Geostatistical features of streambed vertical hydraulic conductivities in Frenchman Creek Watershed in Western Nebraska

This study evaluated the spatial variability of streambed vertical hydraulic conductivity (K_v) in different stream morphologies in the Frenchman Creek Watershed, Western Nebraska, using different variogram models. Streambed K_v values were determined in situ using permeameter tests at 10 sites in Frenchman, Stinking Water and Spring Creeks during the dry season at baseflow conditions. Measurements were taken both in straight and meandering stream channels during a 5 day period at similar flow conditions. Each test site comprised of at least three transects and each transect comprised of at least three K_v measurements. Linear, Gaussian, exponential and spherical variogram models were used with Kriging gridding method for the 10 sites. As a goodness-of-fit statistic for the variogram models, cross-validation results showed differences in the median absolute deviation and the standard deviation of the cross-validation residuals. Results show that using the geometric means of the 10 sites for gridding performs better than using either all the K_v values from the 93 permeameter tests or 10 K_v values from the middle transects and centre permeameters. Incorporating both the spatial variability and the uncertainty involved in the measurement at a reach segment can yield more accurate grid results that can be useful in calibrating K_v at watershed or sub-watershed scales in distributed hydrological models.     

Simulations of deep pencil-beam redshift surveys

We create mock pencil-beam redshift surveys from very large cosmological N -body simulations of two cold dark matter (CDM) cosmogonies, an Einstein–de Sitter model ( τ CDM) and a flat model with Ω₀=0.3 and a cosmological constant (ΛCDM). We use these to assess the significance of the apparent periodicity discovered by Broadhurst et al. Simulation particles are tagged as 'galaxies' so as to reproduce observed present-day correlations. They are then identified along the past light-cones of hypothetical observers to create mock catalogues with the geometry and the distance distribution of the Broadhurst et al. data. We produce 1936 (2625) quasi-independent catalogues from our τ CDM (ΛCDM) simulation. A couple of large clumps in a catalogue can produce a high peak at low wavenumbers in the corresponding one-dimensional power spectrum, without any apparent large-scale periodicity in the original redshift histogram. Although the simulated redshift histograms frequently display regularly spaced clumps, the spacing of these clumps varies between catalogues and there is no 'preferred' period over our many realizations. We find only a 0.72 (0.49) per cent chance that the highest peak in the power spectrum of a τ CDM (ΛCDM) catalogue has a peak-to-noise ratio higher than that in the Broadhurst et al. data. None of the simulated catalogues with such high peaks shows coherently spaced clumps with a significance as high as that of the real data. We conclude that in CDM universes, the regularity on a scale of ∼130  h ⁻¹ Mpc observed by Broadhurst et al. has a priori probability well below 10⁻³.     

Surface complexation of U(VI) on goethite (α-FeOOH)

Sorption of U(VI) to goethite is a fundamental control on the mobility of uranium in soil and groundwater. Here, we investigated the sorption of U on goethite using EXAFS spectroscopy, batch sorption experiments and DFT calculations of the energetics and structures of possible surface complexes. Based on EXAFS spectra, it has previously been proposed that U(VI), as the uranyl cation , sorbs to Fe oxide hydroxide phases by forming a bidentate edge-sharing (E2) surface complex, >Fe(OH)₂UO₂(H₂O)_n. Here, we argue that this complex alone cannot account for the sorption capacity of goethite (α-FeOOH). Moreover, we show that all of the EXAFS signal attributed to the E2 complex can be accounted for by multiple scattering. We propose that the dominant surface complex in CO₂-free systems is a bidentate corner-sharing (C2) complex, (>FeOH)₂UO₂(H₂O)₃ which can form on the dominant {101} surface. However, in the presence of CO₂, we find an enhancement of UO₂ sorption at low pH and attribute this to a (>FeO)CO₂UO₂ ternary complex. With increasing pH, U(VI) desorbs by the formation of aqueous carbonate and hydroxyl complexes. However, this desorption is preceded by the formation of a second ternary surface complex (>FeOH)₂UO₂CO₃. The three proposed surface complexes, (>FeOH)₂UO₂(H₂O)₃, >FeOCO₂UO₂, and (>FeOH)₂UO₂CO₃ are consistent with EXAFS spectra. Using these complexes, we developed a surface complexation model for U on goethite with a 1-pK model for surface protonation, an extended Stern model for surface electrostatics and inclusion of all known UO₂-OH-CO₃ aqueous complexes in the current thermodynamic database. The model gives an excellent fit to our sorption experiments done in both ambient and reduced CO₂ environments at surface loadings of 0.02-2.0 wt% U.     

Response of zooid size in Cupuladria exfragminis (Bryozoa) to simulated upwelling temperatures

We investigate the effect of the temperature–size rule upon zooids of the tropical American bryozoan Cupuladria exfragminis. Results show that mean zooid length, zooid width and zooid area vary significantly between clonal replicates of C. exfragminis kept under different controlled temperature conditions. Significantly larger zooids are produced during times of lowered water temperature that are comparable with the temperatures that occur during seasonal upwelling along the Pacific coast of Panama where the animal lives in abundance. Interpolation of data suggests that a drop of 1 °C causes a 5% increase in zooid size, and that almost all variation in zooid size in natural populations can be explained by temperature. Results are discussed in context of the potential use of zooid size variation in cupuladriid bryozoans to measure the strength of seasonal upwelling in ancient seas by analysing zooid size changes in fossil colonies. The technique of cloning cupuladriid colonies by fragmentation is also discussed with reference to its benefits in experimental studies where genotypes need to be controlled or replicated.     

The geography of water conflict and cooperation: internal pressures and international manifestations

Studies on transboundary water conflict and cooperation generally consider interstate relations over shared water resources as distinct from intrastate relations. While connections have been made between international water relations and regional relationships in general, it is conceivable that international water conflict and cooperation may also be influenced by domestic water events and vice versa. This paper seeks to investigate the dynamics of water interactions across geographic scale and their relationship to broader international affairs. The research approach involves the creation of an analytical framework for assessing possible linkages between external and internal interactions over freshwater resources. The framework is applied to three case studies – the Middle East, South Asia and Southern Africa – utilizing 'event data'. To validate the findings from the quantitative analyses, the results are compared with conventional qualitative understandings of water and overall relations in the three regions. The comparison demonstrates not only the efficacy of the analytical framework in general, but also highlights, at least in terms of the specific case studies selected, the disparate water dynamics across geographic regions and the importance of considering water events, both national and international, within larger political and historical contexts.     

Implications of measurement metrics on soil freezing curves: A simulation of freeze–thaw hysteresis

Soil freeze–thaw events have important implications for water resources, flood risk, land productivity, and climate change. A property of these phenomena is the relationship between unfrozen water content and sub-freezing temperature, known as the soil freezing characteristic curve (SFC). It is documented that this relationship exhibits hysteretic behaviour when frozen soil thaws, leading to the definition of the soil thawing characteristic curve (STC). Although explanations have been given for SFC/STC hysteresis, the effect that ‘scale’ – particularly ‘measurement scale’ – may have on these curves has received little attention. The most commonly used measurement scale metric is the ‘support’, which is the spatial (or temporal) unit within which the measured variable is integrated or soil volume sampled. We show (a) measurement support can influence the range and shape of the SFC and (b) hysteresis can be attributed, in part, to the support and location of the measurements comprising the SFC/STC. We simulated lab measured temperature, volumetric water content (VWC), and permittivity from soil samples undergoing freeze–thaw transitions using Hydrus-1D and a modified Dobson permittivity model. To assess the effect of measurement support and location on SFC/STC, we masked the simulated temperature and VWC/permittivity extent to match the instrument's support and location. By creating a detailed simulation of the intra- and inter-support variability associated with the penetration of a freezing front, we demonstrate how measurement support and location can influence the temperature range over which water freezing events are captured. We show it is possible to simulate hysteresis in homogenous media with purely geometric considerations, suggesting that SFC/STC hysteresis may be more of an apparent phenomenon than mechanistically real. Lastly, we develop an understanding of how the location and support of soil temperature and VWC/permittivity measurements influence the temperature range over which water freezing events are captured.