An answer to an important controversy and the need for caution when using simple models to predict inelastic earthquake response of buildings with torsion

This paper presents evidence that the extension of conclusions based on the widely used simplified, one story, eccentric systems of the shear‐beam type, to actual, nonsymmetric buildings and consequent assessments of the pertinent code provisions, can be quite erroneous, unless special care is taken to match the basic properties of the simplified models to those of the real buildings. The evidence comes from comparisons of results obtained using three variants of simplified models, with results from the inelastic dynamic response of three‐ and five‐story eccentric buildings computed with detailed MDOF systems, where the members are idealized with the well‐known plastic hinge model. In addition, a convincing answer is provided on a pertinent hanging controversy: For frame‐type buildings, designed in accordance with the dynamic provisions of modern codes (such as EC8 or IBC2000), which allow reduced shears at the stiff edge due to torsion, the frames at the flexible sides are the critical elements in terms of ductility demands. Copyright © 2009 John Wiley & Sons, Ltd.     

Ozone Production Efficiency in Savanna and Forested Areas during the EXPRESSO Experiment

NO, NO_x, NO_y and O₃ have been measuredduring the airborne EXPRESSO experiment, November 96,which took place near Bangui (Central Africa) at thebeginning of the dry season. This period correspondsto an intense burning activity. Chemical andphotochemical characteristics of the planetaryboundary layer, which corresponds most of the time tothe monsoon layer, and the Harmattan layer, which issituated above the latter, have been studied forsavanna as well as rain forest areas. These two layersare very different when considering the chemicalcomposition (especially for ozone and NO_z) andthe photochemical age.The relationship of photochemical ozone productionversus photochemical NO_x oxidation products hasbeen investigated. Results indicate an ozoneproduction efficiency (OPE) ranging from 6.3 to 14.8in the planetary boundary layer. Thus, this layer ischaracteristic of a photochemically young and activeair mass. In this layer, the ozone potentialproduction increases with the air mass photochemicalage. On the other hand, the Harmattan layer shows anOPE ranging from 4.6 to 7.4. These values arecharacteristic of photochemically well-aged airmasses. In this layer, the ozone potential productionseems to be exhausted with values around 4.0 (i.e., 4ozone molecules produced for each NO_x moleculeemitted).     

Numerical Modeling of the Long-Term Transport, Dispersion, and Accumulation of Black Sea Pollutants into the North Aegean Coastal Waters

This study investigates the long-term capacity of the North Aegean coastal systems to transport and store conservative pollutants that originate from the Black Sea. Emphasis is placed on modeling the dispersion and accumulation of a passive tracer that represents a Black Sea pollutant (BSP) substance that continuously discharges from the Dardanelles exit into the North Aegean, for a long period of time (16?years). The effects of the Black Sea water (BSW) inflows, meteorological forcing, and seasonal stratification are assessed with a 3D hydrodynamic model (Estuary, Lake and Coastal Ocean Model), after validation with available field data. The salinity, water temperature, and discharge from the Dardanelles Strait are taken to be seasonally varied. According to the authors' best knowledge, the present paper constitutes the first numerical modeling attempt in the literature that apart from the long-term hydrodynamic characteristics that have also been studied in previous works, a suitable tracer is introduced in order to predict the long-term fate, distribution, and accumulation of pollutants that originate from the Black Sea into the North Aegean coastal regions. The overall results of the present investigation indicate that the BSP concentration is very high at the coastal waters of Thassos, Samothraki, and Limnos islands, as well as along the mainland coastal waters between Alexandroupolis and Strymonikos Gulf, during summer and autumn when strong water column stratification occurs. In general, the BSP concentration in the North Aegean surface waters reaches considerable high values (47?C58?% of the initial pollutant concentration at Dardanelles inflow) within 16?years. Even for depths more than 500?m the BSP concentration is still remarkable, slightly increasing with time. The increase of the BSP concentration with respect to time at various depths (from free surface up to 750?m) is also investigated.     

Landfill Base Liners: Assessment of Material Equivalency and Impact to Groundwater

This paper gathered available flow and transport solutions and used them for two composite liners, consisting of geomembrane (GM) overlying either a compacted clay liner (CCL) or a geosynthetic clay liner (GCL). Its aim is to provide a guiding framework for the possible choices of (a) approaches to bottom liner design, (b) respective analytical solutions to flow and transport equations, as well as (c) parameters required for each type of solution. On the basis of the obtained results, the following recommendations are made. When the goal of analysis is to determine material equivalency, leachate flow rate is an adequate key parameter for GM-CCL composite liners. For GM-GCL composite liners, it is necessary to compute contaminant concentration or mass flux, considering (a) transport through defects for inorganic contaminants and (b) diffusion and the contribution of any available attenuation layer for organic contaminants. When the goal of analysis is to assess impact to groundwater, it is advised to calculate both discharge rate and contaminant mass flux regardless of liner type. The critical parameter for the transport calculations is the retardation factor of the contaminant, for the case of CCLs, while the results for GCLs are much less sensitive to this parameter.     

Accidental design eccentricity: Is it important for the inelastic response of buildings to strong earthquakes?

To deal with earthquake-induced torsion in buildings due to some uncertain factors, difficult to account for directly in design, modern codes have introduced the so-called accidental design eccentricity (ADE). This provision has been based primarily on elastic investigations with special classes of multi-story buildings or with simplified, one-story inelastic models. In the present paper, the effectiveness of this provision is investigated using inelastic models, both of the typical one-story, 3-DOF type, and the more sophisticated MDOF, frame idealizations of the plastic hinge type. One, three and five story, realistic, frame buildings with different natural eccentricities were designed for different ADEs, including those specified by the EC8 and IBC codes. The evaluation is made using mean peak ductility factors of the edge frames as measures of their inelastic response, obtained from dynamic analyses for ten pairs of semi-artificial earthquake motions. The simplified models indicate that the accidental design eccentricity is very effective in reducing ductility demands, especially for very stiff systems. However, this is not confirmed by the more accurate and detailed plastic hinge building models, which show that designs accounting for accidental eccentricity do not exhibit any substantial reduction or better distribution of ductility demands, compared to designs in which accidental eccentricity has been entirely ignored. These findings suggest that the ADE provisions in codes, especially the more complicated ones as in the IBC, should be re-examined, by weighting their importance against the additional computational work they impose on designers. In the cases examined herein this importance can be characterized as marginal. Obviously additional studies are required, to include more building types and earthquake motions, in order to arrive at firm conclusions and recommendations for code modifications.     

Relationship between MODIS based Aerosol Optical Depth and PM10 over Croatia

This study analyzes the relationship between Aerosol Optical Depth (AOD) obtained from Terra and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) and ground-based PM10 mass concentration distribution over a period of 5 years (2008–2012), and investigates the applicability of satellite AOD data for ground PM10 mapping for the Croatian territory. Many studies have shown that satellite AOD data are correlated to ground-based PM mass concentration. However, the relationship between AOD and PM is not explicit and there are unknowns that cause uncertainties in this relationship. The relationship between MODIS AOD and ground-based PM10 has been studied on the basis of a large data set where daily averaged PM10 data from the 12 air quality stations across Croatia over the 5 year period are correlated with AODs retrieved from MODIS Terra and Aqua. A database was developed to associate coincident MODIS AOD (independent) and PM10 data (dependent variable). Additional tested independent variables (predictors, estimators) included season, cloud fraction, and meteorological parameters — including temperature, air pressure, relative humidity, wind speed, wind direction, as well as planetary boundary layer height — using meteorological data from WRF (Weather Research and Forecast) model. It has been found that 1) a univariate linear regression model fails at explaining the data variability well which suggests nonlinearity of the AOD-PM10 relationship, and 2) explanation of data variability can be improved with multivariate linear modeling and a neural network approach, using additional independent variables.     

Ground-Based and Airborne Measurements of Nonmethane Hydrocarbons in BERLIOZ: Analysis and Selected Results

During the Berlin Ozone Experiment BERLIOZ in July–August 1998 quasi-continuous measurements ofC₂–C₁₂ nonmethane hydrocarbons (NMHCs) were carried out at 10 sites in and around the city of Berlin using on-line gas-chromatographic systems (GCs) with a temporal resolution of 20–120 minutes. Additional airborne NMHCmeasurements were made using canister sampling on three aircraft and an on-line GC system on a fourth aircraft. The ground based data are analyzed to characterize the different sites and to identify the influence of emissions from Berlin on its surroundings. Benzene mixing ratios at the 4 rural sites were rather low (<0.5 ppbv). Berlin (and the surrounding highway ring) was identified as the main source of anthropogenic NMHCs at Eichstädt and Blossin, whilst other sources were important at the furthermost site Menz. The median toluene/benzene concentration ratio in Berlin was 2.3 ppbv/ppbv, agreeing well with measurements in other German cities. As expected, the ratios at the background sites decreased with increasing distance to Berlin and were usually around one or below. On 20 and 21 July, the three northwesterly sites were situated downwind of Berlin and thus were influenced by its emissions. Considering the distance between the sites and the windspeed, the city plume was observed at reasonable time scales, showing decreasing toluene/benzene ratios of 2.3, 1.6 and 1.3 with increasing distance from Berlin. Isoprene was the only biogenic NMHC measured at BERLIOZ. It was themost abundant compound at the background sites on the hotter days, dominating the local NMHC reactivity with averaged contributions to the total OH loss rate of 51% and 70% at Pabstthum and Blossin, respectively. Emissionratios (relative to CO and to the sum of analysed NMHCs) were derived from airborne measurements. The comparison with an emission inventory suggests traffic-related emissions to be the predominating source of the considered hydrocarbon species. Problems were identified with the emission inventory for propane, ethene and pentanes.     

High PAN concentrations during nonsummer periods: A study of two episodes in Creteil (Paris), France

The effect of sunlight on air containing hydrocarbons and nitrogen oxides leads to a very complex series of reactions which form, among other secondary pollutants, peroxyacetylnitrate (PAN). This compound is believed to be the most useful indicator of photochemical pollution, and has been monitored for several months at the University of Creteil (Paris, France). Although it is commonly accepted that high PAN levels occur more frequently in summer, our results show elevated PAN concentrations during nonsummer periods, precisely during two episodes in October 1985 and February 1986. A close examination of these episodes indicates that, in addition to local photochemical production, long-range transport of polluted air masses can occur in winter, revealing the influence of emissions from central Europe.