Trace element distributions in surficial sediments of the northern Tyrrhenian Sea: Contribution to heavy-metal pollution assessment

The trace element distributions in surficial sediment of Tyrrhenian Sea have been investigated as a part of a series of studies on the environmental quality of the area off the Tuscany coast (west-central Italy). This research has focused on the presence of possible contaminated zones; it also provides data for the identification and future monitoring and control of pollution sources. The study of numerous surface sediments and core samples has made it possible to distinguish between heavy-metal enrichments related to natural sources and other anomalies caused by anthropogenic contamination. Over much of the basin, the surface Pb, Cu, Zn, and As contents appear considerably enriched relative to those below 15 cm; among these metals, Pb shows the highest and most widespread enrichment. Only in the case of some coarse-grained sediments close to the mouth of Cecina River it is possible to relate anomalously high Zn contents to natural sources. In all other sampling stations, the enrichments of Pb, Cu, Zn, and As are ascribed to man's influence. The sediment distributions of Co, Cr, and Ni do not seem to be related to anthropogenic activities; rather they mirror influx of materials derived from sources of ophiolitic rock. The distribution of barium shows only two significant positive anomalies, and both are related to natural causes. Concentrations of vanadium are high in a zone close to an important smelting plant; these are thought to be of anthropogenic origin.     

Fall vs flow activity during the 1991 climactic eruption of Pinatubo Volcano (Philippines)

Six years after the 1991 Mt. Pinatubo eruption, deep erosion incisions into the pyroclastic deposits accumulated around the volcano enabled us to investigate the stratigraphy of the climactic deposits both in valley bottoms and on contiguous ridges. Stratigraphic relationships between fall, flow, and surge deposits in the Marella drainage system indicate that during the climactic eruption a progressive shift occurred from an early convective regime, to a transitional regime feeding both the plinian convective column and mostly dilute density currents, to a fully collapsing regime producing mostly dense pyroclastic flows. Syn-plinian dilute density currents (surges) propagated up to ~10 km from the crater, both along valley bottoms and on contiguous ridges of the Marella Valley, whereas post-plinian pyroclastic flows had greater runout (~13 km), were confined to valleys and were not associated with significant surges. Stratigraphic study and grain-size analyses allow the identification of three types of intra-plinian deposits: (a) lower and often coarse-grained surge deposits, emplaced during the accumulation of the coarsest portion of the fallout bed at time intervals of ~16-24 min; (b) upper fine-grained surge deposits, interstratified with the fine-grained portion of the fall bed and emplaced at shorter time intervals of ~3-13 min; and (c) small-volume, channel-confined, massive pumiceous flow deposits interbedded with the upper surges in the upper fine-grained fall bed. Maximum clast size isopleths of 1.6 and 0.8 cm for lithics (ML) and 2.0 and 4.0 cm for pumices (MP) show almost symmetrical distribution around the vent, indicating that the passing of the typhoon Yunya during the climactic eruption had little effect on trajectories of high-Reynold-number clasts. Significant distortion was, however, observed for the 3.2-cm ML and 6.0-cm MP proximal isopleths, whose patterns were probably influenced by the interaction of the clasts falling from column margins with the uprising co-ignimbrite ash plumes. Application of the Carey and Sparks (1986) model to the undisturbed isopleths generated by the umbrella cloud yields a maximum column height of ~42 km, in good agreement with satellite measurements. Systematic stratigraphic and vertical grain-size studies of the plinian fall deposit in the Marella Valley, combined with satellite data and eyewitness accounts, reveal that the carrying capacity of the convective column and related fallout activity peaked in the early phase of the eruption, beginning slightly before 13:41 and gradually declined until its cessation 3 h later. Most of the pumiceous pyroclastic flow deposits were emplaced after the end of the fallout activity at ~16:30 but before the summit caldera collapse at approximately 19:11. Only a small volume of pumiceous flow deposits accumulated after the final caldera collapse. In contrast to the previous reconstruction of Holasek et al. (1996), which interpreted the progressive lowering of the column, documented by satellite data, as due to a decreasing mass eruption rate, we suggest that a progressive shift from a plinian column to a large co-ignimbrite column could also account for such a variation.     

PCB and HCB in the sediments and waters of the Tiber estuary

The contamination by polychlorinated biphenyls (PCB) and hexachlorobenzene (HCB) in sea waters and sediments of Tiber River estuary has been studied in 1976 and 1977.PCBs have been detected in all the samples analysed at mean levels of 0.297 ppb (1976) and 0.135 ppb (1977); these levels are much higher than those proposed as acceptable for surface waters. Contamination increases with increasing distance from the shore.HCB has been identified in only 16% of the water samples analysed and it was found absent in sediment samples.The results are discussed relative to both the levels of PCB in other sea waters and the toxicity of these products to the aquatic animals.     

Use of SPOT 5 and IKONOS imagery for mapping biocenoses in a Tunisian Coastal Lagoon (Mediterranean Sea)

Mapping marine biocenoses is an efficient method for providing useful data for the management and conservation of Mediterranean lagoons. Fused images from two satellites, SPOT 5 and IKONOS, were tested as management tools for identifying specific ecosystems in the El Bibane lagoon, situated in southern Tunisia near the Libyan border. The objectives of this study were to provide a precise map of the entire El Bibane lagoon using fused images from SPOT 5 and to compare fused images from SPOT 5 and IKONOS over a test-area. After applying a supervised classification, pixels are automatically classified in four classes: low seagrass cover, high seagrass cover, superficial mobile sediments and deep mobile sediments. The maps of the lagoon revealed and confirmed an extremely wide distribution of seagrass meadows within the lagoon (essentially Cymodocea nodosa; 19 546 ha) and a large area of mobile sediments more or less parallel to the shore (3 697 ha). A direct comparison of overall accuracy between SPOT 5 over the entire area, SPOT 5 over the test-area and IKONOS over the test-area revealed that these tools provided accurate mapping of the lagoon environment (83.25%, 85.91% and 73.41% accuracy, respectively). The SPOT 5 images provided greater overall accuracy than the IKONOS image, but did not take into account the heterogeneous spatial structure of the seagrasses and sediments present in the lagoon environment. Although IKONOS imagery provided lower overall accuracy than SPOT 5, it proved a very useful tool for the mapping of heterogeneous structures as it enabled the patchiness of formations to be better taken into account. The use of SPOT 5 and IKONOS fused images appears to be very promising for completing the mapping of lagoons in other regions and countries of the Mediterranean Sea.     

A comparative analysis of three habitat suitability models for commercial yield estimation of Tapes philippinarum in a North Adriatic coastal lagoon (Sacca di Goro, Italy)

Habitat Suitability (HS) models have been extensively used by conservation planners to estimate the spatial distribution of threatened species and of species of commercial interest. In this work we compare three HS models for the estimation of commercial yield potential and the identification of suitable sites for Tapes philippinarum rearing in the Sacca di Goro lagoon (Italy) on the basis of six environmental factors. The habitat suitability index (HSI) is based on expert opinion while the habitat suitability conditional (HSC) is calibrated on observational data. The habitat suitability mixed (HSM) model is a two-part model combining expert knowledge and regression analysis: the first component of the model uses logistic regression to identify the areas in which clams are likely to be present; the second part applies the same parameter-specific suitability functions of the HSI model only in the areas previously identified as productive by the logistic component. The HS models were validated on an independent data set and estimates of potential yield of the Goro lagoon were compared. The effectiveness of the three approaches is then discussed in terms of predicted yield and identification of suitable sites for farming.     

Changes in extremes and hydroclimatic regimes in the CREMA ensemble projections

We analyze changes of four extreme hydroclimatic indices in the RCP8.5 projections of the Phase I CREMA experiment, which includes 21st century projections over 5 CORDEX domains (Africa, Central America, South America, South Asia, Mediterranean) with the ICTP regional model RegCM4 driven by three CMIP5 global models. The indices are: Heat Wave Day Index (HWD), Maximum Consecutive Dry Day index (CDD), fraction of precipitation above the 95th intensity percentile (R95) and Hydroclimatic Intensity index (HY-INT). Comparison with coarse (GPCP) and high (TRMM) resolution daily precipitation data for the present day conditions shows that the precipitation intensity distributions from the GCMs are close to the GPCP data, while the RegCM4 ones are closer to TRMM, illustrating the added value of the increased resolution of the regional model. All global and regional model simulations project predominant increases in HWD, CDD, R95 and HY-INT, implying a regime shift towards more intense, less frequent rain events and increasing risk of heat wave, drought and flood with global warming. However, the magnitudes of the changes are generally larger in the global than the regional models, likely because of the relatively low “climate sensitivity” of the RegCM4, especially when using the CLM land surface scheme. In addition, pronounced regional differences in the change signals are found. The data from these simulations are available for use in impact assessment studies.     

Development and validation of a regional coupled atmosphere lake model for the Caspian Sea Basin

We present a validation analysis of a regional climate model coupled to a distributed one dimensional (1D) lake model for the Caspian Sea Basin. Two model grid spacings are tested, 50 and 20 km, the simulation period is 1989–2008 and the lateral boundary conditions are from the ERA-Interim reanalysis of observations. The model is validated against atmospheric as well as lake variables. The model performance in reproducing precipitation and temperature mean seasonal climatology, seasonal cycles and interannual variability is generally good, with the model results being mostly within the observational uncertainty range. The model appears to overestimate cloudiness and underestimate surface radiation, although a large observational uncertainty is found in these variables. The 1D distributed lake model (run at each grid point of the lake area) reproduces the observed lake-average sea surface temperature (SST), although differences compared to observations are found in the spatial structure of the SST, most likely as a result of the absence of 3 dimensional lake water circulations. The evolution of lake ice cover and near surface wind over the lake area is also reproduced by the model reasonably well. Improvements resulting from the increase of resolution from 50 to 20 km are most significant in the lake model. Overall the performance of the coupled regional climate—1D lake model system appears to be of sufficient quality for application to climate change scenario simulations over the Caspian Sea Basin.     

Non-Gaussian distribution and clustering of hot and cold pixels in the five-year WMAP sky

We present measurements of the clustering of hot and cold patches in the microwave background sky as measured from the Wilkinson Microwave Anisotropy Probe 5-year data. These measurements are compared with theoretical predictions which assume that the cosmological signal obeys Gaussian statistics. We find significant differences from the simplest Gaussian-based prediction. However, the measurements are sensitive to the fact that the noise is spatially inhomogeneous (e.g. because different parts of the sky were observed for different lengths of time). We show how to account for this spatial inhomogeneity when making predictions. Differences from the Gaussian-based expectation remain even after this more careful accounting of the noise. In particular, we note that hot and cold pixels cluster differently within the same temperature thresholds at few-degree scales. While these findings may indicate primordial non-Gaussianity, we discuss other plausible explanations for these discrepancies. In addition, we find some deviations from Gaussianity at sub-degree scales, especially in the W band, whose origin may be associated with extragalactic dust emission.     

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.     

Nonlinear seismic behaviour of wall-frame dual systems accounting for soil–structure interaction

The aim of this paper is to study the effects of soil–structure interaction on the seismic response of coupled wall-frame structures on pile foundations designed according to modern seismic provisions. The analysis methodology based on the substructure method is recalled focusing on the modelling of pile group foundations. The nonlinear inertial interaction analysis is performed in the time domain by using a finite element model of the superstructure. Suitable lumped parameter models are implemented to reproduce the frequency-dependent compliance of the soil-foundation systems. The effects of soil–structure interaction are evaluated by considering a realistic case study consisting of a 6-storey 4-bay wall-frame structure founded on piles. Different two-layered soil deposits are investigated by varying the layer thicknesses and properties. Artificial earthquakes are employed to simulate the earthquake input. Comparisons of the results obtained considering compliant base and fixed base models are presented by addressing the effects of soil–structure interaction on displacements, base shears, and ductility demand. The evolution of dissipative mechanisms and the relevant redistribution of shear between the wall and the frame are investigated by considering earthquakes with increasing intensity. Effects on the foundations are also shown by pointing out the importance of both kinematic and inertial interaction. Finally, the response of the structure to some real near-fault records is studied. Copyright © 2012 John Wiley & Sons, Ltd.