Groundwater-flow modeling in the Yucatan karstic aquifer, Mexico

The current conceptual model of the unconfined karstic aquifer in the Yucatan Peninsula, Mexico, is that a fresh-water lens floats above denser saline water that penetrates more than 40 km inland. The transmissivity of the aquifer is very high so the hydraulic gradient is very low, ranging from 7–10 mm/km through most of the northern part of the peninsula. The computer modeling program AQUIFER was used to investigate the regional groundwater flow in the aquifer. The karstified zone was modeled using the assumption that it acts hydraulically similar to a granular, porous medium. As part of the calibration, the following hypotheses were tested: (1) karstic features play an important role in the groundwater-flow system; (2) a ring or belt of sinkholes in the area is a manifestation of a zone of high transmissivity that facilitates the channeling of groundwater toward the Gulf of Mexico; and (3) the geologic features in the southern part of Yucatan influence the groundwater-flow system. The model shows that the Sierrita de Ticul fault, in the southwestern part of the study area, acts as a flow barrier and head values decline toward the northeast. The modeling also shows that the regional flow-system dynamics have not been altered despite the large number of pumping wells because the volume of water pumped is small compared with the volume of recharge, and the well-developed karst system of the region has a very high hydraulic conductivity. Electronic Publication     

Urban form study: the sprawling city—review of methods of studying urban sprawl

There is a large body of research on urban forms. This review paper focuses on the urban sprawl using new and old approaches and new techniques from the subfield of urban Geography. There has been a debate among researchers about the definition of the sprawl, which makes it difficult to suggest a reliable model of the urban sprawl. This review is extremely selective. Numerous papers have focused on measuring the in terms of its physical cost or the environmental and transportation measures linked to this phenomenon. Several attempts have been made to improve the measurement of the sprawl using new approaches. Furthermore, this paper show that certain researchers did not attempt to explore new methods to investigate the urban sprawl in the past and present overlay layers for many years, researchers may use cartography techniques, for example, thereby collecting 20 years of data to match layers and show the differences in any metropolitan area. Several problems remain like differences in the understanding of the sprawl among planners and between other researchers interested in this issue. Also, it is problematic to find one measure, such as mixing different measures together to distinguish between car density and resident density. This study evaluated and reviewed old and recent studies to show that the most important issue in the urban sprawl relates to measurements. Incorporates inform and which measure is best. This article argues that urban spatial expansion reviews some of articles written on urban sprawl and showing the different approaches to studying.

     

An ecosystem-based composite spatial model for floodplain vulnerability assessment: a case study of Artigas,Uruguay

Floods are natural processes that constitute a hazard to society when associated to improper land use. Anthropic activities in floodplains are a factor of vulnerability that converts a natural hazard into a threat factor, eventually leading to disaster. Nowadays, natural and social complex processes demand integrated assessments in order to improve their understanding, helping decision making over sustainable use of territory, as well as integrating society’s activity in ecosystems and potentials, restrictions and benefits that society obtain from them. In this context, the objective of this work was to build a composite vulnerability model for a floodplain under urban influence, using an integrated assessment approach. This model was based on three dimensions; threat, fragility and an ecosystem services provision. These dimensions were calculated using both primary and secondary information, and weights by specialists. Main results show that the area presents high vulnerability with an increasing gradient towards high and urbanized areas, associated with an important number and relevant ecosystem services. Also, a spatial heterogeneity of the three dimensions emerged, making evident this area’s complexity and the need of integrated assessments to approach it. The composite vulnerability model proposed presents an elevated potential for natural and social processes analysis in floodplains, which is crucial for these territory management. Moreover, these integrated dimensions could contribute to decision making in different levels, as well as generating important supplies for environmental management and land planning.

     

Approaches to environmental restoration of a polluted harbour with submerged archaeology: the Alexandria case study

Many invaluable underwater buildings of archaeological interest in Alexandria were discovered in 1996 at different sites in the Eastern Harbour of Alexandria. There is a belief that the best way to protect these invaluable heritages is to transfer them to an underwater park or museum. Obviously, the execution of such a project depends essentially upon the water quality (including water transparency) improving in the future. The harbour is presently polluted by discharge of wastewater effluents from different sources. It has recently been decided to restore this important coastal area through: (1) stopping the direct discharge of wastewater effluents into this semi-enclosed harbour in 1993 and (2) gradually reducing the discharge of the municipal wastewater through marine outfalls at two sites lying at the outer sides of the harbour. Zero discharge is expected to be effective by the end of the year 2001. The present work, therefore, is a follow up of the study of water quality in the harbour after 1993: in 1996 and 1999-2000. The water quality of an open sea reference station was also studied for comparison. The results reveal occurrence of an improvement of the environmental conditions in the harbour. The water has turned from being eutrophic to mesotrophic. The harbour is expected to become meso/oligotrophic as soon as the complete cessation of the discharge from the two outside sources is attained.     

Development and behaviour of a radar-based operational tool for hailstorms identification

Hailstorms are a common meteorological phenomenon in Spain which causes substantial economic damage especially in spring and summer. During 2000 and 2001, a radar-based application for convective monitoring was developed at STAP (Forecasting and Analysis Techniques Department); in order to improve this nowcasting tool, it is needed to include an advanced procedure to estimate the presence of hail as a complementary module in the operational application. A preliminary study, carried out during 2001, showed that the Waldvogel technique, VIL (vertical integrated liquid) density and the hail detection algorithm (HDA) are the methodologies which proved more accurate in our latitudes.Throughout the spring and summer of 2001, all available information about hail events (time, place and hail size) and about storms without hail was used for tuning an experimental module to detect severe and non-severe hailstorms, taking into account the selected algorithms. During 2002, further information about storms was gathered in order to assess the behaviour of the developed hail module. Afterwards, a new module calibration was carried out with the information of the complete storms data set of 2001 and 2002. With this new calibration, the hail module became an operational tool during the spring and summer of 2003. Currently, the verification of the operational module using the data from the storms in 2003 is being elaborated. The aim of this work is to put forward the calibration procedure carried out, the verification results of 2002, and the performance of the hail estimate module in selected cases during 2003 in Spain.     

Synthesis and characterization of zeolite X obtained from kaolin for adsorption of Zn（Ⅱ）

This study deals with the synthesis and characterization of low-silica zeolite X, from calcined Kalabsha kaolin, for adsorption of Zn(Ⅱ) ions from aqueous solution. The synthesis processes is performed under hydrothermal treatment in alkaline solutions. The obtained zeolite samples are characterized using X-ray diffraction, grain size distribution, surface area, and SEM. The critical molar ratios of both SiO2/Al2O3 and K2O/Na2O are about 2.9 and 0.16, respectively. Those ratios are needed to give individual low silica zeolite X in a minimum reaction time. The adsorption capacity of the synthesized products is determined by adsorption of Zn(Ⅱ) ions from solution. The results suggest that the zeolite obtained could be converted to a beneficial product, which will be used in future as an ion exchanger in removing heavy metals from wastewaters.     

Sorption and desorption behavior of residual antidepressants and caffeine in freshwater sediment and sewage sludge

The use of antidepressants is widespread in modern times. Thus, they present a potential risk for ecosystems due to occurrence in domestic sewage containing unaltered metabolites and structures, even after the treatment plants have processed the sewage. The current research investigated the sorption and desorption of antidepressants(citalopram, venlafaxine, fluoxetine, sertraline, and amitriptyline) and caffeine from freshwater sediment and sewage sludge. The samples of freshwater sediment were ...     

Urban forest loss using a GIS-based approach and instruments for integrated urban planning:A case study of Jo(a)o Pessoa,Brazil

Urban forests play an important role in the thermal comfort and overall life of local populations in large-and medium-sized cities.This study analyzes urban forest loss and maps land use and land cover (LULC) changes between 1991 and 2018 by evaluating the use of urban planning instruments for the mitigation of urban forest loss in Jo～o Pessoa,Brazil.For this purpose,satellite-derived LULC images from 1991,2006,2010 and 2018 and data on urban forest loss areas obtained using the Google Earth Engine were used.In addi-tion,this paper also discusses the instruments used for integrated urban planning,which are(a) the legal sector,responsibility and nature;(b) the urban expansion process;and (c) the elements of urban infrastructure.The results show a clear shift in land use in the study area.The major changes in LULC classes occurred in urban areas and herbaceous vegetation,while the greatest loss was in arboreal/shrub vegetation.Thus,an increase in the pressure to occupy zones intended for environmental preservation could be estimated.Our results showed similar accuracies with other studies and more spatial details.The characteristics of the patterns,traces,and hotspots of urban expansion and forest cover loss were explored.We highlighted the potential use of this proposed framework to be applied and validated in other parts of the world to help better understand and quantify various aspects of ur-ban-related problems such as urban forest loss mapping using instruments for integrated urban planning and low-cost approaches.     

Characterisation and multifaceted anisotropy assessment of Corvio sandstone for geological CO2 storage studies

We present a comprehensive characterisation of the physical, mineralogical, geomechanical, geophysical, and hydrodynamic properties of Corvio sandstone. This information, together with a detailed assessment of anisotropy, is needed to establish Corvio sandstone as a useful laboratory rock‐testing standard for well‐constrained studies of thermo–hydro–mechanical–chemical coupled phenomena associated with CO₂ storage practices and for geological reservoir studies in general. More than 200 core plugs of Corvio sandstone (38.1 and 50 mm diameters, 2:1 length‐to‐diameter ratio) were used in this characterisation study, with a rock porosity of 21.7 ± 1.2%, dry density 2036 ± 32 kg m^?3, and unconfined compressive and tensile strengths of 41 ± 3.28 and 2.3 ± 0.14 MPa, respectively. Geomechanical tests show that the rock behaves elastically between ～10 and ～18 MPa under unconfined conditions with associated Young's modulus and Poisson's ratio of 11.8 ± 2.8 GPa and 0.34 ± 0.01 GPa, respectively. Permeability abruptly decreases with confining pressure up to ～10 MPa and then stabilises at ～1 mD. Ultrasonic P‐ and S‐wave velocities vary from about 2.8–3.8 km s^?1 and 1.5–2.4 km s^?1, respectively, over confining and differential pressures between 0.1 and 35 MPa, allowing derivation of associated dynamic elastic moduli. Anisotropy was investigated using oriented core plugs for electrical resistivity, elastic wave velocity and attenuation, permeability, and tracer injection tests. Corvio sandstone shows weak transverse isotropy (symmetry axis normal to bedding) of <10% for velocity and <20% for attenuation.     

Role of time variant and invariant terms on soil moisture spatio-temporal variability in a subhumid coastal wetland

The knowledge of soil moisture spatio-temporal variability is highly relevant for water resources management. This paper reports an analysis of the spatial–temporal variability of soil moisture data for a small to medium-scale soil-sensors network in a coastal wetland of southwestern Spain. Measurements were taken from five sites located in the Doñana National Park over the time-period of one hydrological year from September 2017 to September 2018. The total area of the soil-sensors network shows an extension about 25 × 3 km. Soil moisture data was separated into time invariant (the temporal mean of the whole period at each site) and time-variant terms (the deviations of soil moisture from the mean, or anomalies). The time-invariant component was generally the main contributor to the total spatial variance of soil moisture and it was mostly controlled by the groundwater levels in the area. Nevertheless, the time variant terms have a huge effect on soil moisture variability in very dry states. Characteristic convex time-dependent patterns for this field site were found between spatially averaged soil moisture and its variability. This information could be used for the up and downscaling of soil moisture from satellite data. Those patterns of relation between spatial mean and variability of soil moisture were only affected by heavy rainfalls giving rise to hysteretic behaviour. This study shows that even though groundwater level is a time-variant variable, it significantly affects soil moisture's time-variant but also time-invariant terms due to the different average groundwater level depths at the different sites.