Chemical fingerprints of life in terrestrial soils and their possible use for the detection of life on Mars and other planets

Organic carbon in oxidizable forms and nitrogen are the only elements among some 40 elements studied that are significantly enriched in terrestrial soils as compared to the crust. This enrichment is due to and reflecting life activity in soils, and is characterized by a unique profile distribution. It is suggested that these facts can constitute the basis for the future chemical-biological search for life in planetary soils.     

Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.     

Glacial Erosion in the Abisko Mountains: Kärkevagge and Vassivagge, Northern Sweden

This paper discusses direct current resistivity soundings and geomorphological studies of Quaternary deposits in two glacial troughs in the Abisko Mountains of northern Sweden. The subject of the fieldwork is the depth of Pleistocene glacial erosion. Studies were carried out in 1998 and 2003 in the Kärkevagge and Vassivagge. The estimated thickness of Quaternary deposits and bedrock properties are discussed in the broader context of glacial erosion studies in the Abisko area. Geophysical and geomorphological studies suggest that the depth of glacial erosion was highly differentiated from –190 m in the Torneträsk basin to the metric overall erosion on the upland plateau. In medium‐sized valleys several kilometres long, erosion depth measures 30–50 m. Present‐day stream channel patterns reveal a strong relation to the bedrock configuration in valley floors     

Geochemistry and Rb–Sr geochronology of a ductile shear zone in the Orlica-Śnieżnik dome (West Sudetes, Poland)

Amphibolite-facies orthogneisses of the Orlica-vnie™nik dome in the West Sudetes (Poland) show a local continuous transition from weakly deformed augen gneisses to finely laminated mylonites. Field evidence indicates that ductile shearing developed pre- or syntectonically to a migmatization event. Bulk-rock compositions of variably deformed samples yield no indications for deformation- and/or fluid-enhanced element mobility and redistribution. ⁸⁷Rb-⁸⁶Sr geochronology (biotite, phengite, whole rock) places time constraints on the deformation process and the post-orogenic cooling history. Phengite- and biotite-whole-rock pairs yield Rb-Sr ages of 340 to 334 Ma and 335 to 294 Ma, respectively, independent of the degree of deformation. The weighted mean of phengite-whole-rock pairs indicates an age of 337.4DŽ.3 Ma. Combining most of the biotite-whole-rock data yields a weighted mean age of 328.6dž.4 Ma. Because of their different closure temperatures for the Rb-Sr system, these differences are interpreted to date cooling after a thermal event. Direct dating of the deformation is not possible, but the cooling history record defines a minimum age for the development of ductile shearing and the last migmatization event. These time constraints provide evidence for the initiation of crustal collapse during or immediately following peak metamorphic conditions. The results of this study further document the importance of Variscan metamorphism in the Orlica-vnie™nik dome.     

Nonlinear Rate Dependent Model of High Damping Rubber Bearing

The accurate analysis of the response of isolated structures requires the application of appropriate models of isolation devices. The purpose of this paper is to analyse a nonlinear strain rate dependent model of a high damping rubber bearing which simulates the horizontal behaviour of the device under specified vertical load using a nonlinear elastic spring-dashpot element. The effectiveness of the model is checked by fitting the experimental data concerning three different rubber bearings. The results of the study show that the model can simulate the bearing behaviour over a wide shear strain range with small simulation errors. This revised version was published online in July 2006 with corrections to the Cover Date.     

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.     

The hydrogeology of the Ballimore region,central New South Wales,Australia: an integrated study

The integrated use of geophysical, geological, hydrogeochemical and hydrogeological data has allowed the development of a plausible conceptual model for groundwater flow in the Ballimore region. A realistic model for this under-explored system could not be derived solely by the use of hydrogeological data. Interpretation of the available datasets indicates that two groundwater systems are active: a regional and a local system. These are separated by a regionally extensive aquiclude. Groundwater flow in the regional groundwater system is controlled by the structural fabric of the Palaeozoic basement rocks. The local groundwater system is restricted to the Permian to Recent sequence of cover rocks. The local groundwater system is subdivided into three cells: the deep, intermediate and shallow cells. Groundwater flow within the deep cell of the local groundwater system is controlled by fracture flow. Groundwaters from this aquifer are under artesian pressure and are effervescent (CO₂-gas). The intermediate cell is a leaky aquitard that acts as a mixing zone between the deep and shallow cells. Groundwater flow within the shallow cell is controlled by the influx of surface waters which migrate laterally through permeable beds.     

Revisiting the abandoned shorelines of Lake George,Australia: a refined optical dating framework

Abandoned shorelines are an important archive used to constrain past fluctuations in the hydrological balance of lakes around the globe. Within Australia, the shorelines preserved at Lake George, NSW, form one of the few shoreline archives in the south-east of the continent that record palaeoenvironmental conditions throughout the late Quaternary. Here, we examined and tested the lake-level record for Lake George constructed in the 1970s by dating a well-preserved shoreline sequence at Luckdale, on the lake's eastern shore, using single-grain optically stimulated luminescence (OSL) dating. Ten stratigraphic units were identified, and these suggest a late Quaternary highstand for Lake George in MIS 3, with fluctuations superimposed upon an overall drying trend throughout MIS 2 and into the present. At Luckdale, the highest four shoreline-associated units were deposited ~13 to 19 m above lake base and date to between 39 ± 2 and 29 ± 1 ka ago. Our study pushes back the timing of maximum lake depth at Lake George to at least MIS 3, rather than MIS 2. The overall drying trend is supported by similar reductions in both Riverine Plain fluvial activity and other associated lake-level records from within the Murray basin.