Formation of Water-Bearing Defects in Olivine in the Presence of Water–Hydrocarbon Fluid at 6.3 GPa and 1200°C

The main trends of water dissolution in Fe-bearing olivine have been investigated in the olivine–H₂O–hydrocarbon fluid system in experiments at a pressure of 6.3 GPa, a temperature of 1200°C, and hydrogen fugacity ( fH₂) buffered by the Mo–MoO₂ equilibrium. The content and contribution of ОH defects of different types in Fe-bearing olivines depend on the composition of reduced fluids in the system. As the fraction of hydrocarbons in the fluid increases, the H₂O content in olivine crystals decreases from 900 to 160–180 ppm, while the ОН absorption peaks become lower at high frequencies and occupy a larger part of the infrared spectrum in the low-frequency region. According to the experimental results, even the deepest seated mantle olivines with OH defects were not equilibrated with a fluid rich in light alkanes or oxygenated hydrocarbons.     

Effect of oxygen fugacity on the H2O storage capacity of forsterite in the carbon-saturated systems

High pressure experiments have been performed in the systems Mg₂SiO₄-C-O-H and Mg₂SiO₄-K₂CO₃-C at 6.3 GPa and 1200 to 1600 °C using a split-sphere multi-anvil apparatus. In the Mg₂SiO₄-C-O-H system the composition of fluid was modeled by adding different amounts of water and stearic acid. The fO₂ was controlled by the Mo-MoO₂ or Fe-FeO oxygen buffers. Several experiments in the Mg₂SiO₄-C-O-H system and all experiments in the Mg₂SiO₄-K₂CO₃-C system have been conducted without buffering the fO₂. Forsterite in the system Mg₂SiO₄-K₂CO₃-C does not reveal OH absorption bands in the IR spectra, while forsterite coexisting with carbon-bearing fluid and silicate melt at logfO₂ from FMQ-2 to FMQ-5 (from 2 to 5 log units below fayalite-magnetite-quartz oxygen buffer) contains 800-1850 wt. ppm H₂O. The maximum concentrations were detected at 1400 °C and FMQ-3.5. We observed an increase in the solidus temperature in the system Mg₂SiO₄-C-O-H from 1200 to above 1600 °C with log fO₂ decreasing from FMQ-2 to FMQ-5. The increase of the solidus temperature and the broadening of the stability field of the H₂O-H₂-CH₄ subsolidus fluid phase at 1400-1600 °C explain the high H₂O storage capacity of forsterite relative to that crystallized from carbon-free, oxidized, hydrous, silicic melt. At temperatures above 1400 °C liquidus forsterite precipitated along with diamond from oxidized (FMQ-1) carbonate-silicate melt and from silicate melt dissolving the moderately reduced C-O-H fluid (from FMQ-2 to FMQ-3.5). Formation of diamond was not detected under ultra-reduced conditions (FMQ-5) at 1200-1600 °C. Olivine co-precipitating with diamond from dry carbonate-silicate or hydrous-silicic fluid/melt can provide information on the H₂O contents and speciation of the diamond-forming media in the mantle. The conditions for minimum post-crystallization alteration of olivine and its hydrogen content are discussed.     

Study of Geoelectrical Responses to Space Weather Anomalies: Auroral Latitudes,Yenisei-Khatanga Regional Trough

Izvestiya, Physics of the Solid Earth - Abstract—The paper presents the results of analysis of the geoelectric (telluric) field variability during the Earth’s magnetic field...     

Observations of extrasolar planet transits with the automated telescopes of the Pulkovo Astronomical Observatory

Exoplanet observations have been performed on the automated Pulkovo Observatory telescopes. We have obtained 33 transit light curves for 16 known exoplanets and six transit observations for three exoplanet candidates discovered by the Kepler telescope. Based on our observations, we have reliably confirmed the existence of an exoplanet with an extremely large radius, R _pl = 1.83 ± 0.16R _Jup, in the system KOI 256 and detected a strong deviation of its orbital revolution from the theoretically predicted one. During the transit of the exoplanet WASP-12b across the stellar disk, we detected bursts that could be caused by the planet transit across spots on the star or by the presence of a satellite around this exoplanet. We detected possible periodic variations in the duration of the exoplanet transit across the stellar disk with time for HAT-P-12b that could be caused by variations in orbital inclination. The transit duration and depth, the central transit time, and the radius and orbital inclination of the planet have been estimated. The equilibrium temperature and albedo have been estimated for several exoplanets.     

New photometric investigation of the Herbig Ae/Be star HD 52721, a close binary system: Evidence for the existence of large-scale azimuthal inhomogeneities

We present new results of our photometry for the Herbig Be star HD 52721 obtained from January 16 to March 25, 2013. A new data reduction technique is used. Using this technique, we have also reanalyzed the previous results of our photometry for this object pertaining to the period from March 7 to March 28, 2010. The Be star HD 52721 is known as an eclipsing variable with the period P = 1^d. 610. Two photometric minima observed during one period are a peculiarity of its photometric variability. They are separated in phase of the period P by 0.5 and differ from one another in depth by 0 ^m . 04. We have also detected additional minima observed at the phases of maximum brightness. We hypothesize that they can be associated with the existence of local azimuthal inhomogeneities rotating synchronously with the orbital motion of the binary component stars in the circumstellar envelope. When processing our CCD frames, we have applied an efficient CCD-frame rejection method that has allowed the accuracy of observations to be increased considerably. The CCD frames have been further processed using the Apex II software package, which is a universal software platform for astronomical image processing. We justify the need for additional photometric observations of HD 52721 in various color bands to confirm the hypothesis about the existence of azimuthal inhomogeneities in the program binary system and to analyze their physical properties.     

Synthesis of NH4-Substituted Muscovite at 6.3 GPa and 1000°C: Implications for Nitrogen Transport to the Earth’s Mantle

Doklady Earth Sciences - The synthesis of NH4-bearing muscovite at P = 6.3 GPa and T = 1000°C in equilibrium with NH3–H2O fluid is performed. It is determined that the newly formed...     

Astrometric and photometric studies of the asteroid 2008 TC3

Near real time astrometric and photometric observations of the asteroid 2008 TC3, discovered 19 hours before it fell to Earth in the area of northern Sudan, were conducted on the night of October 6–7, 2008, using an automated telescope ZA-320M of the Pulkovo Observatory. In the interval of 4 h, 270 observations in the integral band of the telescope were performed, which was about one-third of all global observations of the asteroid. Based on the analysis of all cases, physical parameters of the asteroid were assessed. The estimates of the absolute magnitude of the asteroid (M _V = 30.6 ± 0.4 μm), its size (4.8 ± 0.8 m), and weight (131 ± 5 t) were obtained. A frequency analysis of the observational series was conducted, which helped to detect the periodicity in the brightness variation of the asteroid. The elements of the heliocentric orbit of the asteroid were refined. The trajectory of the asteroid, taking into account the atmospheric drag and nonsphericity of the Earth, was simulated.