In situ high-temperature X-ray diffraction and spectroscopic study of fibroferrite,FeOH(SO<Subscript>4</Subscript>)·5H<Subscript>2</Subscript>O

The thermal dehydration process of fibroferrite, FeOH(SO₄)·5H₂O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO₄)·4H₂O, appearing at about 80 °C due to release of one interstitial H₂O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.     

A new method for specular and diffuse pseudorange multipath error extraction using wavelet analysis

Multipath remains one of the major challenges in Global Navigation Satellite System (GNSS) positioning because it is considered the dominant source of ranging errors, which can be classified into specular and diffuse types. We present a new method using wavelets to extract the pseudorange multipath in the time domain and breaking it down into the two components. The main idea is an analysis-reconstruction approach based on application of both continuous wavelet transform (CWT) and discrete wavelet transform (DWT). The proposed procedure involves the use of L1 code-minus-carrier (CMC) observable where higher-frequency terms are isolated as residuals. CMC residuals are analyzed by applying the CWT, and we propose the scalogram as a technique for discerning time–frequency variations of the multipath signal. Unlike Fourier transform, the potential of the CWT scalogram for examining the non-stationary and multifrequency nature of the multipath is confirmed as it simultaneously allows fine detection and time localization of the most representative frequencies of the signal. This interpretation of the CWT scalogram is relevant when choosing the levels of reconstruction with DWT, allowing accurate time domain extraction of both the specular and diffuse multipath. The performance and robustness of the method and its boundary applicability are assessed. The experiment was carried out using a receiver of Campania GNSS Network. The results are given in which specular multipath error is achieved using DWT level 7 approximation component and diffuse multipath error is achieved using DWT level 6 denoised detail component.     

On the use of Granger causality to investigate the human influence on climate

Summary A paper recently published in “Nature” finds that there is sufficient evidence to identify the effects of human activity on global temperature. The study is based on northern and southern hemispheres’ time series temperature from 1865 to 1994 and the econometric technique applied is Granger causality analysis. In this note, we make some critical remarks on the conclusions of this study which seem to be rather inconsistent from a methodological point of view. It is shown that a more accurate application of Granger causality analysis to this problem may not allow the same strong and unambiguous conclusions. Received December 22, 2000/Revised April 23, 2001     

Reconnaissance geochronology of basement rocks from the Amazonas and Maranhão Basins in Brazil

Rb/Sr whole rock as well as K/Ar whole rock and mineral age determinations have been carried out on drill core samples obtained from the crystalline basement underlying the Amazonas and Maranhão Basins in Brazil. The data confirm the existence of an ancient basement under the Upper and Middle Amazonas Basin. The primary age of the granitic rocks is estimated at about 1560 Ma which correlates with recent age data obtained on granitic rocks on both sides of the Amazonas syneclise. In some areas the K/Ar ages show a decrease probably due to the effect of the Nickerie thermal episode described previously in the Guayana Shield.In the basement of the interconnected Lower Amazonas and Maranhão Basins Late Precambrian (Caririan) metamorphism and igneous activity seems to have been pervasive. The data allow the continuation of the Brazilian age province known in northeastern Brazil under the Maranhão Basin, linking this province to the Brasilia-Paraguay orogenic belt of similar age.     

Contribution of SHRIMP U–Pb zircon geochronology to unravelling the evolution of Brazilian Neoproterozoic fold belts

The South-American continent is constituted of three major geologic–geotectonic entities: the homonym platform (consolidated at the end of the Cambrian), the Andean chain (essentially Meso-Cenozoic) and the Patagonian terrains, affected by tectonism and magmatism through almost all of the Phanerozoic. The platform is constituted by a series of cratonic nuclei (pre-Tonian, fragments of the Rodinia fission) surrounded by a complex fabric of Neoproterozoic structural provinces.     

Sr and Nd isotopic geochemistry of the early ultramafic–mafic rocks of the Mako bimodal volcanic belt of the Kedougou–Kenieba inlier (Senegal)

The Mako bimodal volcanic belt of the Kédougou–Kéniéba inlier is composed of volcanic basalts and peridotites interbedded by quartzites and limestones intruded by different generations of granitoïds. The early volcanic episode of the belt is constituted of submarine basalts with peridotite similar to those of the oceanic abyssal plains. It is intruded by the Badon Kakadian TTG?granitic batholite dated around 2200 Ma. The second volcanic phase is constituted of basaltic, andesitic, and felsitic flows exhibit structures of aerial volcanic rocks. It is intruded by granites dated between 2160 and 2070 Ma. The general pattern of trace element variation of submarine volcanic rocks is consistent with those of basalts from oceanic plateaus which are the modern equivalent of the Archean greenstones belts. The Nd and Sr isotopic systematics typical of juvenile material indicates that the source of these igneous rocks is derived from a depleted mantle source. These results are consistent with the idea of a major accretion within the West African Craton occurring at about 2.1 Ga and corresponding to an important process of mantle–oceanic lithosphere differentiation.     

Measuring persistence in time series of temperature anomalies

Studies on persistence are important for the clarification of statistical properties of the analyzed time series and for understanding the dynamics of the systems which create these series. In climatology, the analysis of the autocorrelation function has been the main tool to investigate the persistence of a time series. In this paper, we propose to use a more sophisticated econometric instrument. Using this tool, we obtain an estimate of the persistence in global land and ocean and hemispheric temperature time series.     

Quantitative morphometric analysis of lakes using GIS: rectangularity R,ellipticity E,orientation O,and the rectangularity vs. ellipticity index,REi

Quantitative measures of polygon shapes and orientation are important elements of geospatial analysis. These kinds of measures are particularly valuable in the case of lakes, where shape and orientation patterns can help identifying the geomorphological agents behind lake formation and evolution. However, the lack of built-in tools in commercial geographic information system (GIS) software packages designed for this kind of analysis has meant that many researchers often must rely on tools and workarounds that are not always accurate. Here, an easy-to-use method to measure rectangularity R, ellipticity E, and orientation O is developed. In addition, a new rectangularity vs. ellipticity index, REi, is defined. Following a step-by-step process, it is shown how these measures and index can be easily calculated using a combination of GIS built-in functions. The identification of shapes and estimation of orientations performed by this method is applied to the case study of the geometric and oriented lakes of the Llanos de Moxos, in the Bolivian Amazon, where shape and orientation have been the two most important elements studied to infer possible formation mechanisms. It is shown that, thanks to these new indexes, shape and orientation patterns are unveiled, which would have been hard to identify otherwise.     

Coastal defence through low crested breakwater structures: jumping out of the frying pan into the fire?

The Adriatic coast of Punta Marina (Ravenna) is protected by 3-km long low crested breakwater structures (LCSs). Through a 3-years long multidisciplinar study, we assessed the impact of such defensive structures on environmental and biological condition. LCSs create pools where conditions are very different from the surrounding nearshore system. Mechanical disturbance by currents and waves varied greatly in intensity and frequency between seaward and landward sides of the structures. Sedimentary budget was positive at the landward side, but it was due to a gain on the seafloor and not on the emerged beach. The budget at seaward was negative. LCSs determine differences in benthic assemblages, alter the seasonal pattern of communities, and modify seasonal fluctuations of animal assemblages. Landward sheltered areas can be seen as “lagoonal island” surrounded by a “sea of marine habitat”. Differences in ecological quality status, obtained through M-AMBI, are due to the sum of these factors.