Photoionization models of QSO's intervening absorption clouds

A new sufficiently compact code LINESPEC is described which is designed to determine the kinetic (collisional+photo) ionization equilibrium in a slab of a hot (T10⁴K) rarefied gas, and to simulate synthetic absorption-line spectra formed due to passing continuous radiation (from a quasar) through the slab. Eighty-six resonant absorption lines of ions and atoms of H, He, C, N, O, Ne, Mg, Al, Si, S, Ca, Fe are included with wavelengths in the range 9125000 Å. the behaviour and observability of various lines are analysed as a function of intensity of the ionizing radiation and kinetic plasma temperature (for a power-law spectrum of ionizing photons,N _ph (E) E ^– with =1.5;E is photon energy). For the purely collisional ionization (N _ph =0), the spectrum contains various combinations of absorption lines of hydrogen and/or of atoms and ions of other elements, the relative intensities of the lines being strongly temperaturedependent. If the ionizing radiation is intense enough, the L line dominates. In a wide parameter range L may be the only line visible in the UV spectral range.     

An X-ray absorption fine structure and nuclear magnetic resonance spectroscopy study of gallium-silica complexes in aqueous solution

The influence of aqueous silica on gallium(III) hydrolysis in dilute (2 × 10⁻⁴ ≤ m_Ga ≤ 5 × 10⁻³) and moderately concentrated (0.02 ≤ m_Ga ≤ 0.3) aqueous solutions was studied at ambient temperature, using high resolution X-ray absorption fine structure (XAFS) and nuclear magnetic resonance (NMR) spectroscopies, respectively. Results show that, in Si-free acidic solutions (pH < 3), Ga is hexa-coordinated with oxygens of H₂O molecules and/or OH groups in the first coordination sphere of the metal. With increasing pH, these hydroxyl groups are progressively replaced by bridging oxygens (-O-), and polymerized Ga-hydroxide complexes form via Ga-O-Ga chemical bonds. In the 2.5-3.5 pH range, both XAFS and NMR spectra are consistent with the dominant presence of the Ga₁₃ Keggin polycation, which has the same local structure as A1₁₃. Under basic pH (pH > 8), Ga exhibits a tetrahedral coordination, corresponding to Ga(OH)₄⁻ species, in agreement with previous NMR and potentiometric studies. Major changes in Ga hydrolysis have been detected in the presence of aqueous silica. Ga is tetra-coordinated, both in basic and acid (i.e., at pH > 2.7) Si-bearing solutions (0.01 ≤ m_Si ≤ 0.2), and forms stable gallium-silicate complexes. In these species, Ga binds via bridging oxygen to 2 ± 1 silicons, with an average Ga-Si distance of 3.16 ± 0.05 Å, and to 2 ± 1 silicons, with an average Ga-Si distance of 3.39 ± 0.03 Å. These two sets of Ga-Si distances imply the formation of two types of Ga-silicate aqueous complex, cyclic Ga-Si_2-3 species (formed by the substitution of Si in its tri-, tetra- or hexa-cyclic polymers by Ga atoms), and chainlike GaSi_2-4 species (similar to those found for A1), respectively. The increase in the number of Si neighbors (a measure of the complex concentration and stability), in alkaline media, with increasing SiO₂(aq) content and decreasing pH is similar to that for A1-Si complexes found in neutral to basic solutions. At very acid pH and moderate silica concentrations, the presence of another type of Ga-Si complex, in which Ga remains hexa-coordinated and binds to the silicon tetrahedra via the GaO₆ octahedron corners, has also been detected. These species are similar to those found for Al³⁺ in acid solutions. Thus, as for aluminum, silicic acid greatly hampers Ga hydrolysis and enhances Ga mobility in natural waters via the formation of gallium-silicate complexes.     

Iron (III)-silica interactions in aqueous solution: insights from X-ray absorption fine structure spectroscopy

The influence of aqueous silica on the hydrolysis of iron(III) nitrate and chloride salts in dilute aqueous solutions (m_Fe ∼ 0.01 mol/kg) was studied at ambient temperature using X-ray absorption fine structure (XAFS) spectroscopy at the Fe K-edge. Results show that in Si-free iron nitrate and chloride solutions at acid pH (pH < 2.5), Fe is hexa-coordinated with 6 oxygens of H₂O- and/or OH-groups in the first coordination sphere of the metal, at an Fe-O distance of 2.00 ± 0.01 Å. With increasing pH (2.7 < pH < 13), these groups are rapidly replaced by bridging hydroxyls (-OH-) or oxygens (-O-), and polymerized Fe hydroxide complexes form via Fe-(O/OH)-Fe bonds. In these polymers, the first atomic shell of iron represents a distorted octahedron with six O/OH groups and Fe-O distances ranging from 1.92 to 2.07 Å. The Fe octahedra are linked together by their edges (Fe-Fe distance 2.92-3.12 Å) and corners (Fe-Fe distance ∼3.47 ± 0.03 Å). The Fe-Fe coordination numbers (N_edge = 1-2; N_corner = 0.5-0.7) are consistent with the dominant presence of iron dimers, trimers and tetramers at pH 2.5 to 2.9, and of higher-polymerized species at pH > 3.At pH > 2.5 in the presence of aqueous silica, important changes in Fe(III) hydrolysis are detected. In 0.05-m Si solutions (pH ∼ 2.7-3.0), the corner linkages between Fe octahedra in the polymeric complexes disappear, and the Fe-Fe distances corresponding to the edge linkages slightly increase (Fe-Fe_edge ∼ 3.12-3.14 Å). The presence of 1 to 2 silicons at 3.18 ± 0.03 Å is detected in the second atomic shell around iron. At basic pH (∼12.7), similar structural changes are observed for the iron second shell. The Fe-Si and Fe-Fe distances and coordination numbers derived in this study are consistent with (1) Fe-Si complex stoichiometries Fe₂Si_1-2 and Fe₃Si_2-3 at pH < 3; (2) structures composed of Fe-Fe dimers and trimers sharing one or two edges of FeO₆-octahedra; and (3) silicon tetrahedra linked to two neighboring Fe octahedra via corners. At higher Si concentration (0.16 m, polymerized silica solution) and pH ∼ 3, the signal of the Fe second shell vanishes indicating the destruction of the Fe-Fe bonds and the formation of different Fe-Si linkages. Moreover, ∼20 mol.% of Fe is found to be tetrahedrally coordinated with oxygens in the first coordination shell (R_Fe-O = 1.84 Å). This new finding implies that Fe may partially substitute for Si in the tetrahedral network of the silica polymers in Si-rich solutions.The results of this study demonstrate that aqueous silica can significantly inhibit iron polymerization and solid-phase formation, and thus increase the stability and mobility of Fe(III) in natural waters. The silica “poisoning” of the free corner sites of iron-hydroxide colloids should reduce the adsorption and incorporation of trace elements by these colloids in Si-rich natural waters.     

Quality Appraisal of Surface Waters on Fennoscandian Territory

Widely applied bioindication methods are analyzed based on the survey data of 1980–1996 for over 400 lakes and 300 watercourses in the northeastern Fennoscandia known to experience anthropogenic impact (toxification, acidification, eutrophication, and thermofication). Representative results of hydrobiological analysis of the quality of surface waters in areas with mixed toxic pollution (or anthropogenic acidification) may be obtained if methods are applied, different from the bioindication methods that are now accepted as standard for Russia, along with methods of biotesting natural waters. The saprotoxibity index, Kola biotic index, acidification estimation scale, biotesting methods were developed and adapted to regional conditions.     

Concentrations of Chemical Elements in the Water and Suspended Matter of the Northern Dvina River and the Annual Gross Runoff to the White Sea

Doklady Earth Sciences - The results of four years of continuous investigations (from May 2015 through April 2019) of the elemental composition of the water of the Northern Dvina River are...     

Heat blanketing envelopes and thermal radiation of strongly magnetized neutron stars

Strong (B?10⁹ G) and superstrong (B?10¹⁴ G) magnetic fields profoundly affect many thermodynamic and kinetic characteristics of dense plasmas in neutron star envelopes. In particular, they produce strongly anisotropic thermal conductivity in the neutron star crust and modify the equation of state and radiative opacities in the atmosphere, which are major ingredients of the cooling theory and spectral atmosphere models. As a result, both the radiation spectrum and the thermal luminosity of a neutron star can be affected by the magnetic field. We briefly review these effects and demonstrate the influence of magnetic field strength on the thermal structure of an isolated neutron star, putting emphasis on the differences brought about by the superstrong fields and high temperatures of magnetars. For the latter objects, it is important to take proper account of a combined effect of the magnetic field on thermal conduction and neutrino emission at densities ρ?10¹⁰ g?cm^?3. We show that the neutrino emission puts a B-dependent upper limit on the effective surface temperature of a cooling neutron star.     

A Geoelectrical Model of the Southern Ladoga Region on the Basis of 3D Magnetotelluric Data Inversion

Izvestiya, Physics of the Solid Earth - Abstract—The paper presents results of magnetotelluric sounding performed in the South-Eastern Ladoga Region in 2018–2021 for the purpose of...