A Preliminary Survey of the Level of Microbiological Pollution of Major Rivers in Northern Greece

The objective of the present survey was to assess the microbiological quality of river waters used mainly to irrigate the large plains of Macedonia and Thessaly in Northern Greece. Five rivers (Aliakmonas, Axios, Loudias, Mavroneri and Pineios) were sampled during a 10‐month period (June 2002 – March 2003) for Total Microbial Flora (TMF) at 22 °C and 37 °C, Total Coliforms (TC), Fecal Coliforms (FC), enterococci, staphylococci, Pseudomonas, fungi, Giardia spp. and Cryptosporidium spp. The results indicate moderate to high microbiological pollution, with the highest levels of microbial pollution found in Mavroneri and Pineios Rivers, and moderate pollution levels in Aliakmonas, Axios and Loudias Rivers. The extent of microbiological pollution is accentuated by the fact that Giardia‐ and/or Cryptosporidium cysts were detected in nine out of eleven samples collected in June 2002 with excessive Giardia counts demonstrated for Pineios River. The microbiological pollution of the surveyed rivers is attributed to various degrees of human interference and to lack of ample pollution monitoring systems, which emphasize the need for implementation of the EU Water Framework Directive.     

Tephrostratigraphy and glass compositions of post-15 kyr Campi Flegrei eruptions: implications for eruption history and chronostratigraphic markers

Volcanic ash (tephra) erupted from the frequently active Campi Flegrei volcano forms layers in many palaeoenvironmental archives across Italy and the Mediterranean. Proximal deposits of 50 of the post-15 ka eruptions have been thoroughly sampled and analysed to produce a complete database of glass compositions (>1900 analyses) to aid identification of these units. The deposits of individual eruptions are compositionally diverse and this variability is often greater than that observed between different units. Many of the tephra units do not have a unique glass chemistry, with compositionally similar tephra often erupted over long periods of time (1000s years). Thus, glass chemistry alone is not enough to robustly correlate most of the tephra from Campi Flegrei, especially in the last 10 kyrs. In order to reliably correlate the eruption units it is important to take into account the stratigraphy, chronology, magnitude, and dispersal of the eruptions, which has been collated to aid identification. An updated chronology is also presented, which was constrained using Bayesian analysis (OxCal) of published radiocarbon dates and ⁴⁰Ar/³⁹Ar ages. All the data presented can be employed to help correlate post-15 ka tephra units preserved in archaeological and Holocene palaeoenvironmental archives. The new database of proximal glass compositions has been used to correlate proximal volcanic deposits through to distal tephra layers in the Lago di Monticchio record (Wulf et al., 2004, Wulf et al., 2008) and these correlations provide information on eruption stratigraphy and the tempo of volcanism at Campi Flegrei.     

Volcanic hazard assessment at the restless Campi Flegrei caldera

Eruption forecasting and hazard assessments at the restless Campi Flegrei caldera, within the Neapolitan volcanic area, have been performed using stratigraphical, volcanological, structural and petrological data.On the basis of the reconstructed variation of eruption magnitude through time, we hypothesize that the most probable maximum expected event is a medium-magnitude explosive eruption, fed by trachytic magma. Such an eruption could likely occur in the north-eastern sector of the caldera floor that is under a tensile stress regime, when the ongoing deformation will generate mechanical failure of the rocks. A vent could open also in the western sector, at the intersection of two fault systems contemporaneously activated, as happened in the last eruption at Monte Nuovo. The eruption could likely be preceded by precursors apparent to the population, such as ground deformation, seismicity and increase in gas emissions. It will probably alternate between magmatic and phreatomagmatic phases with the generation of tephra fallout, and dilute and turbulent pyroclastic currents. During and/or after the eruption, the re-mobilization of ash by likely heavy rains, could probably generate mud flows.In order to perform a zoning of the territory in relation to the expected volcanic hazards, we have constructed a comprehensive hazard map. On this map are delimited (I) areas of variable probability of opening of a new vent, (II) areas which could be affected by variable load of fallout deposits, and (III) areas over which pyroclastic currents could flow. The areas in which a vent could likely open have been defined on the basis of the dynamics of the ongoing deformation of the caldera floor. To construct the fallout hazard map we have used the frequency of deposition of fallout beds thicker than 10 cm, the frequency of load on the ground by tephra fallout and the direction of dispersal axes of the deposits of the last 5 ka, and the limit load of collapse for the variable types of roof construction. The pyroclastic-current hazard map is based on the areal distribution and frequency of pyroclastic-current deposits of the last 5 ka.Editorial Responsibility: T. Druitt     

Fractures and faults in volcanic rocks (Campi Flegrei,southern Italy): insight into volcano-tectonic processes

The present study was focused to analyze fractures and faults in the Campi Flegrei calderas presently hosting several volcanic edifices, such as lava domes, scoria, and tuff cones. A complex network of fractures and faults affects the volcanic rocks, mostly as planar with highly variable density. Frequently faults appearing as conjugate structures showing normal kinematics often associated with ductile deformation such as drag folds and deflexed layers, suggesting a syn-eruption deformation. However, the most of faults, mainly hosted along the caldera/crater rims, are very steep with dominant normal and secondary reverse movements. The fracture pattern indicates a slight prevalence of NE–SW and NW–SE directions, but N–S and E–W trends also occur. Fractures and faults found in rocks older than 15 ka (Neapolitan Yellow Tuff included), measured in western and eastern sectors of the study area, indicate a rotation of ca. 30° of the main directions among these two sectors. For the faults occurring along the caldera/crater rims, we suggest a kinematic evolution characterized by the reactivation of tensile fractures previously formed in response to both regional extension and locale resurgent dome. Finally, normal faults located in the central sector of caldera, between La Starza and Accademia localities, cutting the youngest volcanic deposits, indicate a constant NNE–SSW extension probably related to the caldera resurgence.     

Statistical analysis of textural data from complex pyroclastic sequences: implications for fragmentation processes of the Agnano-Monte Spina Tephra (4.1 ka), Phlegraean Fields, southern Italy

The Agnano-Monte Spina eruption (4.1 ka) generated pyroclastic deposits with complex internal stratigraphy that reflects variations in eruptive style. To obtain constraints on the fragmentation processes, we analysed grain-size and scanning electron microscopy (SEM) data by means of multivariate statistical techniques of the cluster and factor analysis types. The results allow the identification of end-member deposits related to either pure magmatic activity, or pure phreatomagmatic activity. In addition, some deposits show evidence of the contemporaneous operation of both end-member fragmentation modes. The presence of the two contrasting fragmentation processes during the various phases of explosive activity is tentatively interpreted to be a function in inhomogeneities in gas exsolution processes within the magma column that feeds the eruption.     

Tephra fallout hazard assessment at the Campi Flegrei caldera (Italy)

Tephra fallout associated with renewal of volcanism at the Campi Flegrei caldera is a serious threat to the Neapolitan area. In order to assess the hazards related with tephra loading, we have considered three different eruption scenarios representative of past activity: a high-magnitude event similar to the 4.1 ka Agnano-Monte Spina eruption, a medium-magnitude event, similar to the ∼3.8 ka Astroni 6 eruption, and a low-magnitude event similar to the Averno 2 eruption. The fallout deposits were reconstructed using the HAZMAP computational model, which is based on a semi-analytical solution of the two-dimensional advection–diffusion–sedimentation equation for volcanic tephra. The input parameters into the model, such as total erupted mass, eruption column height, and bulk grain-size and components distribution, were obtained by best-fitting field data. We carried out tens of thousands simulations using a statistical set of wind profiles, obtained from NOAA re-analysis. Probability maps, relative to the considered scenarios, were constructed for several tephra loads, such as 200, 300 and 400 kg/m². These provide a hazard assessment for roof collapses due to tephra loading that can be used for risk mitigation plans in the area.     

The Campanian Ignimbrite and Codola tephra layers: Two temporal/stratigraphic markers for the Early Upper Palaeolithic in southern Italy and eastern Europe

Tephra layers from archaeological sites in southern Italy and eastern Europe stratigraphically associated with cultural levels containing Early Upper Palaeolithic industry were analysed. The results confirm the occurrence of the Campanian Ignimbrite tephra (CI; ca. 40 cal ka BP) at Castelcivita Cave (southern Italy), Temnata Cave (Bulgaria) and in the Kostenki–Borshchevo area of the Russian Plain. This tephra, originated from the largest eruption of the Phlegrean Field caldera, represents the widest volcanic deposit and one of the most important temporal/stratigraphic markers of western Eurasia. At Paglicci Cave and lesser sites in the Apulia region we recognise a chemically and texturally different tephra, which lithologically, chronologically and chemically matches the physical and chemical characteristics of the Plinian eruption of Codola; a poorly known Late Pleistocene explosive event from the Neapolitan volcanoes, likely Somma–Vesuvius. For this latter, we propose a preliminary age estimate of ca. 33 cal ka BP and a correlation to the widespread C-10 marine tephra of the central Mediterranean. The stratigraphic position of both CI and Codola tephra layers at Castelcivita and Paglicci help date the first and the last documented appearance of Early Upper Palaeolithic industries of southern Italy to ca. 41–40 and 33 cal ka BP, respectively, or between two interstadial oscillations of the Monticchio pollen record – to which the CI and Codola tephras are physically correlated – corresponding to the Greenland interstadials 10–9 and 5. In eastern Europe, the stratigraphic and chronometric data seem to indicate an earlier appearance of the Early Upper Palaeolithic industries, which would predate of two millennia at least the overlying CI tephra. The tephrostratigraphic correlation indicates that in both regions the innovations connected with the so-called Early Upper Palaeolithic – encompassing subsistence strategy and stone tool technology – appeared and evolved during one of the most unstable climatic phases of the Last Glacial period. On this basis, the marked environmental unpredictability characterising this time-span is seen as a potential ecological factor involved in the cultural changes observed.