Occurrence of noble metals in aluminum- and chromium- rich objects in ordinary chondrites and of baddeleyite (ZrO2) in a chromite inclusion

Abstract— Platinum group elements (PGE) enrichments are found in Fe-Ni blebs (<1 μm) in Al- and Cr-rich objects in the ordinary chondrites Ste. Marguerite, Forest Vale, Montferré. In Ste. Marguerite, high ZrO₂ concentrations (baddeleyite) are also present in a chromite inclusion. Iridium enrichment in this material compared to its metal content is confirmed by INAA. The widespread occurrence of PGE in Al- and Cr-rich objects, mostly present in H-group chondrites of nearly equilibrated types, must be taken into account to understand their conditions of formation.     

Ice‐cover variability on shallow lakes at high latitudes: model simulations and observations

A one‐dimensional thermodynamic model for simulating lake‐ice phenology is presented and evaluated. The model can be driven with observed daily or hourly atmospheric forcing of air temperature, relative humidity, wind speed, cloud amount and snowfall. In addition to computing the energy balance components, key model output includes the temperature profile at an arbitrary number of levels within the ice/snow (or the water temperature if there is no ice) and ice thickness (clear ice and snow‐ice) on a daily basis, as well as freeze‐up and break‐up dates. The lake‐ice model is used to simulate ice‐growth processes on shallow lakes in arctic, sub‐arctic, and high‐boreal forest environments. Model output is compared with field and remote sensing observations gathered over several ice seasons. Simulated ice thickness, including snow‐ice formation, compares favourably with field measurements. Ice‐on and ice‐off dates are also well simulated when compared with field and satellite observations, with a mean absolute difference of 2 days. Model simulations and observations illustrate the key role that snow cover plays on the seasonal evolution of ice thickness and the timing of spring break‐up. It is also shown that lake morphometry, depth in particular, is a determinant of ice‐off dates for shallow lakes at high latitudes. Copyright © 2003 John Wiley & Sons, Ltd.     

Effects of compressibility on the flow of lava

Lava contains gas bubbles and hence is a compressible liquid whose density increases as a function of pressure. After eruption at the Earth's surface, it spreads at a rate which is a function of its thickness and it is compressed under its own weight. Therefore, both thickness and spreading rate are determined by a balance between viscous and compressible effects. Theoretical equations are derived for the shape and velocity of a compressible liquid spreading on a horizontal surface. Solutions are obtained for a fixed eruption rate Q. The radial extent of the flow increases proportional to t ^1/2. A dimensionless number C is defined which characterizes the importance of flow compression: , where ₀ is bubbly lava density at atmospheric pressure, compressibility, viscosity and g the acceleration of gravity. C can be thought of as the ratio of two characteristic length-scales, one for compression effects and one for viscous effects. The larger C is, the more important compressibility effects are. As C is increased, the flow becomes thinner because the liquid is compressed more and more efficiently. Compressibility acts to smooth out variations of flow thickness, which provide the driving force. Thus, all else being equal, a compressible liquid flows less rapidly than an incompressible one. When trying to infer the effective viscosity of a flow from its spreading rate, the neglect of compressibility leads to an overestimate. The various factors which act to determine the distribution of gas bubbles in lava flows are reviewed and discussed quantitatively. Comparison with data from Obsidian Dome (Eastern California) shows that disequilibrium effects are important and that bubble resorption during burial in a thick flow is not a pervasive phenomenon. The analysis is applied to the 1979 dome of Soufrière de Saint Vincent (W.I.). An effective value of compressibility for this 100-m-thick dome is 1.5x10^–6 Pa^–1. This implies that, all else being equal, the viscosity of this lava may be overestimated by a factor of 5 if no account is taken of the compressible nature of the flow.     

The effects of tourism on space and society in the south Vendeen littoral, from La Tranche-sur-Mer to the bay of l'Aiguillon

The attraction of the coast of south Vendée is mainly due to its long stretches of sandy beaches and to the mildness of the weather. Following the Second World War, the number of tourists grew rapidly this being a popular family area with camping, caravanning, renting of lodgings, staying with friends or relatives, or second homes. This tourism development not only puts growing pressure on space, but also on traditional local trades. The most disrupted is agriculture. The biological exploitation of the sea has remained at l'Aiguillon-La Faute. At La Tranche and La Faute, tourism takes first place. At l'Aiguillon, where the balance of trades is better, it would be a mistake to sacrifice the biological exploitation of the sea for tourism.     

ENSO related modulation of coastal upwelling in the eastern Atlantic

An index of ENSO in the Pacific during early boreal winter is shown to account for a significant part of the variability of coastal SST anomalies measured a few months later within the wind driven West African coastal upwelling region from 10°N to 26°N. This teleconnection is thought to result from an atmospheric bridge between the Pacific and Atlantic oceans, leading to warm (cold) ENSO events being associated with a relaxation (intensification) of the Atlantic trade winds and of the wind-induced coastal upwelling. This ENSO related modulation of the wind-driven coastal upwelling appears to contribute to the connection observed at the basin-scale between ENSO and SST in the north Atlantic. The ability to use this teleconnection to give warnings of large changes in the West African upwelling several months in advance is successfully tested using data from the 1998 and 1999 ENSO events.     

Optical properties of low molecular weight and colloidal organic matter: Application of the ultrafiltration permeation model to DOM absorption and fluorescence

Cross-flow ultrafiltration (CFF) is often used to obtain separation and concentration of colloids from bulk natural water samples. Application of the ultrafiltration permeation model allows the quantitative determination of the low molecular weight material (LMW, < 1 kDa) and colloids in bulk dissolved organic matter (DOM) from measurements of time series permeate samples obtained from CFF. Detailed analysis of a Yukon River water sample shows that DOM absorption coefficient and fluorescence follow the permeation model and that the complex spectral optical properties of LMW DOM can be reconstructed from CFF data. A combination of measured and modeled data indicates that the LMW contribution to bulk DOM optical properties obtained from CFF can be grossly underestimated by the use of a low concentration factor (CF, the ratio of initial sample volume to retentate volume). Even at a relatively high CF of 19, optical properties of LMW DOM calculated from measurements of the retentate or integrated permeate would underestimate true values by 5–36%. In the Yukon River sample, LMW dissolved organic carbon represented 26% of the bulk concentration, but only 3–14% of the colored DOM was in the LMW fraction while 31–33% of bulk DOM florescence was due to LMW DOM. The contrasting optical properties of LMW and colloidal DOM support the concept that analysis of bulk DOM absorption and fluorescence properties reveals information about DOM molecular weight.