Phase Relations and Melting of Anhydrous K-bearing Eclogite from 1200 to 1600{degrees}C and 3 to 5 GPa

To investigate eclogite melting under mantle conditions, wehave performed a series of piston-cylinder experiments usinga homogeneous synthetic starting material (GA2) that is representativeof altered mid-ocean ridge basalt. Experiments were conductedat pressures of 3·0, 4·0 and 5·0 GPa andover a temperature range of 1200–1600°C. The subsolidusmineralogy of GA2 consists of garnet and clinopyroxene withminor quartz–coesite, rutile and feldspar. Solidus temperaturesare located at 1230°C at 3·0 GPa and 1300°C at5·0 GPa, giving a steep solidus slope of 30–40°C/GPa.Melting intervals are in excess of 200°C and increase withpressure up to 5·0 GPa. At 3·0 GPa feldspar, rutileand quartz are residual phases up to 40°C above the solidus,whereas at higher pressures feldspar and rutile are rapidlymelted out above the solidus. Garnet and clinopyroxene are theonly residual phases once melt fractions exceed 20% and garnetis the sole liquidus phase over the investigated pressure range.With increasing melt fraction garnet and clinopyroxene becomeprogressively more Mg-rich, whereas coexisting melts vary fromK-rich dacites at low degrees of melting to basaltic andesitesat high melt fractions. Increasing pressure tends to increasethe jadeite and Ca-eskolaite components in clinopyroxene andenhance the modal proportion of garnet at low melt fractions,which effects a marked reduction in the Al₂O₃ and Na₂O contentof the melt with pressure. In contrast, the TiO₂ and K₂O contentsof the low-degree melts increase with increasing pressure; thusNa₂O and K₂O behave in a contrasted manner as a function ofpressure. Altered oceanic basalt is an important component ofcrust returned to the mantle via plate subduction, so GA2 maybe representative of one of many different mafic lithologiespresent in the upper mantle. During upwelling of heterogeneousmantle domains, these mafic rock-types may undergo extensivemelting at great depths, because of their low solidus temperaturescompared with mantle peridotite. Melt batches may be highlyvariable in composition depending on the composition and degreeof melting of the source, the depth of melting, and the degreeof magma mixing. Some of the eclogite-derived melts may alsoreact with and refertilize surrounding peridotite, which itselfmay partially melt with further upwelling. Such complex magma-genesisconditions may partly explain the wide spectrum of primitivemagma compositions found within oceanic basalt suites. KEY WORDS: eclogite; experimental petrology; mafic magmatism; mantle melting; oceanic basalts     

Chlorinated hydrocarbons and hatching success in Baltic herring spring spawners

Eggs from 69 females of spring spawning herring from the German Baltic coast (Travemünde, April 1979) were incubated in clean sea water (20‰ S, temperature 8°C) under standard conditions. Sixty-one trials could be used for the evaluation of hatching success. Viable hatch was taken as a measure to evaluate the effects of chlorinated hydrocarbons accumulated in gonads, liver and muscle of parental fish.PCB levels in running ripe females ranged on a wet weight basis between 19 and 241 ng g^?1 (gonad), 20 and 377 ng g^?1 (liver) and 11 and 1820 ng g^?1 (muscle). Concentrations of other chlorinated hydrocarbons (DDD, DDE, γ-HCH, etc.) were in the same range as reported by other authors for Baltic herring (Huschenbeth, 1973, 1977). Viable hatch was significantly affected at ovary DDE concentrations higher than 18 ng g^?1 (wet wt) and PCB concentrations of more than 120 ng g^?1 (wet wt).Results are compared with data obtained during earlier investigations with flounder eggs.     

Methodology of Environmental Standardization for Natural Waters

Doklady Earth Sciences - This paper discusses sources of significant errors that occur in the course of determination of the primary environmental standard for natural waters: the maximum...     

Nonlinear Effects in the Formation of Water Quality

Doklady Earth Sciences - The indicators of the composition and quality of natural water are random variables. Since the “linear” approach to their assessment and forecast provides no...     

A 1600-year history of the Labrador Current off Nova Scotia

A multicore from Emerald Basin, on the continental margin off Nova Scotia, has a modern ¹⁴C age at the top, and other ¹⁴C dates indicate a linear sedimentation rate of ~30 cm/ka to 1600 calendar years BP. This rate is great enough to record century-to-millennial scale changes in the surface and deep (~250 m) waters in the basin that are influenced by the Labrador Current. We applied five proxies for seawater temperature changes to the sediments of Emerald Basin, including the percent abundance and the oxygen isotope ratio (d ¹⁸O) of the polar planktonic foraminifer N. pachyderma (s.), the unsaturation ratio of alkenones (U ^k' ₃₇) produced by prymnesiophyte phytoplankton, and the d ¹⁸O and Mg/Ca of benthic foraminifera. All five proxies indicate the ocean warmed suddenly sometime in the past 150 years or so. The exact timing of this event is uncertain because ¹⁴C dating is inaccurate in recent centuries, but this abrupt warming probably correlates with widespread evidence for warming in the Arctic in the nineteenth century. Because the Canadian Archipelago is one of the two main sources for the Labrador Current, warming and melting of ice caps in that region may have affected Labrador Current properties. Before this recent warming, sea surface temperature was continually lower by 1–2 °C, and bottom water was colder by about 6 °C in Emerald Basin. These results suggest that there was no Medieval Warm Period in the coastal waters off Nova Scotia. Because there is also no evidence of medieval warming in the Canadian archipelago, it seems likely that coastal waters from Baffin Bay to at least as far south as Nova Scotia were continually cold for ~1500 of the past 1600 years.     

Reconstruction of natural groundwater flow paths in the multiple aquifer system of the northern Negev (Israel), based on lithological and structural evidence

 The Judea Group, a limestone and dolomite karstic aquifer of late Albian–Turonian age, is one of the most important sources of water in Israel. In the western part of the country, the Judea Group aquifer is also known as the Yarkon–Taninim basin. In the northern Negev, the Judea Group is a recipient for fresh water flowing southward from the Hebron Mountains and of brackish paleowater flowing northward from Sinai. Very little is known of the hydraulic properties of this aquifer. In order to outline assumed natural flow paths that existed in this karstic environment prior to groundwater exploitation, use was made of lithological, structural, and paleomorphological features. A detailed hydrogeological conceptual model of the Judea Group aquifer in northern Negev was established by the geological interpretation of high-resolution seismic reflection and by analysis of lithological evidence from boreholes. Isopach, isolith-contour, and isolith-ratio maps were compiled for the main lithological components. Increase in transmissivity values is inversely proportional with the cumulative thickness of argillaceous components. The lithological and hydraulic evidence provides the basis for subdividing the subsurface into distinctive permeability zones for the upper and lower sections of the aquifer; for outlining possible preferential groundwater flow paths for both subaquifers; and for improving understanding of groundwater-salinty variations that result from lithological variability, direction of groundwater flow paths, groundwater flow rates, and the duration of rock/water interactions. In an earlier conceptual model of the basin, the Judea Group aquifer was regarded as a continuous and undisturbed entity. The present study reveals an intricate groundwater flow pattern that is controlled by lithological and structural factors that create zones of preferential flow. This interpretation bears on the overall evaluation of groundwater resources and their management and exploitation. Received, December 1996 · Revised, October 1997, June 1998 · Accepted, July 1998     

Testing GISS-MM5 physics configurations for use in regional impacts studies

The Mesoscale Modeling System Version 5 (MM5) was one-way nested to the Goddard Institute for Space Studies global climate model (GISS GCM), which provided the boundary conditions for present (1990s) and future (IPCC SRES A2 scenario, 2050s) five-summer “time-slice” simulations over the continental and eastern United States. Five configurations for planetary boundary layer, cumulus parameterization, and radiation scheme were tested, and one set was selected for use in the New York City Climate and Health Project—a multi-disciplinary study investigating the effects of climate change and land-use change on human health in the New York metropolitan region. Although hourly and daily data were used in the health project, in this paper we focus on long-term current and projected mean climate change. The GISS-MM5 was very sensitive to the choice of cumulus parameterization and planetary boundary layer scheme, leading to significantly different temperature and precipitation outcomes for the 1990s. These differences can be linked to precipitation type (convective vs. non-convective), to their effect on solar radiation received at the ground, and ultimately to surface temperature. The projected changes in climate (2050s minus 1990s) were not as sensitive to choice of model physics combination. The range of the projected surface temperature changes at a given grid point among the model versions was much less than the mean change for all five model configurations, indicating relative consensus for simulating surface temperature changes among the different model projections. The MM5 versions, however, offer less consensus regarding 1990s to 2050s changes in precipitation amounts. All of the projected 2050s temperature changes were found to be significant at the 95th percent confidence interval, while the majority of the precipitation changes were not.     

Limiting hydrochemical factors for sustainability of water resources: The Cisjordanian experience

In Cisjordan, surface- and groundwater flow are either towards the Jordan Valley-Dead Sea-Arava Valley (the Rift) or the Mediterranean Sea. Due to upstream exploitation by riparians to the Jordan River, the historical annual flow, which fluctuated between 250 and 1100 Mm³, has declined to a mere 100-200 Mm³. The remaining flow south of Lake Kinneret is highly polluted and heavily loaded with salts. Lake Kinneret (Sea of Galilee) is one of the major water resources in the area. Annually, between 200 and 700 Mm³ reach the Lake as surface and groundwater flow. The relatively high salinity of the Lake is caused by thermomineral water discharging from springs and seepages located onshore and on the bottom of the Lake. The main factors causing deterioration of the groundwater quality in the Rift are of geogenic character. These are different types of brines, whose outflow and penetration into freshwater aquifers was triggered by overpumpage. Contemporary encroachment of seawater caused by intensive water exploitation in the Coastal Plain is manageable and reversible. However, due to lack of hydrogeological evidence, no such statement can be made about the circulation of seawater beneath the Coastal Plain and into the deep-seated Yarkon-Taninim aquifer or the upflow of brines in the Rift.The flow regimes of the different brine bodies could not be elucidated. Whether each such brine-body flows by its particular hydrological regime or whether the movement of the different bodies is intradependent or interdependent with the regional movement of fresh groundwater, remain open questions. Therefore, sustainable development of groundwater resources is clearly dependent on the elucidation of the relationship between changes in the pressure of the brine with depth and its relationship to the overlying freshwater.The average total annual recharge of all water sources in Cisjordan is 1820 Mm³, which means that the total production of water must be managed within the limits of this annual volume. During drought years, total groundwater extraction exceeds the safe yield, causing drastic lowering of water levels and upflow of saline waters from greater depths.Because of the structural complexity of aquifers and hydrochemical variability of the numerous groundwater bodies, new hydrochemical methods have been developed for the identification of groundwater bodies and for the elucidation of their origins. These methods combine macrochemical, microchemical, and isotopic evidences. By combining distribution patterns of rare earths, yttrium and stable isotopes, a complete picture of catchment lithology and the altitude and latitude of precipitation could be obtained.The area west of the Jordan River is characterized by the occurrence of transboundary surface- and groundwater basins in which fresh and saline water and brines flow across political borders between Israel and the Palestinian Authority. It is very difficult to assess separately the annual safe yield of water resources for each of the two national entities. Neither country may dispose independently of its waters and is usually at the mercy of the other riparian. There is as yet no general multilateral international treaty in force allocating the water resources of international watercourses. At present there are two rules for the management of the waters of an international drainage basin—the rule of Equitable Distribution, and the obligation Not to Cause Significant Harm. The rules of equitable distribution have tended to focus on the issue of quantities of water rather than on quality of water, which is really relevant to the issue of equitable distribution. Future negotiations on the uses of the basin will need to deal with issues of characteristic salinities and geochemical features and on their impact on equitable sharing of water resources.