Oxygen and bulk element abundances in Luna 20 fines

Abundances of O, Si, Al and Mn have been determined in Luna 20 fines sample 22001,9 by instrumental neutron activation analysis. The abundances of O, Si and Al are among the highest we have observed in lunar samples and reflect a highlands origin for much of this regolith sample. The Luna 20 abundances reported here most closely resemble those we have determined in four samples of two Apollo 16 fines, rock 14310, and a clast from breccia 15459. The Luna 20 $\text{O}\text{Si}$ ratio of 1.96 ± 0.05 is similar to that in most other lunar samples, but the $\text{Al}\text{Si}$ ratio of 0.532 ± 0.024 is exceeded only by our data on the Apollo 16 fines. This $\text{Al}\text{Si}$ ratio is in agreement with the value of 0.55 ± 0.06 determined by the remote X-ray fluorescence experiment for the highlands between Mare Crisium and Mare Smythii which lie near the Luna 20 site (Adleret al., 1972).     

Examining access to GP services in rural Ireland using microsimulation analysis

This paper analyses the effect accessibility has on General Practitioner (GP) utilisation rates at the sub-national level for Ireland. Specifically, the aim of this paper is to estimate whether there is an urban–rural differential in GP utilisation rates. We do this by simulating micro-level healthcare data. Using this synthetic data, simple logit models are employed to estimate the likelihood that individuals in different jurisdictions will attend a GP surgery. These individual logit estimates are then inputted into a spatial interaction model to highlight areas with low GP accessibility given their health status. The policy implications of these results are discussed in relation to both the healthcare literature and current Irish healthcare policy.     

Thiols in hydrothermal solution: standard partial molal properties and their role in the organic geochemistry of hydrothermal environments

In order to assess the potential role of organic sulfur compounds in hydrothermal systems, we use recent advances in theoretical geochemistry to estimate the standard partial molal thermodynamic properties and parameters for the revised Helgeson-Kirkham-Flowers equation of state for aqueous straight-chain alkyl thiols. Thermodynamic properties are used to determine the potential for thiol formation in both modern and Archean hydrothermal systems. We conclude that organic sulfur compounds may hold the key to the organic chemistry that led to the origin of life in hydrothermal settings. These results may also explain the presence of sulfur in a number of biomolecules present in ancient thermophilic microorganisms.     

ELEMENTAL ABUNDANCES IN THE HAVERÖ METEORITE

Abundances of 15 major, minor and trace elements have been determined in powders and interior chips derived from the Haverö ureilite. The values are in close agreement with mean values for other ureilites, as reported in the literature. The powdered samples exhibited slightly higher abundances of O and Si, than the interior chips. It is suggested that this may be due to alteration of the samples during the powdering process     

CHEMICAL ANALYSES OF THE MURCHISON AND LOST CITY METEORITES

The abundances of 22 elements have been determined in the recently fallen Murchison and Lost City meteorites. Analyses were performed by 14-MeV neutron activation, thermal neutron activation, and in a few cases by wet chemical techniques. On the basis of these data the composition of the Murchison chondrite is intermediate between previously reported analyses of Type II and Type III carbonaceous chondrites. The data for the Lost City chondrite in general agree well with mean values reported for H-group ordinary chondrites. The low oxygen content of the Lost City chondrite suggests that previously reported oxygen abundances in H-group falls may be too high due to oxidation in storage or weathering prior to collection     

Energetics of potential heterotrophic metabolisms in the marine hydrothermal system of Vulcano Island, Italy

Values of overall Gibbs free energy of 144 organic oxidation (respiration) and disproportionation (fermentation) reactions are calculated at the temperatures and chemical compositions that exist in nine submarine vents, sediment seeps and geothermal wells in the hydrothermal system of Vulcano Island, Italy. The organic compounds considered here include four carboxylic acids (formic, acetic, propanoic and lactic), two C₅ aldoses (arabinose and xylose), three C₆ aldoses (galactose, glucose and mannose), and 15 protein-forming amino acids (Ala, Arg, Asp, Glu, Gly, His, Ile, Leu, Lys, Met, Phe, Ser, Thr, Tyr, and Val). Oxidation of these compounds is coupled to five redox pairs: O₂/H₂O, , S⁰/H₂S, and Fe₃O₄/Fe²⁺. Energy yields from potential respiration reactions range from 6 to 118 kJ/mol of electrons transferred and show systematic behavior with respect to the terminal electron acceptor. Overall, respiration with O₂ yields the most energy (98–118 kJ/mol e⁻), followed by reactions with (53– 86 kJ/mol e⁻), magnetite (29–91 kJ/mol e⁻), S⁰ (11–33 kJ/mol e⁻) and (6–34 kJ/mol e⁻). Energy yields show little correlation with organic compound family, but are correlated with fluid pH. Variability in energy yields across the nine sites is greatest for Fe(III) reduction and is primarily influenced by pH and the activity of Fe²⁺. In addition to the potential respiration reactions, the energetics of 24 potential fermentation reactions are also calculated. As expected, fermentation reactions generally yield much less energy than respiration. Normalized to the number of moles of carbon transferred, fermentation yields−8 to 71 kJ/mol C, compared with 16 to 531 kJ/mol C for respiration reactions. All respiration and fermentation reactions, except for methionine (Met) fermentation, are exergonic under the in situ hydrothermal conditions and represent a plethora of potential metabolisms for Vulcano’s diverse thermophilic heterotrophs.     

Reorientation of three‐component borehole magnetic data

Three‐component borehole magnetics provide important additional information compared to total field or horizontal and vertical measurements. These data can be used for several tasks such as the localization of ferromagnetic objects, the determination of apparent polar wander curves and the computation of the magnetization of rock units. However, the crucial point in three‐component borehole magnetics is the reorientation of the measured data from the tool's frame to the geographic reference frame North, East and Downwards. For this purpose, our tool, the Göttinger Borehole Magnetometer, comprises three orthogonally aligned fibre optic gyros along with three fluxgate sensors. With these sensors, the vector of the magnetic field along with the tool rotation can be recorded continuously during the measurement. Using the high–precision gyro data, we can compute the vector of the magnetic anomaly with respect to the Earth's reference frame. Based on the comparison of several logs measured in the Outokumpu Deep Drill Hole (OKU R2500, Finland), the repeatability of the magnetic field vector is 0.8° in azimuthal direction, 0.08° in inclination and 71 nT in magnitude.     

PAPUANITES: PSEUDO-TEKTITES FROM NEW GUINEA

Spherical translucent green glasses found in New Guinea for many years have the external appearance of stream abraded tektites, but are chemically distinct from known tektite groups. Their chemical composition is most similar to artificial glasses. If these objects are the source of reports of tektites occurring in New Guinea, the existence of New Guinea tektites must now be discounted.     

Zirconium and hafnium in meteorites

The abundances of zirconium and hafnium have been determined in nine stony meteorites by a new, precise neutron-activation technique. The Zr/Hf abundance ratios for the chondrites vary in a rather narrow range, consistent with previously published observations from our group. Replicate analyses of new, carefully selected clean interior samples of the C1 chondrite Orgueil yield mean zirconium and hafnium abundances of 5.2 and 0.10 ppm, respectively. These abundances are lower than we reported earlier for two C1 chondrite samples which we now suspect may have suffered contamination. The new C1 zirconium and hafnium abundances are in closer agreement with predictions based on theories of nucleosynthesis than the earlier data.     

Bismuth in stony meteorites and standard rocks

Bismuth has been determined by alpha counting of the ²¹⁰Po daughter activity of the ²¹⁰Bi formed by thermal neutron activation. Results are presented for thirty chondrites, six achondrites, eight separated meteoritic phases, and six U.S. Geological Survey standard rocks. There is no resolvable difference in Bi abundances among the different groups of ordinary chondrites. Bismuth concentration decreases with increasing petrologic grade among the ordinary chondrites. The enstatite chondrites are separable into two groups on the basis of Bi data.