Strain localization in sandstone during embryonic stages of shear-zone evolution

Geometric analysis of nested Riedel structures was used to identify and quantify strain localization processes within faulted Navajo sandstone. The analysis shows systematic deviation from the basic Riedel geometry complying with the Mohr–Coulomb criterion. Using cross-cutting relations amongst deformation bands within the Riedel structures, and comparing the orientations of the deformation bands to theoretical strain calculations, we identify two coupling deformation mechanisms involved in the early stages of shear-zone evolution, namely, granular flow and discrete faulting. Both mechanisms localize during strain accumulation, and the granular flow facilitates considerable change in the initial geometry of the Riedel structures. The analysis demonstrates a systematic sequence, by which new Riedel structures form after a constant amount of shear strain takes place in the sandstone. Analysis further indicates that granular flow is the major deformation mechanism during early stages of shear-zone evolution and discrete faulting is the dominant mechanism during later deformation stages.     

Cosmic-ray propagation in compressible turbulent media

The influence of compressibility of media on both the statistical acceleration and the turbulent diffusion of cosmic-ray particles is investigated. The averaging over an ensemble of random velocity fields of the medium was performed in the kinetic equation. The kinetic coefficients, which are responsible for the particle acceleration, were obtained in the cases of weak and strong scattering due inhomogeneous magnetic fields.     

Diffusion of seawater ions. Part II. The role of activity coefficients and ion pairing

A theoretical evaluation of basic thermodynamic relationships reveals that variation of activity coefficients, ion pairing and electrical interactions must be considered when modelling ionic diffusion in seawater. The contributions of ion-pair formation and change in activity coefficient along the diffusion path were studied experimentally by conducting diffusion experiments in which solutions of KCl, NaCl, MgCl₂, Li₂SO₄, K₂SO₄, Na₂SO₄ and MgSO₄, at an ionic strength of 0.7, were allowed to diffuse into distilled water. The study reveals that the thermodynamic factor, required to correct for changes in the activity coefficient along the diffusion path, is significant for all the salts studied. Agreement between a simple diffusion model, which does not include ion pairing, and observed data was good for completely dissociated salts, but poor for salts which are known to form ion pairs at the concentration levels studied. The diffusion of MgSO₄, 0.425 of which is associated at I = 0.7, was successfully modelled by assuming that the diffusion coefficient of the MgSO₄⁰ ion pair is different from the diffusion coefficient of the dissociated salt. The diffusion coefficient of this ion pair is estimated to be 1.9 × 10⁻⁵ cm² s⁻¹ at 30°C, as compared to 0.49 × 10⁻⁵ cm² s⁻¹ for the dissociated salt. It is suggested that the high mobility of this ion pair could cause magnesium enrichment in pore water of sulfate depleted sediments.     

Effects of benzene and dimethylnaphthalene on homeostatic processes in two species of crabs

Long-term exposure of animals to sub-lethal doses of toxicants such as benzene (B) and dimethylnaphthalene (DMN) may result in subtle changes in their physiology and biochemistry. In crustaceans such changes include decreased rate of limb regeneration, extended time to molt and decreased growth increment at molt.^1,2 These processes depend upon an adequate supply of stored nutrients in the tissues and appropriate release of neuroendocrine substances from the central nervous system.^3,4 We are examining the effects of sub-lethal doses of B and DMN on osmotic and ionic regulation and on nutrient storage in the blue crab, Callinectes sapidus, and the green crab, Carcinus maenas. Disturbances in these physiological processes may reflect alterations in neuroendocrine functions brought about by the presence of toxicants. We find that exposure of C. maenas to B or DMN, followed by transfer to a dilute medium, results in impaired osmoregulatory capacity, while addition of these compounds to a dilute medium to which the animal is already acclimated does not affect their regulatory ability. Storage of carbohydrate in the midgut gland (hepatopancreas) is decreased by B or DMN, while the accessory storage tissues (gill, muscle) are not significantly affected.     

The MV Rena shipwreck: time-critical scientific response and environmental legacies

ABSTRACT

The sinking of the MV Rena on Astrolabe Reef (Otaiti) in the Bay of Plenty, New Zealand, resulted in the release of oil and ship debris, including dangerous goods carried as cargo. Two key questions of concern to the public and environmental managers were posed immediately: what was the impact of the Rena oil spill and how long would it take for the marine environment to recover? The research that began immediately after the ship grounded provided answers, as documented in this special issue.     

The wreck of the MV Rena: spatio-temporal analysis of ship-derived contaminants in the sediments and fauna of Astrolabe Reef

ABSTRACT

The October 2011 sinking of the container ship MV Rena on Astrolabe Reef, New Zealand, provided a rare opportunity to examine the fate of shipwreck-derived contaminants on an offshore rocky reef and food chain. Analyses of trace metals, polycyclic aromatic hydrocarbons (PAHs) and organotins indicated significant but localised contamination of Astrolabe Reef but not of nearby Mōtītī Island. Three years after the grounding, PAH concentrations were greater in sediments at Astrolabe (up to 131?mg kg^?1) than at control locations, while organotins from the ship's antifouling hull paint were found exclusively in Astrolabe Reef sediments and biota. Over 80% of Astrolabe sediment samples contained tributyltin at concentrations above guideline sediment levels (>0.07?mg kg^?1). Tributyltin and its decomposition products were also recorded in sea urchins, gastropods, lobster and fishes at concentrations up to 0.2?mg kg^?1. Wreck and cargo-derived metals, particularly copper, tin and zinc, were present in some Astrolabe sediment samples above Australia and New Zealand Environment and Conservation Council guideline concentrations. However, there appeared to be only limited transmission of metals through the food chain. Copper, tin and zinc were recorded at greater concentrations in Astrolabe sea urchins and gastropods compared to control specimens, while metal concentrations in other biota were comparable across impact and control sites. Despite over 3 years having passed since the Rena grounding, the data series does not show any upward or downward trends in contaminant concentrations on Astrolabe Reef. Consequently, there is uncertainty about the long-term implications of the Rena grounding for the ecology of Astrolabe Reef.     

In situ sampling reveals rapid uptake and depuration of polycyclic aromatic hydrocarbons by surf clams (Paphies subtriangulata) affected by the Rena oil spill

ABSTRACT

To investigate the uptake and depuration of polycyclic aromatic hydrocarbons associated with the Rena oil spill we sampled the surf clam Paphies subtriangulata at two open coast locations (6?km apart) just prior to oil coming ashore (7 October 2011), then at 1–3 week intervals for the next 4 months. Total polycyclic aromatic hydrocarbons (tPAH) increased at both sites from 1 to 96–124?µg?kg^?1 (wet weight) by 18 October before declining to low levels (<4?µg?kg^?1) by February 2012. Ongoing sampling throughout 2012–2014 included three additional sites to the north east (up to 30?km away) and a site 5?km to the south east revealing tPAH levels generally <10?µg?kg^?1 except in October 2013 where levels ranged between 39–45?µg?kg^?1 at all sites. A comparison of PAH component profiles with oil-contaminated beach sediment indicated that the high levels observed in surf clams between October–December 2011 were clearly associated with the Rena spill. However, the October 2013 peak had a PAH profile inconsistent with weathered Rena oil, suggesting an alternative source of contamination. Our results highlight the potential for P. subtriangulata as a PAH monitoring tool but recognise more study is needed to better quantify baseline levels and uptake and depuration dynamics.     

Lacustrine basin hydrocarbon exploration – current thoughts

Although much of the world's petroleum resource-base is associated with marine systems, regionally lacustrine petroleum systems are important. Individual accumulations may exceed several billion barrels. In each of these cases the oil is derived from a lacustrine source rock and may be produced from either nonmarine or marine reservoir rocks. The purpose of this paper is to describe the factors that control lacustrine source rock development and the nature of lacustrine reservoirs. Lacustrine oils display different physical and chemical characteristics than their marine counterparts. These differences can be related to the nature of their precursor material. Although the nature of the products are different, the geochemical threshold criteria for defining source rocks in both settings are the same because of common expulsion requirements. Commercially significant lacustrine systems require the presence of large, long-lived lakes. Such lake settings are tectonic in origin and restricted to climatic settings where precipitation exceeds evaporation. Within these large lake systems three primary factors determine source rock potential and quality. These factors are primary productivity level, organic preservation potential, and matrix sedimentation rate, which controls the dilution of preserved organic matter. Source rock potential is maximized where both productivity and preservation potential are maximized and sedimentation rate is minimized. To some degree these factors can compensate for each other. Hydrocarbon reservoir potential within lacustrine basins is partially impacted by overall tectonic setting. Within extensional settings, transport distances tend to be limited, with much of the sediment being transported away from the basin. The sediments delivered to the lake are poorly sorted and sedimentologically immature, commonly resulting in poor reservoirs due to both primary properties and their susceptibility to diagenesis. Within rifts better reservoirs tend to develop along platform or flexural margins. Stacking of reservoirs is important in lacustrine systems but baffles and barriers are often present between individual sand units. These barriers form as a result of lake level fluctuations. In compressional settings transport distances tend to be longer, resulting in more mature, better sorted sediments leading to higher quality reservoirs. These reservoirs typically develop in fluvial-deltaic and wave-dominated shoreline settings. Lacustrine carbonate reservoirs are locally important. These carbonates tend to develop during lake level lowstands and are dependent on diagenesis (dissolution and karstification) for porosity and permeability development. Lacustrine reservoirs are often stratigraphically and areally limited and display low individual well production rates. Within pure lacustrine systems exploration opportunities appear to be often restricted by either reservoir presence or quality (i.e., production rates). The best exploration opportunities in lacustrine basins appear to be associated with hybrid systems where a lacustrine source and marine reservoir exist.