Detection of a new interstellar molecular ion, H2COH+ (protonated formaldehyde)

A new interstellar molecular ion, H2COH+ (protonated formaldehyde), has been detected toward Sgr B2, Orion KL, W51, and possibly in NGC 7538 and DR21(OH). Six transitions were detected in Sgr B2(M). The 1(1,0)-1(0,1) transition was detected in all sources listed above. Searches were also made toward the cold, dark clouds TMC-1 and L134N, Orion (3N, 1E), and a red giant, IRC + 10216, without success. The excitation temperatures of H2COH+ are calculated to be 60-110 K, and the column densities are on the order of 10(12)-10(14) cm-2 in Sgr B2, Orion KL, and W51. The fractional abundance of H2COH+ is on the order of 10(-11) to 10-(9), and the ratio of H2COH+ to H2CO is in the range 0.001-0.5 in these objects. The values in Orion KL seem to be consistent with the "early time" values of recent model calculations by Lee, Bettens, & Herbst, but they appear to be higher than the model values in Sgr B2 and W51 even if we take the large uncertainties of column densities of H2CO into account. We suggest production routes starting from CH3OH may play an important role in the formation of H2COH+.     

Process of Housing Damage Assessment: The 1995 Hanshin-Awaji Earthquake Disaster Case

Rebuilding of victims' livelihoods was a crucial issue in the restoration process in the1995 Hanshin-Awaji Earthquake Disaster. Housing damage assessment influencedmost of the rebuilding of the livelihood in the long term, because the Victim Certificatesissued by the local governments based on the results of the Housing damage assessmentwas required to receive most of the individual assistance measures. In the process ofHousing damage assessment, many complex problems arose, leading to extensivework on the part of the disaster responders. Consequently, a considerable number ofvictims were dissatisfied with the assessment and applied for a resurvey. Due to a floodof requests for resurvey, disaster responders had to work on damage assessment, leavingrelief activities aside.In order to facilitate Housing damage assessment, this paper discusses thefollowing five points: (1) the processes and the problems of assessments performedin the Hanshin-Awaji Earthquake Disaster, (2) the changes in the nature of informationneeded by the victims, (3) the improvements over the present damage assessment, (4)the housing situation in Japan, and (5) the international situation on damage assessment.It is obvious from the results that a poor damage assessment system and the size ofthe disaster produced a very large work load. Differences in appreciation among theinvestigators also contributed to unfair assessments and led to the victims beingincreasingly dissatisfied by the survey results. Finally, a design concept for acomprehensive damage assessment system, which has been derived from theabove five points, is proposed for post-disaster management.     

Resistivity of reservoir sandstones and organic rich shales on the Barents Shelf:Implications for interpreting CSEM data

Marine controlled source electromagnetic(CSEM)data have been utilized in the past decade during petroleum exploration of the Barents Shelf,particularly for de-risking the highly porous sandstone reservoirs of the Upper Triassic to Middle Jurassic Realgrunnen Subgroup.In this contribution we compare the resistivity response from CSEM data to resistivity from wireline logs in both water-and hydrocarbon-bearing wells.We show that there is a very good match between these types of data,particularly when reservoirs are shallow.CSEM data,however,only provide information on the subsurface resistivity.Careful,geology-driven interpretation of CSEM data is required to maximize the impact on exploration success.This is particularly important when quantifying the relative re-sistivity contribution of high-saturation hydrocarbon-bearing sandstone and that of the overlying cap rock.In the presented case the cap rock comprises predominantly organic rich Upper Jurassic-Early Cretaceous shales of the Hekkingen Formation(i.e.a regional source rock).The resistivity response of the reservoir and its cap rock become merged in CSEM data due to the transverse resistance equivalence principle.As a result of this,it is imperative to understand both the relative contributions from reservoir and cap rock,and the geological sig-nificance of any lateral resistivity variation in each of the units.In this contribution,we quantify the resistivity of organic rich mudstone,i.e.source rock,and reservoir sandstones,using 131 exploration boreholes from the Barents Shelf.The highest resistivity(＞10,000 Ωm)is evident in the hydrocarbon-bearing Realgrunnen Subgroup which is reported from 48 boreholes,43 of which are used for this study.Pay zone resistivity is primarily controlled by reservoir quality(i.e.porosity and shale fraction)and fluid phase(i.e.gas,oil and water saturation).In the investigated wells,the shale dominated Hekkingen Formation exhibits enhanced resistivity compared to the background(i.e.the underlying and overlying stratigraphy),though rarely exceeds 20Ωm.Marine mudstones typically show good correlation between measured organic richness and resistivity/sonic velocity log signatures.We conclude that the resistivity contribution to the CSEM response from hydrocarbon-bearing sandstones out-weighs that of the organic rich cap rocks.     

Natural and anthropogenic aquatic environmental changes reconstructed by paleolimnological analyses in Lake Kitaura,central Japan

In order to assess the recent anthropogenic environmental changes in Lake Kitaura, central Japan, changes during the past few centuries were reconstructed from results of radiometric and tephrochlonological age determination, magnetic susceptibility measurements, total organic carbon analyses, total nitrogen analyses and fossil diatom analyses on a sediment core from the lake. A total of six major and sub-zones are recognized according to the diatom fossil assemblages, and we discuss aquatic environmental change in Lake Kitaura mainly based on these diatom assemblage change. Zone Ia and Zone Ib (older than AD 1707) are marine to brackish. In Zone IIa (AD␣1707–AD 1836), most of the brackish diatoms disappeared, and were replaced by freshwater species indicating a decrease in salinity. We interpret the salinity decrease in Zone I–IIa as a sea-level fall during the Little Ice Age. The salinity of the lake decreased to near freshwater conditions in Zone IIb (AD 1836–AD 1970), which could arise from alteration in River Tone or development of a sandspit in the mouth of River Tone in addition to sea-level change. In Zone IIIa (AD 1970–AD 1987), the diatom assemblage indicates a freshwater environment, and sedimentation rates increase rapidly. These changes reflect sedimentary environment change and an ecosystem transition due to the construction of the tide gate. In Zone IIIb (AD 1987–AD 2002), the diatom flux (valves cm⁻² y⁻¹) increased and species composition changed. The changes in Zone IIIb show a good agreement with limnological monitoring data gathered from the lake. These paleolimnological data suggest that the recent human-induced changes of the aquatic environment of the lake after the 1970s exceed rates during the period concerned in this study.     

Trace elements in skin of Dall's porpoises (Phocoenoides dalli) from the northern waters of Japan: an evaluation for utilization as non-lethal tracers

Concentrations of Fe, Zn, Cu, Se, Mn, Mo, Hg, Cd, Cr, Ag, Pb, Sr and V were determined in skins of Dall's porpoises (Phocoenoides dalli) of the Pacific coast truei-type population (PT population) (N=45), and the Sea of Japan-Okhotsk dalli-type population (JD population) (N=31) from the northern waters of Japan. Cutaneous Hg concentrations in both PT and JD populations were significantly correlated with age, indicating a possible alternative method of age estimation. A significant correlation was also noted between Hg concentrations in skin and liver, suggesting that biopsy samples of skin can provide a non-lethal surrogate for monitoring Hg contamination in this species. Trace element accumulation patterns differed strongly between PT and JD populations, when analyzed by principal component analysis, suggesting these patterns could be utilized as non-lethal tracers of population identification.     

Solubility of FeO in (Mg,Fe)SiO3 perovskite and the post-perovskite phase transition

Phase relations in Mg_0.5Fe_0.5SiO₃ and Mg_0.25Fe_0.75SiO₃ were investigated in a pressure range from 72 to 123 GPa on the basis of synchrotron X-ray diffraction measurements in situ at high-pressure and -temperature in a laser-heated diamond-anvil cell (LHDAC). Results demonstrate that Mg_0.5Fe_0.5SiO₃ perovskite is formed as a single phase at 85–108 GPa and 1800–2330 K, indicating a high solubility of FeO in (Mg,Fe)SiO₃ perovskite at high pressures. Post-perovskite appears coexisting with perovskite in Mg_0.5Fe_0.5SiO₃ above 106 GPa at 1410 K, the condition very close to the post-perovskite phase transition boundary in pure MgSiO₃. The coexistence of perovskite and post-perovskite was observed to 123 GPa. In addition, post-perovskite was formed coexisting with perovskite also in Mg_0.25Fe_0.75SiO₃ bulk composition at 106–123 GPa. In contrast to earlier experimental and theoretical studies, these results show that incorporation of FeO stabilizes perovskite at higher pressures. This could be due to a larger ionic radius of Fe²⁺ ion, which is incompatible with a small Mg²⁺ site in the post-perovskite phase.