The Ca-Eskola component in eclogitic clinopyroxene as a function of pressure, temperature and bulk composition: an experimental study to 15 GPa with possible implications for the formation of oriented SiO2-inclusions in omphacite

Experiments have been conducted in the P-T range 2.5–15 GPa and 850–1,500°C using bulk compositions in the systems SiO₂–TiO₂–Al₂O₃–Fe₂O₃–FeO–MnO–MgO–CaO–Na₂O–K₂O–P₂O₅ and SiO₂–TiO₂–Al₂O₃–MgO–CaO–Na₂O to investigate the Ca-Eskola (CaEs Ca_0.5□_0.5AlSi₂O₆) content of clinopyroxene in eclogitic assemblages containing garnet + clinopyroxene + SiO₂ ± TiO₂ ± kyanite as a function of P, T, and bulk composition. The results show that CaEs_ss in clinopyroxene increases with increasing T and is strongly bulk composition dependent whereby high CaEs-contents are favoured by bulk compositions with high normative anorthite and low diopside contents. In this study, a maximum of 18 mol% CaEs_ss was found at 6 GPa and 1,350°C in a kyanite-eclogite assemblage garnet + clinopyroxene + kyanite + rutile + coesite. By comparison, no significant increase in CaEs_ss with increasing P could be observed. If the formation of oriented SiO₂-rods frequently observed in eclogititc clinopyroxenes is due to the retrogressive breakdown of a CaEs-component then these textures are a cooling rather than a decompression phenomenon and are most likely to be found in kyanite-bearing eclogites cooled from temperatures ≥750°C. The presence of clinopyroxene with approx. 4 mol% CaEs_ss in an experiment conducted at 2.5 GPa/850°C confirms earlier suggestions based on field data that vacancy-rich clinopyroxenes are not necessarily restricted to ultrahigh pressure metamorphic conditions. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Rescaling of Access and Property Relations in a Frontier Landscape: Insights from Jambi,Indonesia

The recent expansion of protected areas and oil palm plantations in Jambi (Sumatra), Indonesia, has been notably disruptive. This article investigates the scalar dimensions of land conflicts within a privately managed conservation area. We built on qualitative research focusing on struggles related to the formation of two informal settlements within the conservation area. Results indicate that, especially in the context of rapid rescaling (e.g., decentralization), new power constellations emerge, thereby altering preexisting property relations. We argue that competing scales of meaning and regulation are structuring the ability of actors to access land and, consequently, reflect tensions between structure and agency.     

The impact of uncertain emission trading markets on interactive resource planning processes and international emission trading experiments

Interactive resource planning is an increasingly important aspect of emission trading markets. The conferences of Rio de Janeiro, 1992, and Kyoto, 1997, originally focusing on environmental protection at both macro- and micro-economic levels, called for new economic instruments of this kind. An important economic tool in this area is Joint Implementation (JI), defined in Article 6 of the Kyoto Protocol. Sustainable development can be guaranteed only if JI is embedded in optimal energy management. In this contribution we describe and evaluate one international procedure within uncertain markets which helps to establish optimal energy management and interactive resource planning processes within uncertain emission trading markets.     

The dependence of the Fe2+-Mg cation-partitioning between olivine and basaltic liquid on pressure,temperature and composition

The equilibrium partitioning of Fe²⁺ and Mg between olivine and liquid along a liquid line of descent has been determined for a calc-alkaline system, ranging in composition from picritic to andesitic. Experiments were conducted between 1000–1450° C and 1 bar to 30 kbar. Within the compositional range investigated and , the compositional dependence of the Fe²⁺ and Mg partitioning is a function of the Mg-content of the liquid. The Mg-content of the liquid correlates strongly with temperature. The variation of the Fe²⁺ and Mg partitioning were therefore evaluated individualy as functions of composition and temperature alone. The composition dependence of the cation-partitioning coefficients (Kd) is given by the following two equations:

Halite and sylvite as solid inclusions in high-grade metamorphic rocks

Solid inclusions of halite and sylvite, formed during regional and contact metamorphism have been identified by microscopy and by electron microprobe analysis in rocks from Campolungo, Switzerland and Cornone di Blumone, Italy. The solid inclusions occur in several of the major minerals crystallized during metamorphism and have been observed as idiomorphic crystals and dendrites. The compositions measured in 100 analyses from Campolungo, Switzerland and 40 analyses from Cornone di Blumone, Italy extend across the two-phase region in the system, KCl-NaCl, indicating that the salt inclusions are high temperature precipitates. In both localities compositionally zoned and unzoned crystals have been found. Measured compositions on the temperature maximum of the two-phase region indicate at least 500° C which can be compared with 500°±20° C determined by Mercolli (1982) and Walther (1983) from the Mg content of calcites from Campolungo. The solid inclusions have been trapped apart from CO₂-rich and saline, H₂O-rich fluid inclusions which have been described by Mercolli (1982) as the earliest preserved fluid inclusions in the rocks. The early precipitation of salt minerals at Campolungo indicates that fluids were saturated with NaCl and KCl at 500° C and pressures of 2,000 bars or higher. Similar relationships exist between solid and fluid inclusions in the rocks of Cornone di Blumone which formed at temperatures as high as 800° C and pressures between 0.5 and 1 kilobar (Ulmer 1983). The entrapment of halite and sylvite as solid inclusions preserves the composition of the minerals which may therefore be useful as geothermometers.     

Intrinsic oxygen fugacities of diogenites and mesosiderite clasts

Oxygen fugacities of diogenite and mesosiderite clast material were measured with the double ZrO₂ cell technique between 800° and 1150°C. The samples were taken from large clasts in the diogenites Johnstown (En₇₃) and Tatahouine (En₇₅), and the mesosiderites Estherville (En₈₁), West Point (Fo₈₈) and Emery (En₆₈). Fugacity values for all except Emery plot near the wüstite-iron buffer curve and are interpreted as indicating similar source regions and environments of crystallization for the two suites. Emery orthopyroxene records a lower fugacity, close to the fayalite-quartz-iron buffer curve, probably as a result of equilibration with the mesosiderite matrix assemblage. The similarity of redox conditions experienced by mesosiderite orthopyroxenite and diogenites is not sufficient to require a single parent body and, if the common achondrites were derived from Vesta, mesosiderites probably came from a different body.     

Phase relations of a serpentine composition between 5 and 14 GPa: significance of clinohumite and phase E as water carriers into the transition zone

Run products from high pressure experiments at 800-1,200 °C and 5-14 GPa (corresponding to depths of 150 to 420 km) on a serpentine bulk composition [close to Mg₃Si₂O₅(OH)₄] were analysed by optical microscopy, micro-Raman spectroscopy and electron microprobe. All charges exhibit strong chemical zoning. Fluid, melt and hydrous solids were mostly concentrated at the top, bottom and along the wall of the capsules. The central part of the charge was devoid of H₂O. Both fluid and hydrous magnesian phases exhibit a Mg/Si ratio higher than forsterite. In contrast, the centre of the capsule was enriched in SiO₂. The observed zoning can neither be explained by gravitational settling nor by a thermal gradient alone. Most likely the fluid was separated from the solids by surface forces and thereby established the chemical gradient by preferentially dissolving MgO. If strong chemical zoning is taken into account, the occurrence of more phases than allowed by the phase rule can be explained by separating the bulk into several domains of different bulk compositions. Results indicate that small amounts of F increase the stability field of clinohumite, Mg₉Si₄O₁₆(OH,F)₂, compared to OH-clinohumite in pure MSH previously reported. Clinohumite coexists with enstatite up to 975 °C at 5 GPa, and up to 1,100 °C at 12 GPa. At 14 GPa (close to the !/#-Mg₂SiO₄ transition) phase E becomes the most important water carrier. The new results indicate that clinohumite could be an important mantle mineral for transporting water into the Earth's transition zone due to its high thermal stability compared to other important water carriers such as serpentine and phase A.     

The composition of liquids coexisting with dense hydrous magnesium silicates at 11-13.5 GPa and the endpoints of the solidi in the MgO-SiO2-H2O system

High-pressure liquids in the MgO-SiO₂-H₂O (MSH) system have been investigated at 11 and 13.5 GPa and between 1000 and 1350 °C. A bulk composition more magnesian than the tie-line forsterite-H₂O was employed for the study. Rocking multi-anvil experiments were combined with a diamond trap set-up. After termination of the experiments, the liquid trapped in the diamond layer was analysed by laser ablation ICP-MS using the ‘freezing’ technique. At 11 GPa, liquids coexist with one or two of phase A, clinohumite, chondrodite, and forsterite. A marked discontinuity in the evolution of liquid compositions near 1100 °C is observed at 11 GPa. A step of ∼13 wt% H₂O and 13 wt% MgO is interpreted to result from overstepping the fluid-saturated solidus reaction mass balanced to 1.00(18) phase A + 1.07(4) fluid = 0.63(15) chondrodite + 1.44(2) melt. At 13.5 GPa liquids coexist with one or two of hydrous wadsleyite, clinohumite, superhydrous B, phase B, and forsterite. The discontinuity in liquid composition is no longer present, indicating that the second critical endpoint of the solidus has been overstepped. Thus, hydrous melts in the Mg-rich part of the MSH system (molar bulk Mg/Si > 2) are chemically distinct from aqueous fluids at pressure up to 11 GPa. Convergence of fluid and melt compositions along the solidus resulting in a supercritical liquid occurs between 11 and 13.5 GPa, at which pressure the entire MSH system becomes supercritical.     

Armalcolite stability as a function of pressure and oxygen fugacity

The stability of synthetic armalcolite of composition (Fe_0.5Mg_0.5Ti₂O₅ was studied as a function of total pressure up to 15 kbar and 1200°C and also as a function of oxygen fugacity (?O₂) at 1200°C and 1 atm total pressure. The high pressure experiments were carried out in a piston-cylinder apparatus using silver-palladium containers. At 1200°C, armalcolite is stable as a single phase at 10 kbar. With increasing pressure, it breaks down ($\text{dT}\text{dP}\text{= 20°C/}\text{kbar}$), to rutile, a more magnesian armalcolite, and ilmenite solid solution. At 14 kbar, this three-phase assemblage gives way ($\text{dT}\text{dP}\text{= 30°C/}\text{kbar}$) to a two-phase assemblage of rutile plus ilmenite solid solution.A zirconian-armalcolite was synthesized and analyzed; 4 wt % ZrO₂ appears to saturate armalcolite at 1200°C and 1 atm. The breakdown of Zr-armalcolite occurs at pressures of 1–2 kbar less than those required for the breakdown of Zr-free armalcolite. The zirconium partitions approximately equally between rutile and ilmenite phases.The stability of armalcolite as a function of ?O₂ was determined thermogravimetrically at 1200°C and 1 atm by weighing sintered pellets in a controlled atmosphere furnace. Armalcolite, (Fe_0.5Mg_0.5)-Ti₂O₅, is stable over a range ?O₂ from about 10^?9.5to 10^?10.5 atm. Below this range to at least 10^?12.8 atm, ilmenite plus a reduced armalcolite are formed. These products were observed optically and by Mössbauer spectroscopy, and no metallic iron was detected; therefore, some of the titanium must have been reduced to Ti³⁺. This reduction may provide yet another mechanism to explain the common association of ilmenite rims around lunar armalcolites.