise, we try to discover whether there is a link between good/appropriate resilience and good/appropriate risk management.

     

Estuarine Habitat and Demographic Factors Affect Juvenile Chinook (<Emphasis Type="Italic">Oncorhynchus tshawytscha</Emphasis>) Growth Variability in a Large Freshwater Tidal Estuary

Estuarine rearing has been shown to enhance within watershed biocomplexity and support growth and survival for juvenile salmon (Oncorhynchus sp.). However, less is known about how growth varies across different types of wetland habitats and what explains this variability in growth. We focused on the estuarine habitat use of Columbia River Chinook salmon (Oncorhynchus tshawytscha), which are listed under the Endangered Species Act. We employed a generalized linear model (GLM) to test three hypotheses: (1) juvenile Chinook growth was best explained by temporal factors, (2) habitat, or (3) demographic characteristics, such as stock of origin. This study examined estuarine growth rate, incorporating otolith microstructure, individual assignment to stock of origin, GIS habitat mapping, and diet composition along ~130 km of the upper Columbia River estuary. Juvenile Chinook grew on average 0.23 mm/day in the freshwater tidal estuary. When compared to other studies in the basin our growth estimates from the freshwater tidal estuary were similar to estimates in the brackish estuary, but ~4 times slower than those in the plume and upstream reservoirs. However, previous survival studies elucidated a possible tradeoff between growth and survival in the Columbia River basin. Our GLM analysis found that variation in growth was best explained by habitat and an interaction between fork length and month of capture. Juvenile Chinook salmon captured in backwater channel habitats and later in the summer (mid-summer and late summer/fall subyearlings) grew faster than salmon from other habitats and time periods. These findings present a unique example of the complexity of understanding the influences of the many processes that generate variation in growth rate for juvenile anadromous fish inhabiting estuaries.     

Magnetostratigraphy across the Berriasian-Valanginian stage boundary (Early Cretaceous), at Cehegin (Murcia Province, southern Spain)

The Berriasian-Valanginian stage boundary near the town of Cehegin in the eastern Subbetic Cordillera of Spain is documented by a detailed ammonite zonation in pelagic limestones. Two magnetostratigraphic sections spanning the uppermost ammonite subzone of the Berriasian and the lower two zones of the Valanginian yielded identical magnetic polarity patterns. Remanent magnetization is predominantly carried by magnetite, and characteristic directions were obtained by thermal demagnetization. The mean characteristic directions from both sites have an inclination of 48°; however, the site declinations are divergent (030° and 074°) due to the tectonic disturbance of the region. The Cehegin polarity pattern can be correlated by means of ammonite and calpionellid zonation to the magnetostratigraphies of the Berriasian stratotype and several Italian sections, thereby enabling a unique correlation to the M-sequence magnetic polarity time scale. The Berriasian-Valanginian stage boundary is in the middle of normal-polarity chron M15n.     

Olivine-normative dolerite dikes from western South Carolina: Mineralogy,chemical composition and petrogenesis

This investigation describes five Mesozoic dolerite dikes which intrude Paleozoic metamorphic and igneous rocks of the Inner Piedmont of western South Carolina. The dikes are vertical or nearly so and strike approximately N40° W. Three major northeast-trending faults also occur in the study area. Left lateral displacement of one dolerite is documented at a locality near Cleveland, South Carolina. Elsewhere, several of the dolerite dikes appear to terminate at or near the faults. — The dolerite dikes have subophitic to microporphyritic textures and consist principally of plagioclase (generally An_70–80), olivine (dominantly Fo_80–90) and augite with subordinate pigeonite, titanomagnetite, chromite and brown, partly glassy mesostasis. In one dike pyroxene compositions trend from augite to ferroaugite in contrast to an augitesubcalcic augitepigeonite trend characteristic of the other dolerites. The contrasting trends primarily result from differences in SiO₂ abundance in the dolerite magmas. — Major and trace element analyses indicate the presence of two different olivine-normative dolerite magma types. The two magma types are not related by near surface crystal fractionation. Models for genesis of the olivine-normative dolerite magmas by partial melting of a plagioclase peridotite upper mantle source region are presented. The models require that the source region be enriched in LREE and incompatible elements such as Rb, Ba, Hf and Th relative to Cl chondritic abundances. One magma type appears to represent a primary dolerite magma that ascended from the source region with little subsequent compositional change. The second magma type most likely experienced assimilation of clinopyroxene-garnet (eclogite) during ascent, thereby acquiring a REE pattern with a less steep negative slope for the LREE and a slight positive slope in the HREE.