A case study of atmospheric boundary layer features during winter over a tropical inland station — Kharagpur (22.32°N, 87.32°E)

The local weather and air quality over a region are greatly influenced by the atmospheric boundary layer (ABL) structure and dynamics. ABL characteristics were measured using a tethered balloon-sonde system over Kharagpur (22.32°N, 87.32°E, 40m above MSL), India, for the period 7 December 2004 to 30 December 2004, as a part of the Indian Space Research Organization-Geosphere Biosphere Program (ISRO-GBP) Aerosol Land Campaign II. High-resolution data of pressure, temperature, humidity, wind speed and wind direction were archived along with surface layer measurements using an automatic weather station. This paper presents the features of ABL, like ABL depth and nocturnal boundary layer (NBL) depth. The sea surface winds from Quikscat over the oceanic regions near the experiment site were analyzed along with the NCEP/NCAR reanalysis winds over Kharagpur to estimate the convergence of wind, moisture and vorticity to understand the observed variations in wind speed and relative humidity, and also the increased aerosol concentrations. The variation of ventilation coefficient (V C), a factor determining the air pollution potential over a region, is also discussed in detail.     

Understanding the Past and Present and Predicting the Future: Farmers’ Use of Multiple Nutrient Best Management Practices in the Upper Midwest

Understanding what drives farmers’ voluntary adoption of nutrient and soil best management practices has important consequences for many environmental outcomes including water quality. We build on research revealing the need for simultaneous use of multiple nitrogen best management practices to achieve water quality improvement goals. Using social, economic and attitudinal variables we predict the use of multiple nitrogen best management practices at three time points: current use (2013), past use (before 2013), and likelihood of use on their largest field in the next three years. Our empirical analysis uses structural equation modeling with latent variables and 2014 farmer survey data from three Midwestern US states. Most farmers in our sample used at least one of the six best management practices. Our results reveal that farmers’ attitudes, use of information sources, and conservation program participation affect the number of nitrogen best management practices concurrently in use at multiple time points.     

An empirical analysis of the impact of a bus rapid transit system on the concentration of secondary pollutants in the roadside areas of the TransJakarta corridors

A bus rapid transit (BRT) system began operation in Jakarta City, Indonesia, in January 2004 and led to a modal shift from private to public modes of transport. This modal shift from car and motorcycle to BRT reduced the emission intensity of primary pollutants, such as NO_x and CO. We applied a combined structural equation model and an artificial neural network to evaluate the impact of the BRT system on the concentration of secondary pollutants in the roadside areas in the BRT corridors. An empirical analysis was carried out using data collected at five continuous ambient air quality monitoring stations located near to the BRT TransJakarta corridors in 2005. The establishment of our structural equation model gives a better understanding of the cause–effect relationship among the factors influencing roadside ambient air pollution, and was useful in simplifying the complexity of our artificial neural network model for predicting the modal shift’s impact on the PM₁₀ values and concentration of O₃. The introduction of the BRT system, and the modal shift it produced, had a greater influence on rapidly decaying pollutants, such as PM₁₀, than on O₃ because of the exposure to near-source microenvironments, such as the roadside of the TransJakarta corridors.     

Secondary Ion Mass Spectrometry Bias on Isotope Ratios in Dolomite–Ankerite,Part II: δ13C Matrix Effects

This study is Part II of a series that documents the development of a suite of calibration reference materials for in situ SIMS analysis of stable isotope ratios in Ca‐Mg‐Fe carbonates. Part I explored the effects of Fe²⁺ substitution on SIMS δ¹⁸O bias measured from the dolomite–ankerite solid solution series [CaMg(CO₃)₂–CaFe(CO₃)₂], whereas this complementary work explores the compositional dependence of SIMS δ¹³C bias (calibrated range: Fe# = 0.004–0.789, where Fe# = molar Fe/(Mg+Fe)). Under routine operating conditions for carbonate δ¹³C analysis at WiscSIMS (CAMECA IMS 1280), the magnitude of instrumental bias increased exponentially by 2.5–5.5‰ (session‐specific) with increasing Fe‐content in the dolomite structure, but appeared insensitive to minor Mn substitution [< 2.6 mole % Mn/(Ca+Mg+Fe+Mn)]. The compositional dependence of bias (i.e., the matrix effect) was expressed using the Hill equation, yielding calibration residual values ≤ 0.3‰ relative to CRM NBS‐19 for eleven carbonate reference materials (6‐μm‐diameter spot size measurements). Based on the spot‐to‐spot repeatability of a drift monitor material that ‘bracketed’ each set of ten sample‐spot analyses, the analytical precision was ± 0.6–1.2‰ (2s, standard deviations). The analytical uncertainty for individual sample analyses was approximated by combining the precision and calibration residual values (propagated in quadrature), suggesting an uncertainty of ± 1.0–1.5‰ (2s).     

Pervasive assimilation of carbonate and silicate rocks in the Hortavær igneous complex, north-central Norway

The intrusive complex at Hortavær represents a magma transfer zone in which multiple pulses of gabbroic and dioritic magmas evolved along Fe- and alkali-enrichment trends. Extreme alkali enrichment resulted in nepheline-normative and sparse nepheline-bearing monzodioritic and monzonitic rocks. More evolved monzonitic and syenitic rocks are silica saturated and, in some cases, quartz bearing. Previous and current research recognized an abundance of clinopyroxene and other Ca-rich phases, such as scapolite, grossular-rich garnet, and igneous-textured calcite among the mafic and intermediate rocks. Even the most pyroxene-rich samples contain low Sc concentrations, which suggests early, intense fractionation of clinopyroxene. These features and the alkali enrichment are consistent with assimilation of carbonate-rich host rocks. Carbon isotope ratios of the igneous-textured calcite indicate an origin of the carbon from host rocks rich in calcite, consistent with assimilation. However, low _Nd values (−3.4 to −10.2) and moderate initial ⁸⁷Sr/⁸⁶Sr values (0.7052 to 0.7099) indicate the need for assimilation of quartzofeldspathic rocks as well. Models of combined assimilation and fractional crystallization indicate that assimilation of simple end members, either carbonate or silicate, cannot explain the entire data set. Instead, variable proportions of carbonate and silicate materials were assimilated, with the most pronounced assimilation effects in the mafic rocks. The reasons for variable degrees of assimilation are, as yet, uncertain. It is possible that assimilation of calc-silicate rocks with variable carbonate/silicate proportions resulted in the range of observed compositions. However, the importance of carbonate assimilation in mafic rocks compared to felsic ones suggests that assimilation of carbonates was predominant at high temperature and/or mafic magma compositions and assimilation of silicates was predominant at lower temperature and/or felsic magma compositions. We suggest that the ability of the mafic magma to dissolve higher proportions of carbonate contaminants is the result of the magma's ability to form clinopyroxene as a product of assimilation. In any case, extensive carbonate assimilation was possible because CO₂ escaped from the system.     

Identification of groundwater potential zones within an area with various geomorphological units by using several field parameters and a GIS approach in Kulon Progo Regency, Java, Indonesia

A case study was conducted to find the groundwater potential zones in an area between the Serang and Bogowonto rivers, Kulon Progo Regency, Java, Indonesia. The objectives of this study were to delineate the groundwater potential zone based on a number of groundwater parameters that can be surveyed in the field and to incorporate the geomorphological conditions into these data. The geomorphology interpretation was conducted using the landform approach. This approach begins by preparing supporting data such as an Indonesian Topographic Map containing contour and land use data; a regional geology map containing lithology type and geology structures; and soil, climate, and hydrological data. The determination of the geomorphology unit was conducted manually by the visual interpretation of Digital Landsat ETM⁺ with some image interpretation keys. Four groundwater parameters were surveyed in the field: (a) depth to the water table, (b) water table fluctuation, (c) fluid electrical conductivity to represent groundwater quality, and (d) aquifer thickness. The groundwater potential zones were obtained by overlaying all the groundwater field parameters in terms of weighted overlay methods using the spatial analysis tool in ArcGIS 9.2. During the weighted overlay analysis, rankings were produced for each individual parameter of each groundwater field parameter, and weights were assigned based on the amount of influence they had (i.e., depth to the water table—30 %, water table fluctuation—20 %, aquifer thickness—30 %, and fluid conductivity—20 %). We then found the good, moderate, and poor zones in terms of groundwater potential, which had areas of 5.83, 4.53, and 2.36 km², respectively. Areas with good groundwater potential are located largely within sand dunes, beach ridges, beaches, and fluviomarine plain landforms, which are characterized by a shallow water table, low fluctuation, thick aquifer, and low EC value. Moderate groundwater zones are generally characterized by poor water quality (high EC value), which is found to some degree in the alluvial plain. The regions with poor groundwater potential are spread mainly across the landforms composed of igneous rock (thin aquifers), such as denudational hills, which act as run-off zones due to their steep slope.     

Microphysics and Optical Attenuation in Fog: Observations from Two Coastal Sites

Boundary-Layer Meteorology - A total of 15 fog events from two field campaigns are investigated: the High Energy Laser in Fog (HELFOG) project (central California) and the Toward Improving Coastal...     

Wet season hydrochemistry of Bribin Cave in Gunung Sewu Karst, Indonesia

This research was conducted on the Bribin River, the most important underground river in the Gunung Sewu Karst, Gunung Kidul, Java, Indonesia. The main purpose of this study was to define the wet-season hydrochemistry of this river. This research also focuses on identifying the relationship between hydrochemical parameters to provide better aquifer characterization. Water-level monitoring and discharge measurements were conducted over a 1-year period to define the discharge hydrograph. Furthermore, baseflow-separation analysis is conducted to determine the diffuse-flow percentage throughout the year. Water sampling for hydrogeochemical analysis is taken every month in the wet season and every 2?hours for two selected flood events. To describe the hydrogeochemical processes, a bivariate plot analysis of certain hydrochemical parameters is conducted. The results show that the diffuse-flow percentage significantly controls the river hydrochemistry. The domination of diffuse flow occurs during non-flooding and flood recession periods, which are typified by a high value of calcium and bicarbonate and low CO₂ gas content in water. Conversely, the hydrochemistry of flood events is characterized by the domination of conduit flow and CO₂ gas with low calcium and bicarbonate content. According to the wet-season hydrochemistry, it seems that the small- and medium-sized fractures in the Bribin aquifer still provide storage for the diffuse and fissure flows, although the conduit fracture is already developed.