Diurnal Variations of Atmospheric Hydrogen Peroxide Concentrations in Saxony (Germany)

During a 3-year study, gaseous hydrogenperoxide (H₂O₂) concentrations were measuredas part of the SANA project at the Melpitz FieldResearch Station and in the city of Leipzig. Typicaldaily mean H₂O₂ mixing ratios on sunny dayswere 0.15 to 0.25 ppbv with maximum values of 0.3 to0.5 ppbv at Melpitz, and 0.3 to 0.6 ppbv with maximumvalues of 0.4 to 1.0 ppbv in Leipzig. Over the entireperiod of the project the maximum hourly mean valueswere 2.1 ppbv and 5.3 ppbv in Melpitz and Leipzig,respectively. The data were not complete enough to show a trend.Linear regression analysis shows, that ozone(O₃), temperature and solar radiation arepositively correlated with H₂O₂, whereasnitrogen oxides (NO_x), carbon monoxide (CO) andrelative humidity are negatively correlated. Negativecorrelation between H₂O₂ and CO is caused byjoint occurrence of CO with NO_x in exhaust gases.Negative correlation between H₂O₂ andrelative humidity is not necessarily in contradictionto the accelerating effect of water vapour onH₂O₂ formation. The strong positivecorrelation of H₂O₂ with the dew pointdifference however seems to better reflect theinfluence of water vapour. Multiple linear regression analysis (MLRA) of thecomponents measured, indicates the great influence of CO on the formation of H₂O₂ in the gasphase.     

Basal Waitemata Group lithofacies: rapid subsidence in an early Miocene interarc basin, New Zealand

The abrupt transition from coastal and shallow shelf sediments to bathyal sediments provides a record of rapid subsidence and deepening of the early Miocene Waitemata basin. Basal shallow marine strata (Kawau Subgroup) accumulated upon a highly dissected surface that overlies deformed Mesozoic metagreywacke. The early Miocene coast was characterized by an embayed and cliffed shoreline with numerous sea stacks and islands. Kawau Subgroup lithofacies, which include pocket beach, shallow shelf and base-of-cliff talus deposits, reflect rapidly changing coastline configuration and water depths as the rugged bedrock surface was buried. The response to continued rapid subsidence and transgression in Waitemata basin was a decrease in the supply of coarse clastic sediment. Beach gravels were locally displaced to greater water depths by avalanching down steep bedrock slopes. The first bathyal turbidite facies, which abruptly overlie the shallow-water Kawau Subgroup, include locally derived sediment gravity flows commonly ponded by remnant bedrock submarine highs. When this local supply of sediment had been exhausted, coarse sediment starvation ensued and bathyal muds accumulated. With the resumption of sediment supply and gradual burial of submarine bedrock relief, submarine fans coalesced and increased in lateral extent. Subsidence of the Waitemata basin to bathyal depths is thought to have occurred in less than a million years. From the above hypothesis, a general model of sedimentation is proposed.     

Pseudo-toplap in seismic models of the Schlern-Raibl contact (Sella platform, northern Italy)

In the Sella platform of the Dolomite Alps, the horizontal beds of the Raibl Formation directly overlie the Upper Schlern Dolomite (Cassian Dolomite of some authors). The Schlern Dolomite comprises steep clinoforms, together with a few tens of metres of horizontal topset beds in the platform interior. Two-dimensional seismic modelling techniques were used to determine the seismic-response of this interesting situation. To perform this, two different lithological models were constructed based on outcrops of the Sella south face. The first model is that of a rapidly prograding platform with slow aggradation in the platform interior. The second model shows clinoforms toplapping against the topset beds of the platform interior. P-wave velocities and bulk densities were assigned to the lithostratigraphical units in accordance with values from a similar study, involving the same formations. The vertical-incidence method was used to construct perfectly migrated time sections and depth sections of reflectivity. These were convolved with zero-phase Ricker wavelets of different peak frequencies to produce the final synthetic seismic sections. Using conventional, low frequencies (e.g. 25 Hz), the seismic response of the two models is almost identical. The topset beds and the Schlern-Raibl contact appear as one event. In a real seismic survey, both sections would be interpreted as toplap of Schlern clinoforms against the Raibl Formation. At higher frequencies (75 Hz), however, differences are revealed. The angle of progradation in the progradation & aggradation model becomes visible, as opposed to the horizontal surface in the progradation & toplap model. Topset beds are resolved separate from the Raibl Formation, but still appear to form a single dipping pseudo-toplap surface. Another modelling technique, simulating unmigrated sections, shows few differences between the two models even at high frequencies. In addition, the clinoforms are disturbed by the refraction of rays. This study demonstrates that, even under ideal acquisition and processing conditions, the seismic tool can introduce a pseudo-toplap. This implies that toplap in a seismic section is not necessarily toplap in outcrop.     

Upper Triassic (Norian) cephalopod limestones of the Hallstatt-type, Oman

Norian crinoidal/brachiopod limestones and cephalopod limestones of the Hallstatt-type occur as blocks in a Hettangian(?) calcareous breccia of the Haliw Formation in the Oman Mountains. Crinoidal and brachiopod packstones, up to 12 m thick, prevail in the lower part of the sequence and were deposited on a substrate of Norian forereef breccia. The overlying cephalopod wackestones, up to 4.9 m thick, have a basal white bed followed by red limestones with abundant planar and scalloped, corroded surfaces and local stromatolites. Upward, red, nodular wackestones and, finally, slumped grey wackestones follow. The analysis of geopetal fabrics in orientated samples shows that bedding of these facies is, in fact, inclined bedding. Inclinations varied between 15 and 29°. In addition, the restored dip directions demonstrate rotation, indicating deposition on a gliding block. The preferred orientation of orthoconic cephalopods and imbrication of discoidal ammonoids coincide with the dip direction measured from geopetal fabrics. Such features, generally interpreted as current-induced, are here interpreted as gravity-induced. The overall mud-supported rock fabric thus indicates deposition under very low-energy conditions. The common mud-supported texture of the rocks contrasts with evidence for current activity found in the scalloped surfaces and shell lags, particularly in the crinoidal/brachiopod facies and the lower, stratigraphically condensed, cephalopod limestones. This indicates that deposition of lime mud alternated with periods of elevated current strength. A comparison of the Hallstatt-type limestones and current-influenced sediments on the northern slope of the Little Bahama Bank suggests that condensed sequences of the Hallstatt-type are restricted to relatively shallow depths with strong fluctuation of contour-following currents undersaturated with respect to aragonite along carbonate shelf margins facing the open ocean. On steep slopes, sediment bypassing may be an additional factor for stratigraphic condensation.     

A large-scale meandering submarine canyon: outcrop example from the late Proterozoic Adelaide Geosyncline, South Australia

The late Proterozoic Adelaide Geosyncline, along with overlying Cambrian strata, comprises a thick sequence of sediments and sparse volcanics which accumulated in a major rift and passive margin setting. During late syn-rift or early post-rift phases, large volumes of terrigenous and carbonate sediments of the late Proterozoic Umberatana and Wilpena Groups and Cambrian Hawker Group filled the rift. Submarine canyon development was related to at least four of these depositional cycles, the most notable of which resulted in incision and subsequent filling of the major (several kilometres in width and up to 1.5 km deep) submarine canyons by the Wonoka Formation. The Wonoka Formation canyons are not obviously fault controlled. They are interpreted to have been eroded by turbidity currents during a relative low-stand of sea-level. They were subsequently filled by a fining-upwards suite of sediments which reflects subsequent relative rise of sea-level and carbonate platform development. Ultimately the canyon complex was buried by north-westerly progradation of overlying fluvial and slope sequences (Billy Springs Beds and possibly correlative upper Pound Subgroup). It is considered likely that more distal elements of this prograding clastic wedge provided the necessary material for canyon erosion, prior to canyon filling and ultimate burial by what may have been elements of the same depositional cycle. It is considered possible that the series of isolated outcrops of canyon cross-sections within the Wonoka Formation are sections of a single canyon thalweg developed within a considerably broader zone of slope degradation. If this interpretation is correct, then the gorge-like Patsy Springs Canyon lies in more proximal regions of the basin-slope, whereas 40 km to the north-east the lower slope is cut by the Fortress Hill Canyon Complex. Palaeocurrent analyses of channel-fill turbidites within the canyons imply that the Fortress Hill Complex is in fact the outcropping western edge of a sinuous, incised canyon thalweg. The Wonoka Formation canyons, containing basal sedimentary breccias but only minor conglomerates, are considered typical of passive margin canyon development. They are contrasted with the generally highly conglomeratic channel-fills observed in outcropping Tertiary and Cretaceous examples of active margin canyons and upper fan valleys.     

Stable isotope study of carbonate sediments from the Coorong Area, South Australia

ABSTRACT
The mineralogy and isotope geochemistry of carbonate minerals in the Coorong area are determined by the water chemistry of different depositional environments ranging from seawater to evaporitically modified continental water. The different isotopic compositions of coexisting calcite and dolomite suggest that each of the above two minerals was formed from water of composition and origin unique to that specific mineral. In addition, the dolomite was not formed by simple solid state cation exchange.
The occurrence of two types of dolomite was shown by isotope analysis and SEM observations. The dolomite, which is isotopically light (δ¹³C = -1 to -2% 0 ; δ¹⁸O=+3 to +5%₀) and of fine grain size (˜ 0·5 μm) probably precipitated under the influence of evaporitically modified continental water. Coarser grained dolomite (up to 4 μm) is isotopically heavier (δ¹³C=+3 to +4%₀; δ¹⁸O=+5 to + 6%₀) contains Mg in excess of Ca and was formed in or close to equilibrium with atmospheric CO² probably by the dolomitization of aragonite.     

The Zircon-Bearing Chromitites of the Phlogopite Peridotite of Finero (Ivrea Zone, Southern Alps): Evidence and Geochronology of a Metasomatized Mantle Slab

The phlogopite peridotite unit of the Finero Complex is a restiticharzburgite that records two metasomatic events. The first eventis related to the intrusion of basaltic magma, which reactedwith the pyroxene of the host harzburgite to produce chromititepods with dunite haloes. It also produced secondary clinopyroxeneand amphibole in the harzburgite and enriched harzburgite inNa and the light rare earth elements. The second metasomaticevent is related to the later intrusion of clinopyroxeniticdykes. During this event, water-rich vapour penetrated the harzburgitealong fractures and reacted with it to form phlogopite, thusenriching the rock in K. Chromitites host zircons that yieldan age for the first metasomatic event of 207·9 + 1·7/-1·3Ma, during which time extensional tectonics prevailed in theSouthern Alps. KEY WORDS: metasomatism; chromitite; zircon; geochronology; Finero     

Computer simulation of reef growth

Light is one of the major controls on reef growth and carbonate production. The growth of present reef builders depends largely upon the amount of light available for photosynthesis. As light decreases with water depth, so does reef growth. The computer model presented extends this principle by combining two functions, one for photosynthesis and the other for the extinction of light in water. The model is used to simulate the growth of Alacran Reef, Mexico, two reefs of the Great Barrier Reef and the reefs of the windward platform of St Croix, US Virgin Islands. The model also gives an accurate simulation of the growth of fore-reef walls in Belize, in agreement with the accretion hypothesis developed for this feature.