Removal of chromium (VI) from aqueous solutions using Lewatit FO36 nano ion exchange resin

The removal of the chromium (VI) ion from aqueous solutions with the Lewatit FO36 ion-exchange resin is described at different conditions. The effects of adsorbent dose, initial metal concentration, contact time and pH on the removal of chromium (VI) were investigated. The batch ion exchange process was relatively fast and it reached equilibrium after about 90 min of contact. The ion exchange process, which is pH dependent showed maximum removal of chromium (VI) in the pH range 5.0–8.0 for an initial chromium (VI) concentration of 0.5 mg/dm³. The equilibrium related to Lewatit FO36 ion- exchange capacity and the amounts of the ion exchange were obtained using the plots of the Langmuir adsorption isotherm. It was observed that the maximum ion exchange capacity of 0.29 mmol of chromium (VLVg for Lewatit FO36 was achieved at optimum pH value of 6.0. The ion exchange of chromium (VI) on this cation-exchange resin followed first-order reversible kinetics.     

Study on the Erodibility and Mechanical Resistance of Mulches Prepared from Micro Silica–Cement Mixtures

Geotechnical and Geological Engineering - Mulching is fastest strategy to control sand dune movement in arid and semiarid areas. In the present study the effect of micro silica- cement mixture was...     

Seismic ground amplification induced by box-shaped tunnels

The growing use of underground structures, specifically to facilitate urban transportation, highlights the need to scrutinize the effects of such spaces on the seismic ground response as well as the surrounding buildings. In this regard, the seismic ground amplification variations in the vicinity of single and twin box-shaped tunnels subjected to SV waves have been investigated by the finite difference method. To evaluate the effects, generalizable dimensionless diagrams based on the results of parametric numerical analysis considering factors such as variations in the tunnels’ depth, the distances between the tunnels, tunnel lining flexibility, and input wave frequency, have been presented. In addition, to assess the effects of underground box-shaped tunnels on the response spectrum of the ground surface, seven selected accelerograms have been matched based on a specific design spectrum for the stiff soil condition of Eurocode 8 (CEN, 2006). The results underline the significant amplification effect of the box-shaped tunnels on the ground motions, specifically in the case of horizontal twin tunnels, which should be given more attention in current seismic design practices for surface structures.

     

Modelling of moving bed biofilm reactor (MBBR) efficiency on hospital wastewater (HW) treatment: a comprehensive analysis on BOD and COD removal

Performance of moving bed biofilm reactor system for a real hospital wastewater (HW) was experimented, modelled, and optimized using response surface methodology. Prior to conducting laboratory tests, design of the experiments was evaluated to minimize any prediction error. Statistical analyses demonstrated the models’ validity and adequacy for anticipation of the removal of BOD and COD by the process. The models predictions (with desirability of 0.98) were found to be in very good agreement with confirmative experiments results. The results indicated that under convenient operating conditions of the studied variables (packing rate 70%, HRT 24 h, and MLSS 3000 mg/L), the removal efficiencies for BOD and COD were 97.8 and 95.6%, respectively. Moreover, kinetics of the biological process showed that removal of organic matters for the tested wastewater adheres to modified Stover–Kincannon model with a correlation coefficient of 0.998. Ratio of BOD to COD of 0.6 (optimal range for biological treatment normally is >0.5) suggests acceptable efficiency of the reactor for decomposing organic load. A high overall efficiency of the process and fulfilling the related standards make this system an appropriate option for treating HDW.     

“H” Shaped Echelon Joints Under Uniaxial Loading

Geotechnical and Geological Engineering - In this investigation, the failure behaviour of “H” shaped non-persistent cracks under uniaxial load has been examined using experimental tests...     

Cycle slip detection and repair of undifferenced single-frequency GPS carrier phase observations

Cycle slip detection and repair is an important issue in the GPS data processing. Different methods have been developed to detect and repair cycle slips on undifferenced , single- or double-differenced observations. The issue is still crucial for high-precision GPS positioning, especially for the undifferenced GPS observations. A method is proposed to fix cycle slips based on the generalized likelihood ratio (GLR) test. The method has a good performance on cycle slip fixing of undifferenced carrier phase observations on individual frequencies, either on L1 or on L2, without making a linear combination among the observables. The functional model is a piecewise cubic curve fitted to a number of consecutive data using the least squares cubic spline approximation (LS-CSA). For fixing the cycle slips, an integer estimation technique is employed to determine the integer values from the float solution. The performance of the proposed method is then compared with the existing two methods using simulated data. The results on a few GPS data sets with sampling rate of 1 Hz or higher confirm that this method can detect and correct all simulated cycle slips regardless of the size of the cycle slip or the satellite elevation angle. The efficacy of the method is then investigated on the GPS data sets with lower sampling rates of 5, 10, and 30 s. The results indicate that the proposed method always performs the best for the data sets considered. This is thus an appropriate method for cycle slip detection and repair of single-frequency GPS observations.     

Harmonic analysis of total electron contents time series: methodology and results

In an attempt to model regular variations of the ionosphere, the least-squares harmonic estimation is applied to the time series of the total electron contents (TEC) provided by the JPL analysis center. Multivariate and modulated harmonic estimation spectra are introduced and estimated for the series to detect the regular and modulated dominant frequencies of the periodic patterns. Two significant periodic patterns are the diurnal and annual signals with periods of 24/n hours and 365.25/n days (n = 1, 2, …), which are the Fourier series decomposition of the regular daily and yearly periodic variations of the ionosphere. The spectrum shows a cluster of periods near 27 days, thereby indicating irregularities at this solar cycle period. A series of peaks, with periods close to the diurnal signal and its harmonics, are evident in the spectrum. In fact, the daily signal harmonics of ω _i  = 2πi are modulated with the annual signal harmonics of ω _j  = 2πj/365.25 as ω _ijM  = 2πi(1 ± j/365.25i). Among them, at low and midlatitudes, the largest variations belong to the diurnal signal modulated to the semiannual signal. Some preliminary results on the modulated part are presented. The maximum ranges of the modulated daily signal are ±15 TECU and ±6 TECU at high and low solar periods, respectively. A model consisting of purely harmonic functions plus modulated ones is capable of studying known regular anomalies of the ionosphere, which is currently in progress.     

Failure Behavior of Room and Pillar with Different Room Configuration Under Uniaxial Loading Using Experimental Test and Numerical Simulation

Geotechnical and Geological Engineering - This paper investigates different configuration of the room and pillar under uniaxial loading using experimental and particle flow code in two dimension...