Time-dependent photoionization opacities in dense gamma-ray burst environments

The recent detection of a transient absorption feature in the X-ray prompt emission of GRB 990705 showed the importance of such observations in the understanding of gamma-ray bursts and their progenitors. We investigate the time dependence of photoionization edges during the prompt emission of bursts in different environments. We show that their variability can be used to infer the density and geometry of the surrounding medium, giving important clues to unveil the nature of the burst progenitor.     

Iron oxidation state in the Fe‐rich layer and silica matrix of Libyan Desert Glass: A high‐resolution XANES study

Abstract— Libyan Desert Glass (LDG) is an enigmatic type of glass that occurs in western Egypt in the Libyan Desert. Fairly convincing evidence exists to show that it formed by impact, although the source crater is currently unknown. Some rare samples present dark‐colored streaks with variable amounts of Fe, and they are supposed to contain a meteoritic component. We have studied the iron local environment in an LDG sample by means of Fe K‐edge highresolution X‐ray absorption near edge structure (XANES) spectroscopy to obtain quantitative data on the Fe oxidation state and coordination number in both the Fe‐poor matrix and Fe‐rich layers. The pre‐edge peak of the high‐resolution XANES spectra of the sample studied displays small but reproducible variations between Fe‐poor matrix and Fe‐rich layers, which is indicative of significant changes in the Fe oxidation state and coordination number. Comparison with previously obtained data for a very low‐Fe sample shows that, while iron is virtually all trivalent and in tetrahedral coordination (^[4]Fe³⁺) in the low‐Fe sample, the sample containing the Fe‐rich layers display a mixture of tetra‐coordinated trivalent iron (^[4]Fe³⁺) and penta‐coordinated divalent iron (^[5]Fe²⁺), with the Fe in the Fe‐rich layer being more reduced than the matrix. From these data, we conclude the following: a) the significant differences in the Fe oxidation state between LDG and tektites, together with the wide intra‐sample variations in the Fe‐oxidation state, confirm that LDG is an impact glass and not a tektite‐like glass; b) the higher Fe content, coupled with the more reduced state of the Fe, in the Fe‐rich layers suggests that some or most of the Fe in these layers may be directly derived from the meteoritic projectile and that it is not of terrestrial origin.     

The Agulhas Ridge, South Atlantic: The Peculiar Structure of a Fracture Zone

The Agulhas Ridge is a prominent topographic feature that parallels the Agulhas-Falkland Fracture Zone (AFFZ). Seismic reflection and wide angle/refraction data have led to the classification of this feature as a transverse ridge. Changes in spreading rate and direction associated with ridge jumps, combined with asymmetric spreading within the Agulhas Basin, modified the stress field across the fracture zone. Moreover, passing the Agulhas Ridge’s location between 80 and 69 Ma, the Bouvet and Shona Hotspots may have supplied excess material to this part of the AFFZ thus altering the ridge’s structure. The low crustal velocities and overthickened crust of the northern Agulhas Ridge segment indicate a possible continental affinity that suggests it may be formed by a small continental sliver, which was severed off the Maurice Ewing Bank during the opening of the South Atlantic. In early Oligocene times the Agulhas Ridge was tectono-magmatically reactivated, as documented by the presence of basement highs disturbing and disrupting the sedimentary column in the Cape Basin. We consider the Discovery Hotspot, which distributes plume material southwards across the AAFZ, as a source for the magmatic material.     

First results from the North Iceland experiment

Between June 2004 and September 2004 a temporary seismic network was installed on the northern insular shelf of Iceland and onshore in north Iceland. The seismic setup aimed at resolving the subsurface structure and, thus, the geodynamical transition from Icelandic crust to typical oceanic crust along Kolbeinsey Ridge. The experiment recorded about 1,000 earthquakes. The region encloses the Tjörnes Fracture Zone containing the Husavik–Flatey strike-slip fault and the extensional seismic Grimsey Lineament. Most of the seismicity occurs in swarms offshore. Preliminary results reveal typical mid-ocean crust north of Grimsey and a heterogeneous structure with major velocity anomalies along the seismic lineaments and north–south trending subsurface features. Complementary bathymetric mapping highlight numerous extrusion features along the Grimsey Lineament and Kolbeinsey Ridge. The seismic dataset promises to deliver new insights into the tectonic framework for earthquakes in an extensional transform zone along the global mid-ocean ridge system.     

Tying seismic data to geologic information from core data: an example from ODP Leg 177

The integration of seismic data with core data should provide ground-truth to a structural interpretation of seismic data. The main difficulty in such an integration effort is the correct translation of physical property measurements on cores to a form which can be used in seismostratigraphic interpretation. In the absence of down-hole well data and check-shots, required knowledge of the velocity structure at the drilling locations can be obtained directly from measurements of the physical properties of core samples. This involves upscaling of the data from physical properties of cores to the sample interval used in the seismic data. In the present study, three of the seven drill-sites of ODP (Ocean Drilling Program) Leg 177 in 1997/1998, located on the Agulhas Ridge in the south-eastern Atlantic (sites 1088–1090), were connected with eight seismic profiles. Physical properties data measured on the cores from the various holes at each site were combined to create a single continuous log and used to construct synthetic seismograms. The synthetics generally show a good agreement with real seismic data in terms of amplitude and waveform. Some reflections in these generated traces may have a time-shift due to sections with incomplete or spurious P-wave velocity measurements in the ODP datasets. The main reflectors identified in the real seismic data correspond to hiatuses or periods of reduced sedimentation rates, and correlate well with density variations. One particular hiatus, clearly observable in the real seismic data, was not unequivocally identifiable in the various types of core data, and tying core data to seismic data can confirm its existence in the core data, showing the benefit of including seismic data in an interpretation of core log data. On the other hand, core data provide a calibration tool for the geological timescale of seismic data and information about the lithology, needed in the interpretation of seismic data.     

A seismic reconnaissance survey of the northern Congo Fan

To study the time-varying influence of the Congo River and the Benguela Current on the deposition at the Angola Continental Margin, a high-resolution reflection seismic survey was carried out on the northern Congo Fan. Four seismostratigraphic units have been defined for the upper 800 m (1000 ms TWT) of the data. The units record different depositional environments, ranging from pre-establishment of the Congo River drainage system to the influence of the Benguela Current. An indication of a general change in the turbidite system is provided by a shift in channel distribution and a relocation of the depocentre of coarse material. The ascent of salt is recorded up to the Pliocene. Gas that has migrated out of Lower Cretaceous shales and that was produced from large quantities of organic matter in the younger sediments can be found on the flanks and on top of the salt domes. In a few places, this gas even ascends to the ocean floor along structural pathways through the topmost unit.     

Biomarkers of Exposure and Effects for Assessing Toxicological Risk of Endocrine Disrupters in Top Predators of the Mediterranean Sea

Abstract. Endocrine Disrupting Chemicals (EDCs) have the potential to alter hormone pathways that regulate reproductive processes in wildlife and fisheries. In this research the unexplored hypothesis that Mediterranean top predator species (such as large pelagic fish and marine mammals) are potentially at risk due to EDCs is investigated. In the Mediterranean environment, top predators accumulate high concentrations of polyhalogenated aromatic hydrocarbons (PHAHs) and toxic metals, incurring high toxicological risk. Here we illustrate the need to develop sensitive biomarkers for evaluation of toxicological risk in top marine predators (Xiphias gladius, Thunnus thynnus thynnus) and non-lethal techniques, such as non-destructive biomarkers, for the hazard assessment of threatened species exposed to EDCs, such as marine mammals ( Stenella coeruleoalba, Tursiops truncatus, Delphinus delphis and Balaenoptera physalus ).     

Coalification in Carboniferous sediments from the Lötschberg base tunnel

Vitrinite reflectance (Rr), proximate analysis and carbon isotope composition (δ¹³C) have been used to characterise coal samples from two zones of Late Carboniferous sediments (Gastern and Ferden) in the Aar massif where they are penetrated by the Lötschberg base tunnel (constructed between 1999 and 2005). Samples are characterised by variable ash yields (21.7–93.9%; dry basis); those with ash yields of less than ~50% and with volatile matter content (V;dry ash-free basis) within the limits 2 < V% ≤ 8 are anthracite. Values of Rr range from 3.89% to 5.17% and indicate coalification to the rank of anthracite and meta-anthracite in both Gastern and Ferden Carboniferous zones. Samples of anthracite and shale from the Gastern Carboniferous exhibit a relatively small range in δ¹³C values (–24.52‰ to –23.38‰; mean: –23.86‰) and are lighter than anthracite samples from the Ferden Carboniferous (mean: –22.20‰). The degree of coalification in the Gastern and Ferden Carboniferous zones primarily depends on the maximum rock temperature (T) attained as a result of burial heating. Vitrinite reflectance based estimates of T range from ~290° –360 °C. For a proposed palaeogeothemal gradient of 25 ° C/km at the time of maximum coalification the required overburden is attributable to relatively thin autochtonous Mesozoic/Cenozoic sedimentary cover of the Aar massif and Gastern granite and deep tectonic burial beneath advancing Helvetic, Ultrahelvetic and Prealpine (Penninic) nappes in Early Oligocene to Miocene.     

Dissolved silica budget in the North basin of Lake Lugano

We studied the dissolved silica cycle in the water column of the North basin of Lake Lugano, Switzerland/Italy. Lake Lugano is a meromictic, eutrophic lake, permanently stratified below 100-m depth. A one-box model was used to calculate a silica mass-balance over 1993, based on various lake measurements, such as sediment traps, sediment cores, water analysis and biota countings. We found that the North basin of Lake Lugano is at steady state as far as dissolved silica is concerned. The primary source of dissolved silica in the lake is river input (about 80%), with diffusion from bottom sediments and groundwater input also playing a role. Atmospheric input is negligible. The main export of dissolved silica occurs via biogenic uptake by diatoms and final burial of their frustules in the bottom sediment. Loss of dissolved silica through the lake outflow only represents 15% of the total output. Of the total amount of Si exported to the lake bottom through diatom sinking, less than 20% is re-supplied to the surface water by diffusion. Thus, the lake acts as an important permanent sink for silica. The long residence time of dissolved silica in the lake (7 years) is related to the strong physical stratification of the lake. Only about 10% of the standing stock are available to phytoplankton uptake.